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100-46-9

Basic Information
CAS No.: 100-46-9
Name: Benzylamine
Molecular Structure:
Molecular Structure of 100-46-9 (Benzylamine)
Formula: C7H9N
Molecular Weight: 107.2
Synonyms: phenylmethanamine;1-phenylmethanamine;Monobenzylamine;.omega.-Aminotoluene;benzylazanium;(Phenylmethyl)amine;benzenemethanamine;.alpha.-Aminotoluene;Benzylamine(BA);Benzyl amine;N-Benzylamine;Benzylamine 99%;
EINECS: 202-854-1
Density: 0.979 g/cm3
Melting Point: -30 °C
Boiling Point: 185 °C at 760 mmHg
Flash Point: 60 °C
Solubility: Soluble in water
Appearance: colourless liquid with an ammoniacal odour
Hazard Symbols: CorrosiveC
Risk Codes: 21/22-34
Safety: 26-36/37/39-45
Transport Information: UN 2735 8/PG 2
PSA: 26.02000
LogP: 1.84560
Synthetic route
622-79-7

benzyl azide

100-46-9

benzylamine

Conditions
ConditionsYield
With Zn(BH4)2(Ph3P)2 In tetrahydrofuran for 0.25h; Reduction; Heating;100%
With sodium tetrahydroborate; tin bis(1,2-benzenedithiolate) In tetrahydrofuran; phosphate buffer at 10℃; for 0.5h; pH=10; Product distribution; Further Variations:; pH-values; Solvents; Reduction;100%
With (Sn(SPh)3)(Et3N) In benzene at 15℃; for 0.0833333h;99%
100-47-0

benzonitrile

100-46-9

benzylamine

Conditions
ConditionsYield
With lithium borohydride; 9-methoxy-9-BBN In diethyl ether at 25℃; for 5h; Product distribution; rate of reduction;100%
With borane N-ethyl-N-isopropylaniline complex In tetrahydrofuran for 0.1h; Heating;100%
With hydrogen; palladium In methanol at 20℃; for 432h;100%
104669-74-1

benzyl carbamic acid allyl ester

100-46-9

benzylamine

Conditions
ConditionsYield
With diethylamine; palladium diacetate; trisodium tris(3-sulfophenyl)phosphine In water; acetonitrile for 0.166667h; Ambient temperature;100%
4383-22-6

Allylbenzylamine

100-46-9

benzylamine

Conditions
ConditionsYield
With Thiosalicylic acid; 1,4-di(diphenylphosphino)-butane; bis(dibenzylideneacetone)-palladium(0) In tetrahydrofuran at 60℃; for 0.5h; effect of temperature on deprotection of various primary and secondary allylamines;100%
With Thiosalicylic acid; 1,4-di(diphenylphosphino)-butane; bis(dibenzylideneacetone)-palladium(0) In tetrahydrofuran at 60℃; for 0.5h;100%
With polymethylhydrosiloxane; zinc(II) chloride; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 20℃;92%
With 1,3-bis[(diphenylphosphino)propane]dichloronickel(II); diisobutylaluminium hydride In toluene for 1h; Ambient temperature;66%
4383-26-0

N,N-di-2-propenylbenzylamine

100-46-9

benzylamine

Conditions
ConditionsYield
With Thiosalicylic acid; 1,4-di(diphenylphosphino)-butane; bis(dibenzylideneacetone)-palladium(0) In tetrahydrofuran at 60℃; for 0.5h;100%
With 1,3-bis[(diphenylphosphino)propane]dichloronickel(II); diisobutylaluminium hydride In toluene for 1h; Ambient temperature;79%
42116-44-9

N-tert-butoxycarbonylbenzylamine

100-46-9

benzylamine

Conditions
ConditionsYield
With methanol; Acetyl bromide In dichloromethane at 25℃; for 0.333333h;100%
With 3-butyl-l-methyl-1H-imidazol-3-iumtrifloroacetate In 1,4-dioxane; water at 80 - 82℃; for 4h;98%
With nitric acid In dichloromethane at 0℃; for 1h;95%

N-benzyl-2,4-dinitro-benzenesulfonamide

A

3165-76-2

S-(2,4-Dinitrophenyl)-cystein

B

7446-09-5

sulfur dioxide

C

100-46-9

benzylamine

Conditions
ConditionsYield
In aq. phosphate buffer for 0.5h; pH=7.4;A n/a
B 100%
C n/a
52826-45-6

(benzylimino)triphenylphosphorane

100-46-9

benzylamine

Conditions
ConditionsYield
With phenylsilane In toluene at 111℃; for 12h;100%
100-52-7

benzaldehyde

100-46-9

benzylamine

Conditions
ConditionsYield
With ammonia; hydrogen In methanol at 90℃; under 15001.5 Torr; for 4h; Solvent; Temperature; Pressure; Autoclave;99.7%
With Candida boidinii formate dehydrogenase; Geobacillus stearothermophilus ε‐deaminating L‐lysine dehydrogenase variant 1; nicotinamide adenine dinucleotide In aq. buffer at 30℃; for 24h; pH=8.5; Reagent/catalyst; Enzymatic reaction;99%
With ammonium hydroxide; hydrogen In ethanol at 130℃; under 7500.75 Torr; for 12h; Autoclave;96.9%
1576-37-0

