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100-39-0

Basic Information
CAS No.: 100-39-0
Name: Benzene,(bromomethyl)-
Molecular Structure:
Molecular Structure of 100-39-0 (Benzene,(bromomethyl)-)
Formula: C7H7Br
Molecular Weight: 171.04
Synonyms: Toluene,a-bromo- (8CI);(Bromomethyl)benzene;(Bromophenyl)methane;1-Bromomethylbenzene;NSC 8041;Phenylmethyl bromide;a-Bromotoluene;w-Bromotoluene;
EINECS: 202-847-3
Density: 1.438 g/cm3
Melting Point: -3 ºC
Boiling Point: 198.499 ºC at 760 mmHg
Flash Point: 86.667 ºC
Solubility:
Appearance: clear light amber liquid
Hazard Symbols: IrritantXi
Risk Codes: 36/37/38
Safety: 39-2
Transport Information: UN 1737 6.1/PG 2
PSA: 0.00000
LogP: 2.58150
Synthetic route
108-88-3

toluene

100-39-0

benzyl bromide

Conditions
ConditionsYield
With bromine In tetrachloromethane for 1.5h; Ambient temperature;100%
With manganese(IV) oxide; bromine In dichloromethane at 0℃; for 1h; Product distribution; Further Variations:; Solvents; Temperatures; reaction time;100%
With bromine; sodium t-butanolate In cyclohexane Heating;100%
100-51-6

benzyl alcohol

100-39-0

benzyl bromide

Conditions
ConditionsYield
With 1,1,1,2,2,2-hexamethyldisilane; pyridinium hydrobromide perbromide In chloroform at 25℃; for 0.5h;100%
With phosphorus tribromide In benzene at 20℃;100%
Stage #1: benzyl alcohol With 1,2,3-Benzotriazole; thionyl chloride In dichloromethane for 0.0833333h;
Stage #2: With potassium bromide In dichloromethane; N,N-dimethyl-formamide for 0.5h;
99%

cis-{(PhCH2)2Co(III)(2,2'-bipyridine)2}ClO4

100-39-0

benzyl bromide

Conditions
ConditionsYield
With bromine In acetonitrile one-electron oxidn. of cis-Co complex by Br2 at 298 K; monitored by (1)H-NMR;100%
103514-63-2

C13H25N3PS(1+)

100-39-0

benzyl bromide

Conditions
ConditionsYield
With bromide In N,N-dimethyl-formamide98%
100-52-7

benzaldehyde

100-39-0

benzyl bromide

Conditions
ConditionsYield
With Dichloromethylsilane; phosphorus tribromide; iron(III) chloride In acetonitrile for 4h; Heating;97%
With polymethylhydrosiloxane; dimethylbromosulphonium bromide In chloroform at 20℃; for 5h;96%
With chloro-trimethyl-silane; 1,1,3,3-Tetramethyldisiloxane; lithium bromide In acetonitrile at 80℃; for 30h;94%
620-05-3

iodomethylbenzene

100-39-0

benzyl bromide

Conditions
ConditionsYield
With bismuth(III) bromide In 1,2-dichloro-ethane at 25℃; for 2.25h;97%
With pyridine; tributyltin bromide at 50℃; Thermodynamic data; Equilibrium constant; other temperatures, Δ G;26 % Spectr.
936-51-6

2-phenyl-1,3-dioxolane

100-39-0

benzyl bromide

Conditions
ConditionsYield
With triethylsilane; Acetyl bromide; tin(II) bromide In dichloromethane for 3h; Ambient temperature;96%
1927-62-4

tetrahydro-2-(benzyloxy)-2H-pyran

100-39-0

benzyl bromide

Conditions
ConditionsYield
With 4-aminophenyl diphenylphosphinite; N-Bromosuccinimide In dichloromethane at 20℃; for 2h;95%
With boron trifluoride diethyl etherate; lithium bromide In acetonitrile for 24h; Ambient temperature;89%
With 1-(2-OPPh2-propyl)-3-methylimidazolium hexafluorophosphate; bromine at 80℃; for 2h;89%
350-50-5

benzyl fluoride

100-39-0

benzyl bromide

Conditions
ConditionsYield
With hydrogen bromide at 130℃; for 1h;95%
Multi-step reaction with 2 steps
1: 12 N HCl / 105 °C
2: 93 percent / 47percent aq. HBr / 1 h / 130 °C
View Scheme
14642-79-6

