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Cas Database |
| Name |
Zinc nitrate hexahydrate |
EINECS | 231-943-8 |
| CAS No. | 10196-18-6 | Density | 2.065 g/mL at 25 °C(lit.) |
| PSA | 193.14000 | LogP | 0.17990 |
| Solubility | 1800 g/L (20 °C) in water | Melting Point |
36 °C(lit.) |
| Formula | Zn(NO3)2.6(H2O) | Boiling Point | 105～131oC (-6H2O) |
| Molecular Weight | 189.4 | Flash Point | N/A |
| Transport Information | UN 1514 5.1/PG 2 | Appearance | white crystal |
| Safety | 17-26-24/25 | Risk Codes | 8-22-36/37/38-38 |
| Molecular Structure |
|
Hazard Symbols |
 O,  Xn
|
| Synonyms |
Nitricacid, zinc salt, hexahydrate (8CI,9CI);Nitric acid, zinc salt,hydrate (2:1:6);Zincnitrate (Zn(NO3)2), hexahydrate;Zinc nitratehexahydrate (Zn(NO3)2.6H2O); |
Article Data | 68 |
Zinc nitrate hexahydrate Synthetic route
- 10196-18-6
zinc(II) nitrate
| Conditions | Yield |
|---|---|
| at 20 - 800℃; | 69.8% |
- 7440-66-6
zinc
A
- 10196-18-6
zinc(II) nitrate
| Conditions | Yield |
|---|---|
| In water aq. soln. of Al(NO3)3*9H2O treated with Zn, stirred overnight; filtered, evapd., washed with isopropanol; monitored by XRD; | A n/a B 55.2% |
| Conditions | Yield |
|---|---|
| In nitric acid prepn. by treating of metal carbonate with 70% HNO3 at room temp.; washed (petroleum ether); recrystd. (H2O); dried over fused CaCl2 in desiccator; |
| Conditions | Yield |
|---|---|
| In water formation from Zn(NO2)2 in aq. soln. with O2 or O2 containing gases under pressure above 150°C;; | |
| In water formation from Zn(NO2)2 in aq. soln. with O2 or O2 containing gases under pressure above 150°C;; |
- 10196-18-6
zinc(II) nitrate
| Conditions | Yield |
|---|---|
| In neat (no solvent) byproducts: basic zinc nitrates; on dehydration on monohydrate on heating or at room temp. in vacuum, insol. basic zinc nitrates are formed;; | 0% |
| In neat (no solvent) byproducts: basic zinc nitrates; on dehydration on monohydrate on heating or at room temp. in vacuum, insol. basic zinc nitrates are formed;; | 0% |
| Conditions | Yield |
|---|---|
| In nitric acid aq. HNO3; oxide dissoln. soln. evapn. to dryness; residue dissoln. in water, soln. evapn. (excess acid removal); | |
| In water | |
| In water |
| Conditions | Yield |
|---|---|
| In further solvent(s) byproducts: NH3, H2O; on dissolving of ZnO in molten ammonium nitrate;; | |
| byproducts: NH3; H2O; |
| Conditions | Yield |
|---|---|
| In water Irradiation (UV/VIS); addition of solid ZnO to a solution of AgNO3 in H2O; sun light (day light) irradiation;; |
| Conditions | Yield |
|---|---|
| byproducts: Ag, O2; Irradiation (UV/VIS); irradiated ZnO is reacting with AgNO3;; |
| Conditions | Yield |
|---|---|
| on react. of N2O5 in a closed apparatus;; small amt. of ZnO and Zn(NO2)2;; | |
| on react. of N2O5 in a closed apparatus;; small amt. of ZnO and Zn(NO2)2;; |
Zinc nitrate hexahydrate Chemical Properties
Molecule structure of Zinc nitrate hexahydrate (CAS NO.10196-18-6):
.gif)
IUPAC Name: Zinc dinitrate hexahydrate
Molecular Weight: 297.51048 g/mol
Molecular Formula: H12N2O12Zn
Density: 2.065 g/mL at 25 °C(lit.)
Melting Point: 36 °C(lit.)