N-benzyl-p-toluenesulfonamide

100-46-9

benzylamine

Conditions
ConditionsYield
Stage #1: N-benzyl-p-toluenesulfonamide With n-butyllithium In tetrahydrofuran at 0℃;
Stage #2: With naphthalene; lithium In tetrahydrofuran at -78 - 20℃;
99%
Stage #1: N-benzyl-p-toluenesulfonamide With n-butyllithium In tetrahydrofuran at 0℃; for 0.166667h; Inert atmosphere;
Stage #2: With naphthalene; lithium In tetrahydrofuran at -78 - 25℃;
Stage #3: With water In tetrahydrofuran
99%
With naphthalene; water; lithium 1.) THF, -78 deg C, 2 h; Yield given. Multistep reaction;
383865-57-4

4-methoxy-7-morpholin-4-yl-benzothiazol-2-yl-amine

A

1-Benzyl-3-(4-methoxy-7-morpholin-4-yl-benzothiazol-2-yl)-urea

B

100-46-9

benzylamine

Conditions
ConditionsYield
A 99%
B n/a
6343-54-0

N-benzylformamide

100-46-9

benzylamine

Conditions
ConditionsYield
With sodium ethanolate In methanol at 80℃; for 2h;99%
With sodiumsulfide nonahydrate In water at 100℃; for 12h;86%
Multi-step reaction with 2 steps
1: 3 h / Reflux
2: triphenylphosphine; triethylamine / dichloromethane; tetrachloromethane / 4 h / Reflux; Inert atmosphere
View Scheme
622-42-4

1-nitro-1-phenylmethane

100-46-9

benzylamine

Conditions
ConditionsYield
With 5%-palladium/activated carbon; hydrogen; ammonium formate In methanol under 2068.65 Torr; Flow reactor;98%
With palladium on activated charcoal; tetrabutylammomium bromide; water; sodium hydroxide; silicon at 100℃; for 6h; Reagent/catalyst;94%
With hydrazine hydrate In dichloromethane at 20℃; for 1h;71%
122954-29-4

benzylammonium O-ethylstyrylphosphonate

A

5849-49-0

styrylphosphonic acid ethylester

B

100-46-9

benzylamine

Conditions
ConditionsYield
With sodium hydroxide at 20℃; for 0.5h;A 98%
B 83%
3378-73-2

1-phenyl-N-tritylethanamine

100-46-9

benzylamine

Conditions
ConditionsYield
With ammonium cerium (IV) nitrate; water; acetic acid In dichloromethane at 20℃; for 7.5h; Inert atmosphere;98%
With water; ytterbium(III) triflate In tetrahydrofuran at 20℃; Product distribution; Further Variations:; Catalysts; Reagents; Hydrolysis;93%
54535-21-6

2-(benzylamino-methylene)-malonic acid diethyl ester

100-46-9

benzylamine

Conditions
ConditionsYield
With ethylenediamine In ethanol at 20℃; for 0.75h;98%

N-benzyl-3,3-dimethoxypropylsulfonamide

100-46-9

benzylamine

Conditions
ConditionsYield
Stage #1: N-benzyl-3,3-dimethoxypropylsulfonamide With p-toluenesulfonic acid monohydrate In water; acetone at 0 - 20℃; for 6h;
Stage #2: With sodium hydroxide In methanol; water; acetone at 0 - 20℃; for 1.08333h;
98%
932-90-1

Benzaldoxime

100-46-9

benzylamine

Conditions
ConditionsYield
With sodium hydrogensulfate monohydrate; molybdenum(V) chloride; sodium cyanoborohydride In N,N-dimethyl-formamide for 1.5h; Reflux;96%
With sodium tetrahydroborate at 20℃; for 0.0333333h; neat (no solvent, solid phase);94%
With iron oxide; zirconium(IV) chloride; sodium cyanoborohydride In neat (no solvent) at 75 - 80℃; for 0.25h; Reagent/catalyst; Temperature;93%
100-51-6

benzyl alcohol

100-46-9

benzylamine

Conditions
ConditionsYield
With sodium azide; triphenylphosphine In dichloromethane; N,N-dimethyl-formamide at 90℃; for 4h; Substitution; Mitsunobu reaction; Staudinger reaction;96%
With ammonia In toluene at 110℃; under 5250.53 Torr; for 20h;91%
With (carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II); ammonia; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In tert-Amyl alcohol at 140℃; for 20h; Inert atmosphere; Cooling;87%
33148-47-9