benzyloxy-trimethylsilane

100-39-0

benzyl bromide

Conditions
ConditionsYield
With 4-aminophenyl diphenylphosphinite; bromine In dichloromethane at 20℃;95%
With 1-(2-OPPh2-propyl)-3-methylimidazolium hexafluorophosphate; bromine at 80℃; for 1h;87%
With Tri-n-butylfluorphosphoniumbromid In benzene at 20℃; for 24h;81%
55791-06-5

benzyl mesylate

100-39-0

benzyl bromide

Conditions
ConditionsYield
With 1-n-butyl-3-methylimidazolim bromide at 50℃; for 1h; Inert atmosphere; Green chemistry;95%
With lithium bromide In tetrahydrofuran at 20℃; for 2h; Inert atmosphere;89%
With calcium bromide In dimethyl sulfoxide for 3h; Ambient temperature;79%
35052-27-8

3,5-dimethoxy-4-methylphenylmethyl alcohol

A

35047-51-9

5-(bromomethyl)-1,3-dimethoxy-2-methylbenzene

B

100-39-0

benzyl bromide

Conditions
ConditionsYield
With phosphorus tribromideA n/a
B 95%
946-80-5

(benzyloxy)benzene

A

100-39-0

benzyl bromide

B

108-95-2

phenol

Conditions
ConditionsYield
With water; boron tribromide In chloroform-d1 at 20℃; Solvent;A 95%
B 88%
100-44-7

benzyl chloride

100-39-0

benzyl bromide

Conditions
ConditionsYield
With calcium bromide; tetrahexylammonium bromide at 110℃; for 24h;94%
With hydrogen bromide at 130℃; for 1h;93%
With 1-bromo-butane; Mg6Al2(OH)16Cl2*4H2O In N,N-dimethyl-formamide at 69.9℃; for 20h;90%
100-53-8

phenylmethanethiol

100-39-0

benzyl bromide

Conditions
ConditionsYield
With Silphos; bromine In acetonitrile for 0.166667h; Heating;92%
With N-Bromosuccinimide; triphenylphosphine In dichloromethane at 20℃; for 5h;72%
774-48-1

(diethoxymethyl)benzene

100-39-0

benzyl bromide

Conditions
ConditionsYield
With triethylsilane; Acetyl bromide; tin(II) bromide In dichloromethane for 3h; Ambient temperature;91%
53172-91-1

(benzyloxy)(tert-butyl)dimethylsilane

100-39-0

benzyl bromide

Conditions
ConditionsYield
With boron tribromide In dichloromethane for 0.166667h; Ambient temperature;90%
108-88-3

toluene

A

100-39-0

benzyl bromide

B

100-44-7

benzyl chloride

Conditions
ConditionsYield
With tetrabutylammomium bromide; hydrogen bromide; potassium bromide In water at 20℃; Irradiation; Green chemistry;A 90%
B n/a
With N-hydroxyphthalimide; carbon tetrabromide; trichloroisocyanuric acid; cobalt(II) diacetate tetrahydrate In dichloromethane at 25℃; for 20h;
103-82-2

phenylacetic acid

100-39-0

benzyl bromide

Conditions
ConditionsYield
With tetra-N-butylammonium tribromide; dibromoisocyanuric acid In dichloromethane at 20℃; for 2h; UV-irradiation;90%
1125-88-8

benzaldehyde dimethyl acetal

100-39-0

benzyl bromide

Conditions
ConditionsYield
With triethylsilane; Acetyl bromide; tin(II) bromide In dichloromethane for 3h; Ambient temperature;89%
631-61-8

ammonium acetate

100-51-6

benzyl alcohol

A

140-11-4

Benzyl acetate

B

100-39-0

benzyl bromide

Conditions
ConditionsYield
With N-Bromosuccinimide; triphenylphosphine In acetonitrile at 20℃; for 2h; Cooling with ice;A 87%
B 3%
With bromine; triphenylphosphine In acetonitrile at 20℃; for 0.7h;A 40%
B 53%
108-88-3

toluene

A

618-31-5

benzylidene dibromide

B

100-39-0

benzyl bromide

Conditions
ConditionsYield
With bromine In dichloromethane for 2h; Ambient temperature; Irradiation;A 11%
B 86%
With hydrogen bromide; dihydrogen peroxide In water at 20℃; for 10h; Irradiation;A 4%
B 81%
With hydrogen bromide; dihydrogen peroxide In water at 27℃; for 24h; Irradiation;A 7%
B 81%

