Welcome to LookChem.com Sign In|Join Free
  • or
Home > Products >  > 

Zinc cyanide

Related Products

Hot Products

Name

Zinc cyanide

EINECS 209-162-9
CAS No. 557-21-1 Density 1.85 g/cm3
PSA 47.58000 LogP 0.03106
Solubility Soluble in alkalies, potassium cyanide and ammonia. Insoluble in water and most solvents. Melting Point 800 °C
Formula C2N2Zn Boiling Point 25.7 °C at 760 mmHg
Molecular Weight 117.425 Flash Point N/A
Transport Information UN 1713 Appearance white to off-white powder
Safety 7-61-60-45-29-28 Risk Codes 50/53-32-26/27/28
Molecular Structure Molecular Structure of 557-21-1 (ZINC CYANIDE) Hazard Symbols DangerousN,VeryT+
Synonyms

Zinccyanide (6CI,7CI,8CI);Zinc dicyanide;

Article Data 62

Zinc cyanide Synthetic route

773837-37-9

sodium cyanide

zinc(II) nitrate hexahydrate

A

557-21-1

zinc(II) cyanide

B

sodium fluoride

Conditions
ConditionsYield
In water compds. dissolved in degassed H2O at 80°C, allowed to stand for 1d at 4°C; NaF filtered off, washed with ice-cold EtOH, aq. EtOH mixt. evapd.;A 78%
B n/a
Conditions
ConditionsYield
With air In neat (no solvent) sample heating at 4 K/min in air to 300°C, temp. keeping for 3 h; XRD;A n/a
B 1%
C n/a
D 1%
460-19-5

ethanedinitrile

557-21-1

zinc(II) cyanide

Conditions
ConditionsYield
slow react. of liq. (CN)2 with Zn at higher temp. up to 115°C; deposition of paracyan layer on Zn is stopping react.; O2 is inhibiting react., benzene vapor and CO2 have no influence on react.;;
Kinetics; at 22°C very slow, studies on influence of temp.; inhibited by O2;
In neat (no solvent) formation on Zn-surface in the cold after several days, at 100 °C after 3 - 4 h;;

hydrogen cyanide; compound of sodium cyanide with copper cyanide

A

557-21-1

zinc(II) cyanide

B

copper(l) cyanide

Conditions
ConditionsYield
With zinc(II) sulfate byproducts: Na2SO4; calcd. amts. of ZnSO4;
With ZnSO4 byproducts: Na2SO4; calcd. amts. of ZnSO4;
773837-37-9

sodium cyanide

7646-85-7

zinc(II) chloride

557-21-1

zinc(II) cyanide

Conditions
ConditionsYield
In neat (no solvent) byproducts: N2; at 550°C, although evolving of N2 but no formation of cyanamide;;
pptn.;;
In neat (no solvent) byproducts: N2; at 550°C, although evolving of N2 but no formation of cyanamide;;
pptn.;;
460-19-5

ethanedinitrile

A

557-21-1

zinc(II) cyanide

B

2074-87-5

carbon nitride

Conditions
ConditionsYield
by heating in sealed tube at 300°C;
by heating in sealed tube at 300°C;

calcium cyanide

7733-02-0

zinc(II) sulfate

557-21-1

zinc(II) cyanide

Conditions
ConditionsYield
pptn.;;
pptn.;;
10196-18-6

zinc(II) nitrate

calcium cyanide

557-21-1

zinc(II) cyanide

Conditions
ConditionsYield
pptn.;;
pptn.;;

calcium cyanide

7646-85-7

zinc(II) chloride

557-21-1

zinc(II) cyanide

Conditions
ConditionsYield
pptn.;;
pptn.;;
74-90-8

hydrogen cyanide

zinc(II) oxide

557-21-1

zinc(II) cyanide

Conditions
ConditionsYield
In water passing HCN into a sludge of ZnO;;
In water passing HCN into a sludge of ZnO;;

Zinc cyanide Consensus Reports

 Zinc and its compounds, as well as cyanide and its compounds, are on the Community Right-To-Know List. Reported in EPA TSCA Inventory.

Zinc cyanide Standards and Recommendations

DOT Classification:  6.1; Label: Poison
OSHA PEL: TWA 5 mg(CN)/m3
ACGIH TLV: CL 5 mg(CN)/m3 (skin)
DFG MAK: 5 mg/m3
NIOSH REL: (Cyanide) CL 5 mg(CN)/m3/10M

Zinc cyanide Specification

This chemical is called Zinc cyanide, and its IUPAC name is zinc dicyanide. With the molecular formula of C2N2Zn, its classification codes are Agricultural Chemical; Experimental pesticide; Unspecified / Unclassified pesticide. The CAS registry number of this chemical is 557-21-1. Additionally, its product categories are Inorganics; Zinc Salts; Metal and Ceramic Science; Salts. Moreover, it's insoluble in cold water, hydrocyanic acid, ethanol, ether and organic acids, slightly soluble in water, soluble in caustic soda, ammonia, acetic acid zinc solution.

Other characteristics of the Zinc cyanide can be summarised as followings: (1)ACD/LogP: -0.25; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -0.25; (4)ACD/LogD (pH 7.4): -0.25; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 17.42; (8)ACD/KOC (pH 7.4): 17.42; (9)#H bond acceptors: 1; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 0; (12)Polar Surface Area: 23.79 Å2; (13)Enthalpy of Vaporization: 27.18 kJ/mol; (14)Boiling Point: 25.7 °C at 760 mmHg; (15)Vapour Pressure: 740 mmHg at 25°C.

The Zinc cyanide could be obtained by the reactants of serum zinc chloride and sodium cyanide solution. This reaction needs the processes of separation and drying. The reaction equation is as following: 2NaCN+ZnC12→Zn(CN)2+2NaCl.

Uses of this chemical: The Zinc cyanide is mainly used in electroplating, organic synthesis, medicine and pesticide manufacturing. It could react with 1,3,5-triethyl-benzene to obtain the 2,4,6-triethyl-benzaldehyde. This reaction needs the reagent of HCl , and the yield is about 79 %.

Zinc cyanide could react with 1,3,5-triethyl-benzene to obtain the 2,4,6-triethyl-benzaldehyde

When you are using this chemical, please be cautious about it as the following: This chemical is very toxic by inhalation, in contacting with skin and if swallowed. It's also very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. If contacts with acid, it will liberate very toxic gas. Keep its container tightly closed. Do not empty into drains. Refer to special instructions / safety data sheets if you use it. After contacting with skin, wash immediately with plenty of soap-suds. Moreover, this material and its container must be disposed of as hazardous waste. 

You can still convert the following datas into molecular structure:
1.SMILES: [Zn+2].[C-]#N.[C-]#N
2.InChI: InChI=1/2CN.Zn/c2*1-2;/q2*-1;+2
3.InChIKey: GTLDTDOJJJZVBW-UHFFFAOYAM

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rat LCLo inhalation 61mg/m3/4H (61mg/m3)   National Technical Information Service. Vol. OTS0571244,
rat LD50 oral 54mg/kg (54mg/kg)   Toxicologist. Vol. 3, Pg. 170, 1983.
rat LDLo intraperitoneal 100mg/kg (100mg/kg)   National Academy of Sciences, National Research Council, Chemical-Biological Coordination Center, Review. Vol. 5, Pg. 28, 1953.

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 557-21-1