4-allyloxy-benzonitrile

A

60758-84-1

4-cyanophenyl propyl ether

B

100-46-9

benzylamine

Conditions
ConditionsYield
With hydrogen; palladium on activated charcoal; ethylenediamine In tetrahydrofuran at 20℃; for 24h; atmospheric pressure;A 96%
B n/a
100-39-0

benzyl bromide

100-46-9

benzylamine

Conditions
ConditionsYield
With 5-methyl-1,3,4-thiadiazol-2-amine; triethylamine In ethanol; water at 25℃; for 1h;96%
Multi-step reaction with 2 steps
1.1: n-butyllithium / tetrahydrofuran / Inert atmosphere
1.2: 8 h / Inert atmosphere
1.3: 2 h / 60 °C / Inert atmosphere
2.1: titanium(III) chloride; water / tetrahydrofuran / pH 10 / Reflux; Alkaline aq. solution; Inert atmosphere
View Scheme
Multi-step reaction with 2 steps
1: potassium carbonate / N,N-dimethyl-formamide / 3 h / 80 °C
2: hydrogenchloride / water / 3 h / 100 °C
View Scheme
Multi-step reaction with 2 steps
1.1: potassium carbonate / 1 h / Milling
1.2: 1 h / Milling
2.1: ethylenediamine / neat (no solvent) / Milling
View Scheme
5817-70-9

methyl N-benzylcarbamate

A

67-56-1

methanol

B

100-46-9

benzylamine

Conditions
ConditionsYield
With C25H19BrMnN2O2P; potassium tert-butylate; hydrogen In toluene at 130℃; under 15001.5 Torr; for 48h;A 98 %Spectr.
B 96%
7387-69-1

N-benzyl-2,2,2-trifluoroacetamide

100-46-9

benzylamine

Conditions
ConditionsYield
With potassium hydroxide at 20℃; for 0.25h;95%
5001-26-3

2-hydroxy-N-(benzyl)benzylamine

A

C21H18O3

B

100-46-9

benzylamine

Conditions
ConditionsYield
at 220℃; under 10 Torr; for 0.0833333h; Product distribution; pyrolysis without solvent, isolated as sulfate;A n/a
B 95%

1-naphthylmethyl N-benzyl carbamate

100-46-9

benzylamine

Conditions
ConditionsYield
With ammonium formate; 1,2-bis-(diphenylphosphino)ethane; bis(dibenzylideneacetone)-palladium(0) In dimethyl sulfoxide at 80℃; for 12h; deprotection;95%
2621-78-5

ethyl N-benzylcarbamate

100-46-9

benzylamine

Conditions
ConditionsYield
With ammonium bromide; 3-azapentane-1,5-diamine at 110℃; for 5h; Temperature; Microwave irradiation;95%
2142-01-0

N-benzylphthalimide

A

612-14-6

phthalyl alcohol

B

100-46-9

benzylamine

Conditions
ConditionsYield
With [RuCl2(2-(diphenylphosphino)-N-((6-((diphenylphosphino)methyl)pyridin-2-yl)methyl)ethan-1-amine)]; potassium tert-butylate; hydrogen In tetrahydrofuran at 100℃; under 37503.8 Torr; for 20h; Catalytic behavior; Autoclave; chemoselective reaction;A 95%
B 87%
With C25H19BrMnN2O2P; potassium tert-butylate; hydrogen In tetrahydrofuran at 130℃; under 22502.3 Torr; for 48h; Mechanism; Inert atmosphere; Glovebox; Autoclave; Green chemistry;A 94%
B 92%
With [Ru(PtBuNNHtBu)H(CO)Cl]; potassium tert-butylate; hydrogen In tetrahydrofuran at 110℃; under 15001.5 Torr; for 24h; Autoclave;
With C25H19BrMnN2O2P; potassium tert-butylate; hydrogen In 1,4-dioxane at 130℃; under 22502.3 Torr; for 48h; Catalytic behavior; Solvent; Reagent/catalyst; Pressure; Inert atmosphere; Glovebox; Autoclave; Green chemistry;A 92 %Spectr.
B 97 %Spectr.
100-44-7

benzyl chloride

100-46-9

benzylamine

Conditions
ConditionsYield
With copper(ll) sulfate pentahydrate; ammonium hydroxide In PEG1000-DIL; methyl cyclohexane at 60℃; for 3h;94%
With 5-methyl-1,3,4-thiadiazol-2-amine; triethylamine In ethanol; water at 25℃; for 1h; Reagent/catalyst;94%
With hydrogenchloride; potassium hydride; 1,1,3,3-tetramethyldisilazane In tetrahydrofuran at 0 - 25℃; multistep selective monoamination reaction of various alkyl halides;88%
119592-74-4

N-benzyl-2,2,6,6-tetramethyl-2,6-disilapiperidine

100-46-9

benzylamine

Conditions
ConditionsYield
In hydrogenchloride for 8h; Heating;94%
674-82-8

4-methyleneoxetan-2-one

100-46-9

benzylamine

882-36-0

N-benzyl-3-oxobutanamide

Conditions
ConditionsYield
In dichloromethane at 0 - 20℃;100%
In dichloromethane at 0 - 20℃;100%
In dichloromethane at 0 - 20℃;100%
96-48-0