4-[(3,5-bis-trifluoromethyl-benzyl)-methoxycarbonyl-amino]-2-ethyl-piperidine-1-carboxylic acid tert-butyl ester

100-39-0

benzyl bromide

Conditions
ConditionsYield
Stage #1: 4-[(3,5-bis-trifluoromethyl-benzyl)-methoxycarbonyl-amino]-2-ethyl-piperidine-1-carboxylic acid tert-butyl ester With hydrogenchloride In ethyl acetate for 4.08333h;
Stage #2: With water; sodium hydrogencarbonate In ethyl acetate
84%
780-24-5

dibenzylmercury(II)

A

100-39-0

benzyl bromide

B

103-29-7

1,1'-(1,2-ethanediyl)bisbenzene

Conditions
ConditionsYield
With N-Bromosuccinimide In dichloromethane; benzene Irradiation (UV/VIS); nitrogen atmosphere; mercurial and NBS (2.5 equiv)/CH2Cl2 in deoxygenated solvent irradiated (250-W sunlamp, 40 °C, 6h);; filtration; solvent removed (vacuum); PhCH2CH2Ph and PhCH2Br analysed by (1)H NMR, GLC and GCMS;;A 84%
B 4%
With N-Bromosuccinimide In dichloromethane; benzene Irradiation (UV/VIS); nitrogen atmosphere; mercurial and NBS (2.5 equiv)/CH2Cl2 in deoxygenated solvent irradiated (250-W sunlamp, 40 °C, 4h) in the presence of 20 mol% (t-Bu)2NO (radical);; filtration; solvent removed (vacuum); PhCH2CH2Ph and PhCH2Br analysed by (1)H NMR, GLC and GCMS;;A 46%
B 2%
64-19-7

acetic acid

108-88-3

toluene

A

100-39-0

benzyl bromide

B

98-86-2

acetophenone

C

65-85-0

benzoic acid

Conditions
ConditionsYield
With hydrogen bromide; oxygen; bromide; cobalt(II) acetate; manganese(II) acetate at 75℃; Kinetics; Product distribution; atmospheric pressure;A n/a
B n/a
C 83%
116670-02-1

{(η5-C5Me5)Os(CO)(PMe2Ph)CH2Ph}

7726-95-6

bromine

A

107087-80-9

{(η5-C5Me5)Os(CO)(PMe2Ph)Br}

B

100-39-0

benzyl bromide

Conditions
ConditionsYield
In dichloromethane-d2 (N2); electrophilic cleavage reaction by addn. of bromine to a soln. of Cp*Os(CO)(PMe2Ph)CH2Ph in CD2Cl2;; not isolated, detected by NMR;;A 77%
B 83%
54673-14-2

[(ethoxymethoxy)methyl]benzene

100-39-0

benzyl bromide

Conditions
ConditionsYield
With tetrabutylammomium bromide; 1-(n-butyl)-3-methylimidazolium tetrachloroindate at 135 - 140℃; for 0.075h; Microwave irradiation; Neat (no solvent); chemoselective reaction;83%
1539-57-7

diethyl 2,6-dimethyl-4-benzyl-1,4-dihydropyridine-3,5-dicarboxylate

100-39-0

benzyl bromide

Conditions
ConditionsYield
With dipotassium peroxodisulfate; tris(2,2′-bipyridyl)dichlororuthenium(II) hexahydrate; sodium bromide In water; acetonitrile at 20℃; for 24h; Sealed tube; Inert atmosphere; Irradiation; regioselective reaction;83%
110-86-1

pyridine

100-39-0

benzyl bromide

2589-31-3

N-benzylpyridinium bromide

Conditions
ConditionsYield
100%
In acetone; benzene at 20℃; for 24h;100%
In dichloromethane at 20℃; for 12h;100%
616-47-7

1-methyl-1H-imidazole

100-39-0

benzyl bromide

65039-11-4

3-benzyl-1-methylimidazolium bromide

Conditions
ConditionsYield
at 100℃; for 2h;100%
In 1,4-dioxane at 100℃; for 12h;98%
In ethanol; acetonitrile at 80℃; for 12h;98%
119-65-3

isoquinoline

100-39-0

benzyl bromide

23277-04-5

2-benzylisoquinolin-2-ium bromide

Conditions
ConditionsYield
In methanol for 336000h; Heating;100%
In acetone; benzene at 20℃; for 24h;100%
In methanol for 336h; Heating;100%
98-92-0

nicotinamide

100-39-0

benzyl bromide

13076-43-2

3-(aminocarbonyl)-1-benzylpyridinium bromide

Conditions
ConditionsYield
In acetone for 12h; Reflux;100%
In acetonitrile93%
In acetonitrile at 140℃; for 1.5h; Sealed tube; Microwave irradiation;89%
117-99-7

