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10030-85-0

Basic Information
CAS No.: 10030-85-0
Name: L(+)-Rhamnose monohydrate
Molecular Structure:
Molecular Structure of 10030-85-0 (L(+)-Rhamnose monohydrate)
Formula: C6H14O6
Molecular Weight: 182.174
Synonyms: (2R,3R,4S,5S)-2,3,4,5-Tetrahydroxyhexanal hydrate;(2R,3R,4S,5S)-2,3,4,5-Tetrahydroxyhexanalhydrat;6-Deoxy-L-mannose hydrate (1:1);6-Deoxy-L-mannose hydrate;
EINECS: 222-793-4
Density: 1.47 g/cm3
Melting Point: 90-95 °C(lit.)
Boiling Point: 323.9 °C at 760 mmHg
Flash Point: 149.7 °C
Solubility: water: 0.1 g/mL, clear, colorless
Appearance: White crystals or crystalline powder
Hazard Symbols: IrritantXi
Risk Codes: 36/38
Safety: 24/25-37/39-26
Transport Information: N/A
PSA: 107.22000
LogP: -2.41550
Synthetic route
2213-43-6

1-Aminopiperidine

10030-85-0

L-rhamnose monohydrate

(2S,3S,4S,5S)-1-(piperidin-1-ylimino)hexane-2,3,4,5-tetrol

Conditions
ConditionsYield
In methanol for 3.75h; Reflux;83%
10030-85-0

L-rhamnose monohydrate

16596-41-1

N-aminopyrrolidine

(2S,3S,4S,5S)-1-(pyrrolidin-1-ylimino)hexane-2,3,4,5-tetrol

Conditions
ConditionsYield
In methanol for 2.5h; Reflux;80%
5906-35-4

1-azepanylamine

10030-85-0

L-rhamnose monohydrate

(2S,3S,4S,5S)-1-(azepan-1-ylimino)hexane-2,3,4,5-tetrol

Conditions
ConditionsYield
In methanol for 3.25h; Reflux;74%
10030-85-0

L-rhamnose monohydrate

14807-05-7

6-deoxy-L-arabino-2-hexulose

Conditions
ConditionsYield
In pyridine for 5h; Heating;63%
2425-77-6

2-hexyldecan-1-ol

10030-85-0

L-rhamnose monohydrate

2-hexyldecyl 6-deoxy-L-mannopyranoside

Conditions
ConditionsYield
With sodium hydrogencarbonate In ethyl acetate48%
10030-85-0

L-rhamnose monohydrate

A

35867-45-9

6-deoxy-L-glucose

B

14807-05-7

6-deoxy-L-arabino-2-hexulose

C

1026722-79-1

6-deoxy-L-ribo-hexulose

Conditions
ConditionsYield
With pyridine for 5h; Product distribution; Heating; variation of time;A 5%
B 34%
C 3%
5333-42-6

2-octyldodecan-1-ol

10030-85-0

L-rhamnose monohydrate

2-octyldodecyl 6-deoxy-L-mannopyranoside

Conditions
ConditionsYield
10%
58670-89-6

2-decylteradecanol

10030-85-0

L-rhamnose monohydrate

2-decyltetradecyl 6-deoxy-L-mannopyranoside

Conditions
ConditionsYield
6%
10030-85-0

L-rhamnose monohydrate

72774-23-3, 72774-24-4

6-deoxy-L-fructose 2-nitrophenylhydrazone

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 63 percent / pyridine / 5 h / Heating
2: H2O; ethanol / 0.17 h / Heating
View Scheme
1197-55-3

4-aminophenylacetic acid

10030-85-0

L-rhamnose monohydrate

p-aminophenylacetic acid-N-L-rhamnoside

Conditions
ConditionsYield
With ammonium chloride In ethanol; nitrogen
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Specification

The L-Mannose, 6-deoxy-,hydrate (1:1) with the CAS registry number 10030-85-0 is also known as 6-Deoxy-L-mannosehydrat. Its EINECS registry number is 222-793-4. The IUPAC name is (2R,4S,5R)-6-methyloxane-2,3,4,5-tetrol hydrate. In addition, the molecular formula is C6H14O6 and molecular weight is 182.17. And it is a kind of white crystals or crystalline powder and belongs to the class of Arbohydrates.

Physical properties about L-Mannose, 6-deoxy-,hydrate (1:1) are: (1)# of Rule of 5 Violations: 1; (2)#H bond acceptors: 6; (3)#H bond donors: 6; (4)#Freely Rotating Bonds: 8; (5)Polar Surface Area: 97.99 Å2; (6)Flash Point: 250.5 °C; (7)Enthalpy of Vaporization: 87.23 kJ/mol; (8)Boiling Point: 490.6 °C at 760 mmHg; (9)Vapour Pressure: 1.1E-11 mmHg at 25°C.

Preparation and uses of L-Mannose, 6-deoxy-,hydrate (1:1): this chemical is prepared by sugar ligand which come from sweet orange and other Citrus Branch said extract. In addition, it can be used as biochemical reagents and edible sweeteners.

When you are using this chemical, please be cautious about it as the following:
This chemical is irritating to eyes, skin and may cause inflammation to the skin or other mucous membranes. Therefore, you should wear suitable gloves, eye/face protection and avoid contact with skin and eyes. In addition, in case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1)SMILES: O.O[C@@H]([C@H](C)O)[C@@H](O)[C@@H](O)C=O
(2)InChI: InChI=1/C6H12O5.H2O/c1-3(8)5(10)6(11)4(9)2-7;/h2-6,8-11H,1H3;1H2/t3-,4-,5-,6-;/m0./s1
(3)InChIKey: CBDCDOTZPYZPRO-DEZHIRTDBL

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