4-butanolide

100-46-9

benzylamine

19340-88-6

N-benzyl-4-hydroxybutanamide

Conditions
ConditionsYield
With bis(trifluoromethane)sulfonimide lithium In chloroform at 85℃; for 40h;100%
Stage #1: benzylamine With diisobutylaluminium hydride In tetrahydrofuran; toluene
Stage #2: 4-butanolide In tetrahydrofuran at 20℃; for 0.5h;
98%
In benzene for 12h; Reflux;98%
98-01-1

furfural

100-46-9

benzylamine

4393-11-7

N-benzyl-1-(furan-2-yl)methanimine

Conditions
ConditionsYield
With copper(II) bis(trifluoromethanesulfonate) In water at 20℃; for 0.0166667h;100%
In water at 20℃; for 2h;93%
In dichloromethane Inert atmosphere; Molecular sieve;81%
286-20-4

cyclohexane-1,2-epoxide

100-46-9

benzylamine

Conditions
ConditionsYield
bismuth(lll) trifluoromethanesulfonate at 160℃; for 0.25h; microwave irradiation;100%
at 150℃; Neat (no solvent);99%
With zinc(II) perchlorate hexahydrate at 80℃; for 1h;97%
3282-30-2

pivaloyl chloride

100-46-9

benzylamine

26209-45-0

N-benzyl-2,2-dimethylpropanamide

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine In acetonitrile at 25℃; for 1h;100%
With triethylamine In dichloromethane at 0 - 20℃; for 4h; Inert atmosphere;100%
With 1-methyl-1H-imidazole In dichloromethane at 0℃; Inert atmosphere;99%
108-94-1

cyclohexanone

100-46-9

benzylamine

4383-25-9

N-benzylcyclohexylamine

Conditions
ConditionsYield
With formic acid; Cp*IrCl(N-(phenyl(pyridin-2-yl)methyl)methanesulfonamide)complex In ethyl acetate at 40℃; for 18h; Reagent/catalyst; Inert atmosphere;100%
Stage #1: cyclohexanone; benzylamine With formic acid; chlorido(8-quinolinolato-k2N,O)(η5-pentamethylcyclopentadienyl)iridium(III) In ethyl acetate at 0 - 40℃; Inert atmosphere; Schlenk tube; Cooling with ice;
Stage #2: With sodium hydrogencarbonate In water; ethyl acetate Product distribution / selectivity;
98%
With 4 A molecular sieve; borane pyridine complex In methanol for 16h;96%
104-87-0

4-methyl-benzaldehyde

100-46-9

benzylamine

24431-15-0

N-benzyl-p-tolylmethanimine

Conditions
ConditionsYield
In chloroform at 20℃; for 1h;100%
for 6h; Kinetics; Molecular sieve; Reflux;100%
With magnesium sulfate In dichloromethane at 20℃; Inert atmosphere;65%
104-88-1

4-chlorobenzaldehyde

100-46-9

benzylamine

130517-96-3, 13540-93-7

N-(4-chlorobenzylidene)benzylamine

Conditions
ConditionsYield
for 6h; Molecular sieve; Reflux;100%
In ethanol at 20℃;94%
In dichloromethane at 20℃; for 16h; Molecular sieve;92%
623-27-8

terephthalaldehyde,

100-46-9

benzylamine

20941-14-4

1,4-bis(benzyliminomethyl)benzene

Conditions
ConditionsYield
In methanol at 20℃;100%
In methanol at 20℃;80%
622-78-6

Benzyl isothiocyanate

100-46-9

benzylamine

1424-14-2

dibenzyl thiourea

Conditions
ConditionsYield
In hexane at 20℃; for 2h;100%
In dichloromethane at 20℃;98%
In chloroform for 0.5h; Heating;88%
100-52-7

benzaldehyde

100-46-9

benzylamine

780-25-6

N-benzylidene benzylamine

Conditions
ConditionsYield
In toluene at 120℃; for 24h;100%
With magnesium sulfate In dichloromethane for 3h; Reflux;100%
With aluminum oxide at 20℃; for 2.5h;99%
123-11-5