2-Hydroxybenzophenone

100-39-0

benzyl bromide

93254-81-0

o-(benzyloxy)benzophenone

Conditions
ConditionsYield
With potassium carbonate; potassium iodide In acetone Heating;100%
With caesium carbonate In acetonitrile at 50℃;98%
With caesium carbonate In acetonitrile at 50℃; Inert atmosphere;98%
106-41-2

4-bromo-phenol

100-39-0

benzyl bromide

6793-92-6

p-benzyloxyphenylbromide

Conditions
ConditionsYield
With potassium carbonate In acetonitrile for 6h;100%
Stage #1: 4-bromo-phenol With sodium hydride In N,N-dimethyl-formamide at 5℃; for 0.333333h; Inert atmosphere;
Stage #2: benzyl bromide In N,N-dimethyl-formamide at 20℃; for 2h; Inert atmosphere;
99%
With potassium phosphate; tetrabutylammomium bromide In water at 20℃; for 2h; Sealed tube; Green chemistry;99%
102-84-1

triallyl phosphite

100-39-0

benzyl bromide

74038-34-9

diallyl benzylphosphonate

Conditions
ConditionsYield
In toluene at 95℃; for 4h;100%
5460-31-1

3-nitro-o-cresol

100-39-0

benzyl bromide

20876-37-3

2-benzyloxy-6-nitrotoluene

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 3h;100%
With caesium carbonate In N,N-dimethyl-formamide at 20℃; for 3h;87%
With potassium carbonate In N,N-dimethyl-formamide at 60℃; for 12h; Inert atmosphere;48.6%
4920-77-8

3-methyl-2-nitrophenol

100-39-0

benzyl bromide

61535-21-5

1-(benzyloxy)-3-methyl-2-nitrobenzene

Conditions
ConditionsYield
With potassium carbonate In acetonitrile Heating / reflux;100%
With potassium carbonate In acetonitrile at 40 - 75℃; for 7.75h;99%
With potassium carbonate; acetone
3943-97-3

methyl 4-hydroxycinnamate

100-39-0

benzyl bromide

84184-51-0

(E)-methyl 3-(4-(benzyloxy)phenyl)acrylate

Conditions
ConditionsYield
With potassium carbonate In acetone at 23℃; for 4h; Reflux; Inert atmosphere;100%
With sodium hydride In N,N-dimethyl-formamide at 20℃; for 14h; Etherification;87%
With sodium hydroxide In ethanol82%
100-39-0

benzyl bromide

123-08-0

4-hydroxy-benzaldehyde

4397-53-9

p-benzyloxybenzaldehyde

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 60℃; for 1.16667h;100%
With potassium carbonate In N,N-dimethyl-formamide at 60℃;100%
With potassium carbonate In acetonitrile for 3h;100%
100-39-0

benzyl bromide

603-35-0

triphenylphosphine

1449-46-3

benzyltriphenylphosphonium bromide

Conditions
ConditionsYield
In xylene for 0.00833333h; Heating; microwave irradiation;100%
In toluene for 12h; Reflux;100%
at 100℃; for 0.0333333h; Irradiation;99%
100-39-0

benzyl bromide

95-01-2

2,4-Dihydroxybenzaldehyde

13246-46-3

2,4-dibenzyloxybenzaldehyde

Conditions
ConditionsYield
With potassium carbonate In acetone Heating;100%
With caesium carbonate In acetone at 20℃;100%
With potassium carbonate In acetonitrile at 20℃; Reflux;98%
100-39-0

benzyl bromide

95-01-2

2,4-Dihydroxybenzaldehyde

52085-14-0

4-benzoxy-salicylaldehyde

Conditions
ConditionsYield
Stage #1: 2,4-Dihydroxybenzaldehyde With sodium hydrogencarbonate In acetonitrile at 20℃; for 0.75h; Inert atmosphere;
Stage #2: benzyl bromide In acetonitrile Inert atmosphere; Reflux;
100%
With potassium hydrogencarbonate In acetonitrile for 15h; Reflux;85%
With sodium hydrogencarbonate In acetonitrile for 15h; Reflux;85%
100-39-0

