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101-90-6

Basic Information
CAS No.: 101-90-6
Name: 2,2'-[1,3-Phenylenebis(oxymethylene)]dioxirane
Article Data: 5
Molecular Structure:
Molecular Structure of 101-90-6 (2,2'-[1,3-Phenylenebis(oxymethylene)]dioxirane)
Formula: C12H14O4
Molecular Weight: 222.241
Synonyms: Benzene,m-bis(2,3-epoxypropoxy)- (6CI,7CI,8CI);1,3-Bis(2,3-epoxypropoxy)benzene;1,3-Diglycidyloxybenzene;Diglycidyl resorcinol ether;NSC 76621;Resorcinolbis(2,3-epoxypropyl) ether;Resorcinol diglycidyl ether;Resorcinol glycidylether;m-Bis(2,3-epoxypropoxy)benzene;m-Bis(glycidyloxy)benzene;
EINECS: 202-987-5
Density: 1.248 g/cm3
Melting Point: 33-35 °C
Boiling Point: 364.338 °C at 760 mmHg
Flash Point: 156.585 °C
Solubility: insoluble in water
Appearance: yellow liquid
Hazard Symbols: HarmfulXn
Risk Codes: 21/22-36/38-40-43-52/53-68
Safety: 23-36/37-61
Transport Information: UN 2811
PSA: 43.52000
LogP: 1.24180
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  • 1,3-Bis(glycidyloxy)benzene

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    1,3-Bis(glycidyloxy)benzene

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Chemistry

The Molecular formula of RESORCINOL DIGLYCIDYL ETHER(101-90-6) : C12H14O4
The Molecular Weight of RESORCINOL DIGLYCIDYL ETHER(101-90-6) : 222.24
Molecular Structure :
EINECS: 202-987-5
Melting point: 33-35°C
Boiling point: 172 °C(lit.)
Flash point: >230 °F
density: 1.21 g/mL at 25 °C(lit.)
refractive index: n20/D 1.542(lit.)
solubility  H2O: insoluble
BRN: 203671
Stability: Stable. Combustible. Incompatible with strong oxidizing agents.
Synonyms: 1,3-Bis(2,3-epoxypropoxy)benzene;2,2'-(1,3-Phenylenebis(oxymethylene))bisoxirane;2,2’-(1,3-phenylenebis(oxymethylene))bis-oxiran;2,2’-[1,3-phenylenebis(oxymethylene)]bis-oxiran;2,2’-[1,3-phenylenebis(oxymethylene)]bis-Oxirane;2,2’-(1,3-phenylenebis(oxymethylene))bisoxirane;1,3-Diglycidyloxybenzene;2-([3-(2-Oxiranylmethoxy)phenoxy]methyl)oxirane;

Toxicity Data With Reference

1.   

skn-rbt 500 mg/24H MOD

   AMIHAB    AMA Archives of Industrial Health. 17 (1958),129.
2.   

mmo-sat 50 µg/plate

   MUREAV    Mutation Research. 135 (1984),159.
3.   

sln-dmg-orl 5 pph

   ENMUDM    Environmental Mutagenesis. 7 (1985),325.
4.   

trn-dmg-orl 5 pph

   ENMUDM    Environmental Mutagenesis. 7 (1985),325.
5.   

cyt-ham:ovr 8 mg/L

   MUREAV    Mutation Research. 135 (1984),159.
6.   

orl-rat LD50:2570 mg/kg

   AMIHAB    AMA Archives of Industrial Health. 17 (1958),129.
7.   

ipr-rat LD50:178 mg/kg

   AMIHAB    AMA Archives of Industrial Health. 17 (1958),129.
8.   

orl-mus LD50:980 mg/kg

   AMIHAB    AMA Archives of Industrial Health. 17 (1958),129.
9.   

ipr-mus LD50:243 mg/kg

   AMIHAB    AMA Archives of Industrial Health. 17 (1958),129.
10.   

orl-rbt LD50:1240 mg/kg

   AMIHAB    AMA Archives of Industrial Health. 17 (1958),129.

Consensus Reports

NTP 10th Report on Carcinogens. IARC Cancer Review: Group 2B IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 ,1987,p. 56.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Sufficient Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 36 ,1985,p. 181.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Inadequate Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 11 ,1976,p. 125.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . NTP Carcinogenesis Studies (gavage); Clear Evidence: mouse, rat NTPTR*    National Toxicology Program Technical Report Series. (Research Triangle Park, NC 27709) No. 206- NTP-TR-257 ,1986. . Reported in EPA TSCA Inventory.

Safety Profile

Confirmed carcinogen with experimental carcinogenic and tumorigenic data. Poison by intraperitoneal route. Moderately toxic by ingestion. Mutation data reported. A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes. See also ETHERS.
The Hazard Codes of RESORCINOL, DIACETATE(108-58-7): Xn
HazardClass: 6.1
PackingGroup: II
The Risk Statements information of RESORCINOL, DIACETATE(108-58-7) 21/22-36/38-40-43-52/53-68
The Safety Statements information of RESORCINOL, DIACETATE(108-58-7) 23-36/37-61
RIDADR: 2811
WGK Germany: 2
RTECS: VH1050000

Standards and Recommendations

DFG MAK: Animal Carcinogen, Suspected Human Carcinogen