4-methoxy-benzaldehyde

100-46-9

benzylamine

622-72-0

N-(4-methoxylbenzylidene)benzylamine

Conditions
ConditionsYield
In chloroform at 20℃; for 1h;100%
With sodium sulfate In dichloromethane at 20℃;99%
In chloroform at 20℃; for 1h;96.8%
98-88-4

benzoyl chloride

100-46-9

benzylamine

1485-70-7

N-benzylbenzamide

Conditions
ConditionsYield
In tetrahydrofuran at 20℃;100%
With sodium hydroxide In 1,2-dimethoxyethane; water at 25℃; for 0.5h; pH 10.45;99%
Stage #1: benzoyl chloride; benzylamine With triethylamine In dichloromethane at 20℃; for 0.333333h;
Stage #2: With poly{trans-bicyclo[2.2.1]hept-5-ene-2,3-di(chlorocarbonyl)} In dichloromethane at 20℃; for 0.5h;
99%
103-72-0

phenyl isothiocyanate

100-46-9

benzylamine

726-25-0

1-benzyl-3-phenylthiourea

Conditions
ConditionsYield
In acetonitrile at 20℃; for 3h;100%
In acetonitrile at 25℃; for 0.166667h; Milling;99%
With C64H52CaN6 In neat (no solvent) at 60℃; for 12h; Schlenk technique; Glovebox; Inert atmosphere;98%
100-46-9

benzylamine

6343-54-0

N-benzylformamide

Conditions
ConditionsYield
With Iron(III) nitrate nonahydrate In toluene for 2h; Concentration; Reflux;100%
With H-β-zeolite In neat (no solvent) at 80℃; for 24h; Green chemistry;99%
at 20 - 120℃; for 15h;99%
78-84-2

isobutyraldehyde

100-46-9

benzylamine

22483-21-2

isobutylidenebenzylamine

Conditions
ConditionsYield
With magnesium sulfate In dichloromethane at 20℃; Inert atmosphere;100%
With aluminum oxide at 20℃; for 7h;90%
In water Condensation;65.12%
292638-85-8

acrylic acid methyl ester

100-46-9

benzylamine

23574-01-8

3-benzylamino-propionic acid methyl ester

Conditions
ConditionsYield
at -40℃; for 12h;100%
With [HP(HNCH2CH2)3N]NO3 In acetonitrile at 20℃; for 48h; Michael addition;98%
copper In methanol at 20℃; for 0.3h; Aza-Michael Addition;98%
292638-85-8

acrylic acid methyl ester

100-46-9

benzylamine

793-19-1

bis(2-methoxycarbonylethyl)benzylamine

Conditions
ConditionsYield
In methanol at 20℃; for 8h; Reflux;100%
In methanol Reflux;99%
In methanol at 34℃; for 72h; Inert atmosphere;99%
79-04-9

chloroacetyl chloride

100-46-9

benzylamine

2564-06-9

N-benzyl-2-chloroacetamide

Conditions
ConditionsYield
In dichloromethane100%
With triethylamine In dichloromethane at 0 - 20℃; for 4h; Inert atmosphere;98%
With potassium carbonate In dichloromethane Heating;97%
598-21-0

2-Bromoacetyl bromide

100-46-9

benzylamine

2945-03-1

N-benzyl-2-bromoacetamide

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran at 20℃; for 2h;100%
With N-ethyl-N,N-diisopropylamine In dichloromethane at 0 - 20℃; for 16h;99%
In dichloromethane at 0 - 20℃; for 0.5h; Inert atmosphere;98%
98-09-9

benzenesulfonyl chloride

100-46-9

benzylamine

837-18-3

N-benzylbenzenesulfonamide

Conditions
ConditionsYield
With triethylamine In dichloromethane 1) 0 deg C, 1 h, 2) room temperature;100%
With sodium hydroxide In water at 25℃; for 2h; pH 9.6;99.9%
With Fe3O4-supported (diisopropylamino)acetamide In dichloromethane at 25℃;98%
98-59-9

p-toluenesulfonyl chloride

100-46-9

benzylamine

1576-37-0

N-benzyl-p-toluenesulfonamide

Conditions
ConditionsYield
With triethylamine In dichloromethane at 4℃;100%
With pyridine; dmap In dichloromethane at 0 - 20℃; for 16h;99%
With triethylamine at 20℃; for 1h; Inert atmosphere;99%
3173-56-6

benzyl isothiocyanate

100-46-9

benzylamine

1466-67-7

1,3-dibenzylurea

Conditions
ConditionsYield
In tetrahydrofuran at 10 - 35℃; for 16h;100%
In dichloromethane at 5℃; for 0.5h;99%
Multistep reaction;96%
75-15-0

carbon disulfide

100-46-9

benzylamine

1424-14-2

dibenzyl thiourea

Conditions
ConditionsYield
at 100℃; for 12h; Ionic liquid; Green chemistry;100%
aluminum oxide; zinc(II) oxide at 100℃; for 2h; Condensation;98%
In water at 20℃; for 1.33333h; Solvent; Time; Green chemistry;97%
1013-88-3