benzyl bromide

103-29-7

1,1'-(1,2-ethanediyl)bisbenzene

Conditions
ConditionsYield
With TiCl2*2THF In tetrahydrofuran for 24h; Heating;100%
With Wilkinson's catalyst; dimethyl zinc(II) In tetrahydrofuran; hexane at 20℃; for 1h;100%
With hafnium(II) chloride In tetrahydrofuran for 12h; Heating;99%
100-39-0

benzyl bromide

620-05-3

iodomethylbenzene

Conditions
ConditionsYield
With sodium iodide In acetone at 20℃; for 24h;100%
With sodium iodide In acetone at 20℃; for 24h; Inert atmosphere; Darkness;100%
With hydrogen iodide; cetyltributylphosphonium bromide at 60℃; for 0.0833333h;99%
95-16-9

1,3-Benzothiazole

100-39-0

benzyl bromide

4614-22-6

3-benzylbenzothiazolium bromide

Conditions
ConditionsYield
In neat (no solvent) at 75℃;100%
Inert atmosphere; Neat (no solvent);99%
for 5h; Reflux;93%
2973-76-4

5-bromo-4-hydroxy-3-methoxybenzaldehyde

100-39-0

benzyl bromide

2556-04-9

4-(benzyloxy)-3-bromo-5-methoxybenzaldehyde

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 20℃; Inert atmosphere;100%
With potassium carbonate In N,N-dimethyl-formamide at 80℃; for 4h;97%
With potassium carbonate In N,N-dimethyl-formamide at 50℃;94%
100-39-0

benzyl bromide

111-42-2

2,2'-iminobis[ethanol]

101-32-6

N-benzyl-diethanolamine

Conditions
ConditionsYield
With potassium carbonate In acetone Reflux;100%
With potassium carbonate In acetone for 8h; Heating;97%
With potassium carbonate In acetone for 8h; Heating / reflux;97%
100-39-0

benzyl bromide

67-63-0

isopropyl alcohol

937-54-2

benzyl isopropyl ether

Conditions
ConditionsYield
Stage #1: isopropyl alcohol With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0℃; for 0.5h; Inert atmosphere;
Stage #2: benzyl bromide In N,N-dimethyl-formamide; mineral oil at 0 - 20℃; for 5h; Inert atmosphere;
100%
With iron(II) sulfate at 75℃; for 12h;92%
With silver(II) oxide Heating;90%
With potassium hydroxide; tetrafluoroboric acid; mercury(II) oxide In dichloromethane 1.) room temp., 1 h;60%
(i) Ag2O, (ii) Py, PhCOCl; Multistep reaction;
100-39-0

benzyl bromide

109-77-3

malononitrile

3779-31-5

2,2-dibenzylmalononitrile

Conditions
ConditionsYield
With potassium carbonate; tetrabutylammomium bromide for 96h; Ambient temperature;100%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In N,N-dimethyl-formamide at 80℃; for 2h;91%
With 1-butyl-3-methylimidazolium hydroxide at 100℃; under 51.7148 Torr; for 0.0833333h; microwave irradiation;82%
100-39-0

benzyl bromide

927-74-2

1-butyn-4-ol

22273-77-4

((but-3-yn-1-yloxy)methyl)benzene

Conditions
ConditionsYield
With tetra-(n-butyl)ammonium iodide; sodium hydride In trichlorophosphate Heating;100%
With tetra-(n-butyl)ammonium iodide; sodium hydride In tetrahydrofuran at 23℃; for 5.5h;100%
With tetra-(n-butyl)ammonium iodide; sodium hydride In tetrahydrofuran; mineral oil at 0 - 23℃; for 18h; Inert atmosphere; Sealed tube;100%
100-39-0

benzyl bromide

15285-42-4

benzyl nitrate

Conditions
ConditionsYield
With silver nitrate In acetonitrile at 70℃; for 5h; Darkness;100%
With silver nitrate In acetonitrile at 20℃; Nitration;97%
With silver nitrate In acetonitrile at 20℃; for 24h;82%
288-32-4

1H-imidazole

100-39-0

benzyl bromide

4238-71-5

1-benzylimidazole

Conditions
ConditionsYield
Stage #1: 1H-imidazole With sodium hydride In N,N-dimethyl-formamide at 0 - 20℃; for 2h;
Stage #2: benzyl bromide In N,N-dimethyl-formamide at 20℃; for 4h;
100%
Stage #1: 1H-imidazole With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0℃; for 0.25h;
Stage #2: benzyl bromide In N,N-dimethyl-formamide; mineral oil at 25℃; for 3h;
97%
With caesium carbonate at 100℃; for 0.416667h; Microwave irradiation;90%
109-06-8