Water Solubility: 1800 G/L (20 °C)
H-Bond Donor: 6
H-Bond Acceptor: 12
Exact Mass: 295.96817
MonoIsotopic Mass: 295.96817
Topological Polar Surface Area: 138
Heavy Atom Count: 15
Canonical SMILES: [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].O.O.O.O.O.O.[Zn+2]
InChI: InChI=1S/2NO3.6H2O.Zn/c2*2-1(3)4;;;;;;;/h;;6*1H2;/q2*-1;;;;;;;+2
InChIKey: JGPSMWXKRPZZRG-UHFFFAOYSA-N
EINECS: 231-943-8
Product Categories: Essential Chemicals; Reagent Grade; Routine Reagents
Zinc nitrate hexahydrate Uses
Zinc nitrate hexahydrate (CAS NO.10196-18-6) is mainly used for machines and bicycle parts galvanized, preparation of steel phosphating agent. It is also used as a mordant in dyeing. And it's used as analytical reagent, but also for the pharmaceutical industry.
Zinc nitrate hexahydrate Production
The following is the reaction fomular of preparation of Zinc nitrate hexahydrate .
ZnO +2 HNO3 → Zn (NO3) 2 + H2O
Zinc nitrate hexahydrate Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| mouse | LD50 | intraperitoneal | 110mg/kg (110mg/kg) | SENSE ORGANS AND SPECIAL SENSES: CONJUNCTIVE IRRITATION: EYE VASCULAR: BP ELEVATION NOT CHARACTERIZED IN AUTONOMIC SECTION SKIN AND APPENDAGES (SKIN): HAIR: OTHER | Veterinary and Human Toxicology. Vol. 30, Pg. 224, 1988. |
| mouse | LD50 | oral | 926mg/kg (926mg/kg) | SENSE ORGANS AND SPECIAL SENSES: CONJUNCTIVE IRRITATION: EYE VASCULAR: BP ELEVATION NOT CHARACTERIZED IN AUTONOMIC SECTION SKIN AND APPENDAGES (SKIN): HAIR: OTHER | Veterinary and Human Toxicology. Vol. 30, Pg. 224, 1988. |
| rat | LD50 | intraperitoneal | 133mg/kg (133mg/kg) | SENSE ORGANS AND SPECIAL SENSES: MIOSIS (PUPILLARY CONSTRICTION): EYE VASCULAR: BP ELEVATION NOT CHARACTERIZED IN AUTONOMIC SECTION | Veterinary and Human Toxicology. Vol. 30, Pg. 224, 1988. |
| rat | LD50 | oral | 1190mg/kg (1190mg/kg) | "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha, Czechoslovakia, 1972Vol. -, Pg. 10, 1972. |
Zinc nitrate hexahydrate Consensus Reports
Zinc and its compounds are on the Community Right-To-Know List.
Zinc nitrate hexahydrate Safety Profile
Hazard Codes: 
O, 
Xn
Risk Statements: 8-22-36/37/38-38
R8 :Contact with combustible material may cause fire.
R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin.
R38:Irritating to skin.
Safety Statements: 17-26-24/25
S17:Keep away from combustible material.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S24/25:Avoid contact with skin and eyes.
RIDADR: UN 1514 5.1/PG 2
WGK Germany: 3
RTECS: ZH4775000
HazardClass: 5.1
PackingGroup: II
Moderately toxic by ingestion. A severe skin and eye irritant. Can react violently with carbon; copper; metal sulfides; organic matter; phosphorus; sulfur. When heated to decomposition it emits toxic fumes of NOx and ZnO. See also ZINC COMPOUNDS and NITRATES.
Zinc nitrate hexahydrate Specification
Zinc nitrate hexahydrate (CAS NO.10196-18-6) is also named as CCRIS 8894 ; Dusicnan zinecnaty ; Dusicnan zinecnaty [Czech] ; Nitric acid, zinc salt, hexahydrate ; Zinc(II) nitrate, hexahydrate (1:2:6) . Zinc nitrate hexahydrate (CAS NO.10196-18-6) is white crystal. It is soluble in water and ethanol .
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