Benzophenone imine

100-46-9

benzylamine

7699-79-8

benzhydrylidene-benzyl-amine

Conditions
ConditionsYield
In chloroform at 20℃; for 288h;100%
In dichloromethane for 13h; Inert atmosphere; Reflux;98.3%
In dichloromethane for 13h; Reflux; Inert atmosphere;95.3%
64-18-6

formic acid

100-46-9

benzylamine

6343-54-0

N-benzylformamide

Conditions
ConditionsYield
With sodium hydrogencarbonate; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; ethyl cyanoglyoxylate-2-oxime In water; N,N-dimethyl-formamide at 20℃; for 3h; Reagent/catalyst; Solvent;100%
With 4-methyl-morpholine; dmap; 2-chloro-4,6-dimethoxy-1 ,3,5-triazine In dichloromethane at 35℃; for 0.1h; microwave irradiation;99%
With sulfated tungstate at 70℃; for 0.166667h; Neat (no solvent);99%
54221-37-3

diethyl meso-2,5-dibromoadipate

100-46-9

benzylamine

17740-40-8

diethyl meso-1-benzyl-2,5-pyrrolidinedicarboxylate

Conditions
ConditionsYield
In toluene for 4h; Reflux;100%
97-65-4

2-methylenesuccinic acid

100-46-9

benzylamine

5733-86-8

1-benzyl-5-oxopyrrolidine-3-carboxylic acid

Conditions
ConditionsYield
at 130℃; Inert atmosphere;100%
86%
at 130℃; for 2.5h; Inert atmosphere;82.9%
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    FOB Price:  USD $ 0.0-0.0/Kilogram

    • 1.Cooperate with research institutions, we strictly control the process from raw material to finished product. • 2.The customer comes first, we provide reasonable price, high quality product and prompt shipment. • 3.

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     China (Mainland)  |  Contact Details

    Business Type:Manufacturers

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    Business Type:Lab/Research institutions

    Tel:+86-571-88938639

    Address:9/F, Unit 2 Changdi Torch Building, 259# WenSan Road, Xihu District, Hangzhou City 310012, P.R.China

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    100-46-9

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    Hangzhou Dingyan Chem Co., LTD. is located in the beautiful tourist city of hangzhou, is a comprehensive chemical enterprice which doing import and export business by its own comp

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     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:86-571-86465881,86-571-87157530,86-571-88025800

    Address:RM.1118,NO.1 Building, Baiyun Tower,Jianggan Area, Hangzhou city, China,310004

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    100-46-9

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    Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

    Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional

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     China (Mainland)  |  Contact Details

    Business Type:Manufacturers

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    Address:21/F Hualong Office Building,No.6 Hubin East Road, Xiamen,China

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    Founded in 2011, Amadis Chemical Company Limited is an innovative manufacturer of chemical products and technical service providers. Our business includes sales, manufacture, and s

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     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

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    100-46-9

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    Chemwill Asia co.,Ltd is one of the leading manufacturer in CHINA.Our main production base is located in Xuzhou industry park. We produce a wide range of organics including Active pharmaceutical ingredients(APIs), Veterinary, Indole derivatives, Aro

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     China (Mainland)  |  Contact Details

    Business Type:Manufacturers

    Tel:021-51086038

    Address:High-Tech Industrial park,Chemical Economical Development Zone,Xuzhou, Jiangsu-Province, P.R.China

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    100-46-9

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    Welcome to Henan Sinotech! Sinotech Corporation has exceptional sourcing ability for chemicals used in Organic Fine Chemicals and APIs; Inorganic chemicals; Flame Retardants;OLED

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     China (Mainland)  |  Contact Details

    Business Type:Other

    Tel:86-371-86181678

    Address:No. 260, Dongming Road,Jinshui District

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    100-46-9

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     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:86-371-55170693/55170694

    Address:Zhengzhou International Trade New Territory,Jinshui District,Zhengzhou ,China

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    100-46-9

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    Business Type:Lab/Research institutions

    Tel:+86-25-58409506

    Address:11F, Building A1, No.288 North Zhongshan Road, Gulou District, Nanjing,210003, P.R.China.

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    100-46-9

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    Shijiazhuang Sdyano Fine Chemical Co., Ltd. is a company specializing in pharmaceutical intermediates, liquid crystal intermediates, PDLC LCD, OLED LCD, such as fine chemicals R &a

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     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:+86-311-89830448

    Address:Room 37-2-2501, Yiyuan Dong Gang Jianshe Nan Street

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    100-46-9

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     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:86-917-3909592

    Address:China

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    Our Service: 1. Best quality in your requirement 2. Competitive price in china market 3. Mature technical support 4. Professional logistic support 5 . Full experience of large numberscontainers loading in chinese sea port 6 .Fast

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     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:+8613397160123

    Address:13th Floor, Tower B, Century Plaza, Zhongnan Road, Wuchang District, Wuhan, China.