α-picoline

100-39-0

benzyl bromide

2654-66-2

1-Benzyl-6-methylpyridinium bromide

Conditions
ConditionsYield
100%
In acetone Reflux;100%
In toluene for 14h; Inert atmosphere; Reflux;72%
108-89-4

picoline

100-39-0

benzyl bromide

57042-58-7

1-benzyl-1-bromo-4-methylpyridinium bromide

Conditions
ConditionsYield
100%
In acetonitrile at 45℃; for 3h;99%
In acetonitrile at 100℃; for 12h;98.71%
536-78-7

3-ethylpyridine

100-39-0

benzyl bromide

55077-15-1

1-benzyl-3-ethylpyridinium bromide

Conditions
ConditionsYield
100%
at 0 - 20℃;99.6%
at 0 - 20℃;99.6%
105-60-2

caprolactam

100-39-0

benzyl bromide

33241-96-2

1-Benzyl-hexahydro-azepin-2-on

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran for 4h; 0 deg C to 25 deg C;100%
Stage #1: caprolactam With sodium hydride In tetrahydrofuran at 0℃; for 0.5h; Inert atmosphere;
Stage #2: benzyl bromide In tetrahydrofuran at 0 - 20℃; Inert atmosphere;
98%
With sodium hydride In tetrahydrofuran; paraffin 1.) 0 deg C to room temperature, 2 h, 2.) room temperature, 2 h;96%
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    Benzyl bromide 99% factory supply in stock fast shipment

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  • Benzyl bromide

  • Casno:

    100-39-0

    Benzyl bromide

    Min.Order: 1 Kilogram

    FOB Price:  USD $ 0.0-0.0/Kilogram

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    Business Type:Manufacturers

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  • Benzyl bromide

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    100-39-0

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    Min.Order: 0

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    100-39-0

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    Address:Zhengzhou International Trade New Territory,Jinshui District,Zhengzhou ,China

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    100-39-0

    MSDS/COA Download

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  • Benzyl bromide

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    Benzyl bromide CAS NO.100-39-0

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    100-39-0

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    Benzyl bromide Basic information Product Name: Benzyl bromide Synonyms: (bromomethyl)-benzen;1-Bromotoluene;ai3-15300;alpha-bromo-toluen;Bromophenylmethane;-Bromotoluene;Bromotoluene, alpha;bromotoluene,alpha CAS: 100-39-0 MF: C7H7Br MW: 171.0

    SHANGHAI MINSTAR CHEMICAL CO., LTD. is a leading, experienced, professional supplier of API & intermediates, plant extract, food additive, fine chemicals and industry chemicals, et

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    Business Type:Lab/Research institutions

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    Address:BUILDING 8, NO.1098, CHUANSHA ROAD, SHANGHAI, CHINA

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    100-39-0

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    High qualityHangzhou Keying Chem Co., Ltd. Is a comprehensive enterprise, dedicated to the development, production and marketing of chemicals. As a technology innovative and service professional enterprise, Our company mainly engages in global phar

    Hangzhou Keying Chem Co., Ltd. Is a comprehensive enterprise, dedicated to the development, production and marketing of chemicals. As a technology innovative and service profession

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    Business Type:Lab/Research institutions

    Tel:+86-571-85378921

    Address:Jintong international Building, No.113,Huayuangang Street, Gong shu District, Hangzhou,Zhejiang, China.

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    100-39-0

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    ProductName:Benzylbromide Synonyms:(bromomethyl)-benzen;1-Bromotoluene;ai3-15300;alpha-bromo-toluen;Bromophenylmethane;-Bromotoluene;Bromotolue…Appearance:colorless liquid Storage:Store at RT. Package:70kg drums Application:Pharmaceutical Int

    QINGDAO ON-BILLION INDUSTRIAL CO.,LTD was established in 2004 with registered capital RMB 26 million. (Former Qingdao on-billion imp&exp co.,ltd was founded in 1993 ) Awarded as E

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  • Casno:

    100-39-0

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    Min.Order: 1 Gram

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    Henan Coreychem co., LTD focus on high complex new type intermediates and fine chemical custom synthesis,scale-up production and rare chemicals trade.Product category including Intermediates&API,Catalyst and Electronic Chemicals.Covering 811 sq