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    100-46-9

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    Product Name: Benzylamine Synonyms: Moringine;moringine[qr];omega-Aminotoluene;omega-aminotoluene[qr];Sumine 2005;sumine2005;sumine2006;BZA CAS: 100-46-9 MF:

    Hebei Guanlang Biotechnology Co., Ltd. belongs to Guanlang Group,which was founded in 2007 , located in Shijiazhuang city which is the capital of Hebei Province and hub sector amon

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     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:+8619930503256

    Address:No.66, Yuhua West Road

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    100-46-9

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    Changzhou Xuanming Chemical Co., Ltd. is dedicated to the technology development, manufacturing, import and export chemicals, which are specialized in pharmaceutical intermediates, pesticide intermediate, industry of fine chemicals and custom synt

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     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:86 0519 85525329

    Address:China Town, Xinbei, Changzhou, Jiangsu Room 6019

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  • Benzylamine

  • Casno:

    100-46-9

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    Min.Order: 200 Kilogram

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    QINGDAO ON-BILLION INDUSTRIAL CO.,LTD was established in 2004 with registered capital RMB 26 million. (Former Qingdao on-billion imp&exp co.,ltd was founded in 1993 ) Awarded as E

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     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:+86-15005320811 +86-532-80681989

    Address:F35 Parkson Mansion No.44-60 Zhongshan Rd.

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    100-46-9

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    We, Jilin Tely Imp & Exp Co., Ltd. mainly supply and export products including: pharmaceutical raw materials,Chemical reagents, Food additives, pharmaceutical and pesticide interme

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     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:+86-0431-81915458

    Address:Room 302, 47 Changping Street, Chaoyang District, Changchun, Jilin Province,China

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     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:+86-371-86658258

    Address:Building 3 of Innovation Park, East District of the National University Science Park

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    100-46-9

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    1. Subsidiary of Institute of Chemistry, Henan Academy of Sciences, national research platform;2. About 30 years’ experience in this field since 1983;3. An experienced R&D team consisting of Doctors and Masters;4. Various types of analytical instrume

    Zhengzhou Kingorgchem Chemical Technology Co., Ltd. was founded on the basis of Organophosphorus Chemistry Lab of Institute of Chemistry Henan Academy of Sciences in 2015. The

  •  Zhengzhou Kingorgchem Chemical Technology Co., Ltd.

     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:+86-371-65511936

    Address:NO.56,Hongzhuan Road

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    100-46-9

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    Hebei Mojin Biotechnology Co., Ltd, Our company is a professional in lead acetate, diphenyl ethylamine and other chemical raw materials and chemical reagents research and development production enterprises. Our business covers more than 30 countrie

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     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:13231137666

    Address:room 1401,A building,Enjoy city,shijiazhuang city,hebei province,China

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  • Casno:

    100-46-9

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    Min.Order: 100 Metric Ton

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    Appearance:white powder Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Aripiprazole Intermediate Transportation:Common products:Sea/Air/Courier Dangerous Chem:Se

    Triumph International Development Limilted is engaged in the API, pharmaceutical intermediates research and developmen.Adhering to the "customer first" business philosophy,we suppl

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    China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:+86-536-7971999

    Address:Yinhai Road,Shouguang

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    100-46-9

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    Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

    Shandong Hanjiang Chemical Co., Ltd. is located in Qilu Petrochemical Industrial Park, Zibo City, Shandong Province, involving pesticide, medicine, chemical industry, coating, dy

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     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:18369939125

    Address:95A, Xingyuan East Road, Zhangdian District

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    100-46-9

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    J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

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  •  Hangzhou J&H Chemical Co., Ltd.

     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:+86-571-87396432

    Address:No.200 Zhenhua Rd.Xihu Industrial Park, Hangzhou 310030, China

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    100-46-9

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    FOB Price:  USD $ 1.0-1.0/Gram

    Qingdao Sigma Chemical Ltd is is a global chemical industry manufacturers and suppliers of pharmaceuticals and intermediates, peptide,Nootropis etc API, food and feed additives, herbal extracts, agrochemicals and fine chemicals etc. Our Labo

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     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:0532-80916960

    Address:shandong qingdao

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    100-46-9

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    Min.Order: 1 Kilogram

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    Our advantages: 1, High quality with competitive price: 2, Fast and safe delivery 3.Excellent pre-sales and after-sales service 4. Well-trained and professional technologist and sales with rich experience in the field for 5-10 years Appearanc

    Hangzhou Clap Technology Co., Ltd is a leading manufacturer and supplier of API, Pharma intermediates, organic and inorganic compounds, rare earth, pesticide, raw drugs, fine chemi

  •  HANGZHOU CLAP TECHNOLOGY CO,.LTD

     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:86-571-56972507

    Address:Room 4198,Floor 4,No.4,ShanXian Road XiaCheng District,HangZhou city,ZheJiang province,China

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    100-46-9

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    Min.Order: 1 Kilogram

    FOB Price:  USD $ 100.0-100.0/Kilogram

    HangYu Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. HangYu Chemical consis

    Zibo HangYu Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals

  •  Zibo Hangyu Import&Export Co., Ltd

    China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:86-15988566987

    Address:Room1701, Tianxing Building,Licheng district, jinan, Shandong, China

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    100-46-9

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    Min.Order: 1 Gram

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    Superiority: Zhejiang J&C Biological Technology Co., Limited is specialized in the production of high complex new type intermediates and chemical custom synthesis, scale-up production and rare chemicals trade. Products category is including I

    ZHEJIANG BIOLOGY AND TECHNOLOGY CO., LTD. is a modern professional high-tech enterprise, which is specializing in generic APIs and pharmaceutical intermediates. especially in pepti

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    China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:0570-4045877

    Address:46# zhongshan road, quzhou zhejiang

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    100-46-9

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    Min.Order: 1 Kilogram

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    BaiFuChem is a Professional chemical raw material supplier in China, our main products include Biochemical , Pharma Intermediate and Organic chemical etc. BaiFuChem have wealth of products,experience , expertise and state-of-the-art

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  •  Xiamen BaiFuchem Co.,Ltd

     China (Mainland)  |  Contact Details

    Business Type:Other

    Tel:+86 592 605 6448

    Address:No.31 Pingshan South Road, HaiCang District, Xiamen, China

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    100-46-9

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    Min.Order: 1 Gram

    FOB Price:  USD $ 1.0-2.0/Gram

    span lang="EN-US" style="font-size: 9.0pt;font-family:"Arial",sans-serif;color:#4D4D4D">As a leading manufacturer and supplier of chemicals in china, weckchem not only supply popular chemicals, but also weckchem’s r&d center off

    Hangzhou Weckchem Co.,Ltd, located in Hangzhou,China, is specialized in Green chemicals and Fine chemicals over 10 years. Our main products are used in Fuel oil, Water treatment an

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     China (Mainland)  |  Contact Details

    Business Type:Other

    Tel:86-15158040660

    Address:Xiaoshan district

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    100-46-9

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    Min.Order: 1 Gram

    FOB Price:  USD $ 2.0-2.0/Gram

    We are leading fine chemicals supplier in China with ISO certificate, Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED

    The company is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds,

  •  Henan Wentao Chemical Product Co., Ltd.

     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:+86-370-2722992

    Address:32 Room, 5th Floor, Building 11, No. 6 Yinxing Road, High-tech Industrial Development Zone, Zhengzhou City, Henan Province

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    Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service and

    Located in Hangzhou National Hi-Tech Industrial Development Zone, Hangzhou zhongqi chem co.,Ltd is an ISO 9001:2015 & SGS certified molden chemical company,who is mainly focus on t

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     China (Mainland)  |  Contact Details

    Business Type:Other

    Tel:0086-571-86976032

    Address:Kangkang Gu 1010, Chun xiao road 61,Binjiang District 310052,Hangzhou city , China

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    100-46-9

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    Product name: Benzylamine CAS No.:100-46-9 Molecule Formula:C7H9N Molecule Weight:107.1551 Purity: 99.0% Package: 200kg/drum Description:Colorless transparent liquid Manufacture Standards:Enterprise Standard TESTIN

    Siwei Development Group Ltd. is a reputed professional enterprise in China dedicated to the Amino Acids production and sales of fine chemical products.Over the years we have been m

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    China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:86-571-82881840

    Address:Rm2-2-503 Zhongdingyuan, Xianghurenjia Wenyan Xiaoshan, Hangzhou China

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Chemistry

Molecular Structure of Benzylamine (CAS NO.100-46-9):

IUPAC Name: phenylmethanamine
Molecular formula: C7H9N
Molecular Weight:107.15
H bond acceptors: 1
H bond donors: 2
Freely Rotating Bonds: 2
Polar Surface Area: 3.24 Å2
Index of Refraction: 1.547
Molar Refractivity: 34.7 cm3
Molar Volume: 109.4 cm3
Surface Tension: 38.8 dyne/cm
Density: 0.979 g/cm3
Flash Point: 60 °C
Enthalpy of Vaporization: 42.12 kJ/mol
Boiling Point: 185 °C at 760 mmHg
Vapour Pressure: 0.713 mmHg at 25°C
EINECS: 202-854-1
Melting point: -30 °C
Product Categories: Pharmaceutical Intermediates; Organics
InChI
InChI=1/C7H9N/c8-6-7-4-2-1-3-5-7/h1-5H,6,8H2
Smiles
c1(ccccc1)CN

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mammal (species unspecified) LD50 oral 700mg/kg (700mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 39(4), Pg. 86, 1974.
mouse LD50 intraperitoneal 600mg/kg (600mg/kg)   United States Patent Document. Vol. #3816470,

Safety Profile

The Hazard Codes:  C
The Risk Statements information:
34:  Causes burns
21/22:  Harmful in contact with skin and if swallowed 
The Safety Statements information:
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice  
45:  In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
36/37/39:  Wear suitable protective clothing, gloves and eye/face protection  
RIDADR: UN 2735 8/PG 2

Specification

  Benzylamine , with CAS number of 100-46-9, can be called .alpha.-Aminotoluene ; (Aminomethyl)benzene ; (Phenylmethyl)amine ; Benzenemethanamine ; Moringine ; alpha-Aminotoluene . Benzylamine (CAS NO.100-46-9) consists of a benzyl group, attached to an amine functional group. This colorless liquid is a common precursor in organic synthesis.