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    Business Type:Lab/Research institutions

    Tel:+86-371-86658258

    Address:Building 3 of Innovation Park, East District of the National University Science Park

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  • Casno:

    100-39-0

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    Min.Order: 1 Gram

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    Betterbiochem is specialized in APIs, pharmaceutical intermediates & fine chemicals. 1. The best quality, competitive price. 2. The best service before or after shipment. 3. Rich experience in export operation. 4. Rich experience in

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    Business Type:Lab/Research institutions

    Tel:+86-18013506594

    Address:No. 8 Building, 18 nong, Xi Yingnan Road, Pudong, Shanghai,China

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    100-39-0

    ISO 9001 National Research Platform CAS No. 100-39-0

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    1. Subsidiary of Institute of Chemistry, Henan Academy of Sciences, national research platform;2. About 30 years’ experience in this field since 1983;3. An experienced R&D team consisting of Doctors and Masters;4. Various types of analytical instrume

    Zhengzhou Kingorgchem Chemical Technology Co., Ltd. was founded on the basis of Organophosphorus Chemistry Lab of Institute of Chemistry Henan Academy of Sciences in 2015. The

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    Business Type:Lab/Research institutions

    Tel:+86-371-65511936

    Address:NO.56,Hongzhuan Road

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  • Casno:

    100-39-0

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    Appearance:colorless liquid

    Zouping Mingxing Chemical Co., Ltd lies at the west of the Huangshan Mountain in Zouping city, near to Zibo and Qingdao in the east, Japan in the west and Ji-Qing Expressway

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    Business Type:Trading Company

    Tel:86-543-8178171

    Address:428 Daixi Third Road Zouping County Shandong Province China

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    Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

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    Business Type:Lab/Research institutions

    Tel:18369939125

    Address:95A, Xingyuan East Road, Zhangdian District

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    100-39-0

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    Business Type:Lab/Research institutions

    Tel:+86-571-87396432

    Address:No.200 Zhenhua Rd.Xihu Industrial Park, Hangzhou 310030, China

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    100-39-0

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    Min.Order: 1 Gram

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    Qingdao Sigma Chemical Ltd is is a global chemical industry manufacturers and suppliers of pharmaceuticals and intermediates, peptide,Nootropis etc API, food and feed additives, herbal extracts, agrochemicals and fine chemicals etc. Our Labo

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    Business Type:Trading Company

    Tel:0532-80916960

    Address:shandong qingdao

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  • Casno:

    100-39-0

    Benzyl bromide

    Min.Order: 1 Gram

    FOB Price:  USD $ 1.0-2.0/Gram

    span lang="EN-US" style="font-size: 9.0pt;font-family:"Arial",sans-serif;color:#4D4D4D">As a leading manufacturer and supplier of chemicals in china, weckchem not only supply popular chemicals, but also weckchem’s r&d center off

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    HangYu Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. HangYu Chemical consis

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    Business Type:Lab/Research institutions

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    100-39-0

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    Superiority: Zhejiang J&C Biological Technology Co., Limited is specialized in the production of high complex new type intermediates and chemical custom synthesis, scale-up production and rare chemicals trade. Products category is including I

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    100-39-0

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    BaiFuChem is a Professional chemical raw material supplier in China, our main products include Biochemical , Pharma Intermediate and Organic chemical etc. BaiFuChem have wealth of products,experience , expertise and state-of-the-art

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    Business Type:Other

    Tel:+86 592 605 6448

    Address:No.31 Pingshan South Road, HaiCang District, Xiamen, China

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    100-39-0

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    Min.Order: 500 Gram

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    We have strong R&D center which can support and provide custom synthesis accordingly such as fine chemicals,biotechnique , pharmaceuticals etc.We can provide free sample for our clients to test anf verify the quality of our goods.LongyuChem holds str

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     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:86-15821988213

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    100-39-0

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    Min.Order: 1 Kilogram

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    Superior quality Appearance:Clear light amber liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Used as Pharmaceutical Intermediates Transpor

    Hangzhou Yunuo Chemical Co., Ltd. is located in Hangzhou City, China We are specialized in fine chemicals and basic chemical auxiliary materials, Organic compounds, rubber

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    Business Type:Trading Company

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    100-39-0

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    Min.Order: 1 Gram

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    We are leading fine chemicals supplier in China with ISO certificate, Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED

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     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:+86-370-2722992

    Address:32 Room, 5th Floor, Building 11, No. 6 Yinxing Road, High-tech Industrial Development Zone, Zhengzhou City, Henan Province

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    100-39-0

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    Ality Group, established in 2007, is a comprehensive Chemical Supply Group with Patent Technology as its core. Ality Group operates branches in Hong Kong, Singapore and mainland Ch

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  • Casno:

    100-39-0

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    Business Type:Other

    Tel:0086-571-86976032

    Address:Kangkang Gu 1010, Chun xiao road 61,Binjiang District 310052,Hangzhou city , China

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  • Casno:

    100-39-0

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    Business Type:Manufacturers

    Tel:0731-85567275

    Address:No.10048, xiangjiang centry bulding ,kaifu district ,changsha city ,Hunan

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    100-39-0

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     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:+86-571-86758373

    Address:Room1707, 7Th Floor, Xin Chuanmei Industry Building , No.58 of Xintang Road, Jianggan District, Hangzhou, China.

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    100-39-0

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    U-CHEMO is a high-tech enterprise taking pharmaceutical intermediates and fine chemicals as main products. We pay high attention on product quality and apply quality management in the whole manufacturing process from research to production. In additi

    Our company specializes in chemical products, including pharmaceutical intermediates, active pharmaceutical ingredients etc. High quality! High pur

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  • Casno:

    100-39-0

    Benzene,(bromomethyl)-

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Specification

The Benzyl bromide, with the CAS registry number 100-39-0, is also known as a-Bromotoluene. It belongs to the product categories of Pharmaceutical Intermediates; Aromatic Halides (substituted); Organics; Benzyl; Biochemistry; Reagents for Oligosaccharide Synthesis. Its EINECS registry number is 202-847-3. This chemical's molecular formula is C7H7Br and molecular weight is 171.03. What's more, both its IUPAC name and systematic name are the same which is called Bromomethylbenzene. It is an organic compound consisting of a benzene ring substituted with a bromomethyl group. This chemical is a colorless liquid that is decomposed slowly in water.

Physical properties about Benzyl bromide are: (1)ACD/LogP: 2.81; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 2.805; (4)ACD/LogD (pH 7.4): 2.805; (5)ACD/BCF (pH 5.5): 79.805; (6)ACD/BCF (pH 7.4): 79.805; (7)ACD/KOC (pH 5.5): 799.993; (8)ACD/KOC (pH 7.4): 799.993; (9)#H bond acceptors: 0; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 1; (12)Polar Surface Area: 0 Å2; (13)Index of Refraction: 1.568; (14)Molar Refractivity: 38.901 cm3; (15)Molar Volume: 118.926 cm3; (16)Surface Tension: 38.493 dyne/cm; (17)Density: 1.438 g/cm3; (18)Flash Point: 86.667 °C; (19)Enthalpy of Vaporization: 41.693 kJ/mol; (20)Boiling Point: 198.499 °C at 760 mmHg; (21)Vapour Pressure: 0.506 mmHg at 25 °C.

Preparation of Benzyl bromide: this chemical can be prepared by Benzyloxy-tert-butyl-dimethylsilan. This reaction needs reagent BBr3 and solvent CH2Cl2 at ambient temperature. The reaction time is 10 min. The yield is 90 %.

 Benzyl bromide can be prepared by Benzyloxy-tert-butyl-dimethylsilan.

Uses of Benzyl bromide: (1) It is used in organic synthesis for the introduction of the benzyl protecting group for alcohols and carboxylic acids. It is also used as a war gas. (2) it is used to produce other chemicals. For example, it can react with 4-Acetoxymethyl-pyridine to get 4-Benzyloximethyl-pyridine. The reaction occurs with reagents 18-crown-6, KOH and solvent benzene at ambient temperature. The yield is 87 %.

Benzyl bromide can react with 4-Acetoxymethyl-pyridine to get 4-Benzyloximethyl-pyridine.

When you are dealing with this chemical, you should be very careful. This chemical is inflammation to the skin, eyes and respiratory system or other mucous membranes. Therefore, you should wear eye/face protection and keep out of the reach of children.

You can still convert the following datas into molecular structure:
(1) SMILES: c1ccc(cc1)CBr
(2) InChI: InChI=1S/C7H7Br/c8-6-7-4-2-1-3-5-7/h1-5H,6H2
(3) InChIKey: AGEZXYOZHKGVCM-UHFFFAOYSA-N