CAS No.10170-69-1,MANGANESE CARBONYL Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	10170-69-1
Name:	MANGANESE CARBONYL
Article Data:	218

Formula:	C₁₀Mn₂O₁₀
Molecular Weight:	389.98
Synonyms:	Manganesecarbonyl (6CI);CORM 1;Decacarbonyldimanganese;Decacarbonyldimanganese(0);Dimanganese decacarbonyl;Manganese carbonyl (Mn2(CO)10);Manganesepentacarbonyl dimer;NSC 203018;NSC 22319;
EINECS:	233-445-6
Density:	1.75 g/cm³
Melting Point:	154 ºC
Boiling Point:	80°C/1mm
Flash Point:	80°C/1mm subl.
Solubility:	Soluble in organic solvents. Insoluble in water
Appearance:	yellow crystalline powder
Hazard Symbols:	T
Risk Codes:	23/24/25
Safety:	22-26-36/37/39-45
PSA:	0.00000
LogP:	-2.08000

Synthetic route

: 37504-44-2
(acetonitrile)pentacarbonylmanganese(I) hexafluorophosphate

: 13859-41-1
sodium pentacarbonyl manganate

: 10170-69-1
dimanganese decacarbonyl

Conditions

Conditions	Yield
In tetrahydrofuran Kinetics; byproducts: NaPF6, MeCN; Ar-atmosphere; 0.3 M TBAP, molar ratio Mn-complex cation : Mn-complex anion = 1:1; not isolated, detected by IR spectroscopy;	100%
In tetrahydrofuran byproducts: CH3CN; addn. of 5 mL of 1E-2 M NaMn(CO)5 in THF to 5 mL of 1E-2 M Mn(CO)5(MeCN)PF6 in THF under Ar at 22°C, react. time <5 min; not isolated; monitored by IR;	88%

: 13859-41-1
sodium pentacarbonyl manganate

: 96412-38-3
pentacarbonyl(pyridine)manganese(I) tetrafluoroborate

: 10170-69-1
dimanganese decacarbonyl

Conditions

Conditions	Yield
In tetrahydrofuran Kinetics; byproducts: NaBF4, pyridine; Ar-atmosphere; 0.3 M TBAP, molar ratio Mn-complex cation : Mn-complex anion = 1:1; not isolated, detected by IR spectroscopy;	100%
In tetrahydrofuran NaMn(CO)5 (1.2 M, 5 mL) added under Ar to 5 mL of 1E-2 M Mn(CO)5(C5H5N)BF4, 0.3 M tetra-n-butylammonium perchlorate added, react. time approx. 30 min;

: 52542-59-3, 192520-17-5
bis(triphenylphosphineiminium) pentacarbonylmanganate(1-)

: 124401-76-9
2-methylisoquinolin-2-ium trifluoromethanesulfonate

: 10170-69-1
dimanganese decacarbonyl

Conditions

Conditions	Yield
In tetrahydrofuran react. at 20°C;	100%

: 16972-33-1
pentacarbonylhydridomanganese

: 85317-79-9, 89044-05-3
Li(1+)*Mn2(CO)9(CHO)(1-)=Li(Mn2(CO)9(CHO))

: 639-58-7
triphenyltin chloride

A: 10170-69-1
dimanganese decacarbonyl

B: 14405-84-6
triphenyltinmanganesepentacarbonyl

C: 1333-74-0
hydrogen

Conditions

Conditions	Yield
In tetrahydrofuran under N2, soln. of HMn(CO)5 in THF was cooled to -23°C, added tosoln. of formyl-complex in THF (-23°C), warmed slowly to room temp., Ph3SnCl was added, stirred for 1 h; solvent removed by rotary evapn., vac. sublimed at 60°C, residueeluted through silica gel column with ethyl acetate-hexane;	A 69% B 99% C >90

...Expand

: 52542-59-3, 192520-17-5
bis(triphenylphosphineiminium) pentacarbonylmanganate(1-)

: 105-39-5
chloroacetic acid ethyl ester

A: 10170-69-1
dimanganese decacarbonyl

B: 14100-30-2
pentacarbonylchloromanganese(I)

C: η1-(CH2COOEt) manganese pentacarbonyl

Conditions

Conditions	Yield
In tetrahydrofuran (N2 or Ar); 25°C, rapid mixing; determination by NMR;	A 1% B 0% C 99%
In chloroform-d1 (N2 or Ar); 25°C, rapid mixing; determination by NMR;	A 1% B 0% C 99%

...Expand

: 52542-59-3, 192520-17-5
bis(triphenylphosphineiminium) pentacarbonylmanganate(1-)

: 10170-69-1
dimanganese decacarbonyl

Conditions

Conditions	Yield
With N-t-butylbenzaldimine; NOPF6 In tetrahydrofuran soln. of benzaldehyde t-butylimine in THF added dropwise to NOPF6, Mn complex in THF added dropwise, stirred at room temp. for 45 min; not isolated; detected by IR;	98%
With N-t-butylbenzaldimine; NOPF6 In tetrahydrofuran soln. of benzaldehyde t-butylimine in THF added dropwise to NOPF6, Mn complex in THF added dropwise, stirred at -78°C for 45 min; not isolated; detected by IR;	95%
With NOPF6 In not given
With triethylamine; NOPF6 In tetrahydrofuran Et3N in THF added to NOPF6, suspn. of Mn complex in THF added dropwise,stirred at room temp. for 1 h;

: 52542-59-3, 192520-17-5
bis(triphenylphosphineiminium) pentacarbonylmanganate(1-)

: 999-54-2
(E)-methyl 4-chlorobut-2-enoate

A: 10170-69-1
dimanganese decacarbonyl

B: 14100-30-2
pentacarbonylchloromanganese(I)

C: η1-4-oxo-4-ethoxy-2-butenyl manganese pentacarbonyl

Conditions

Conditions	Yield
In tetrahydrofuran (N2 or Ar), 25°C, stirring for 30 min in a round-bottom flask; solvent is removed under reduced pressure, extd. with pentane, chromy. on silica gel(CH2Cl2), determined by (55)Mn-NMR;	A 2% B 0% C 98%

...Expand

: Mn(CO)5(OC(O)C12H25)

: 201230-82-2
carbon monoxide

: 1333-74-0
hydrogen

: 10170-69-1
dimanganese decacarbonyl

Conditions

Conditions	Yield
In hexane byproducts: HCOOC12H25, n-C12H25OH; N2-atmosphere; closed vessel, 48 bar CO/H2, 85°C, 11 h; cooling to room temp., solvent removal (vac.), dissoln. in 5% CH2Cl2/hexane, chromy. (SiO2, 5% CH2Cl2/hexane), evapn., drying (vac.);	96%

...Expand

: 159983-78-5
Mn(CO)5(CO(CH2)10CH3)

: 201230-82-2
carbon monoxide

: 1333-74-0
hydrogen

A: 10170-69-1
dimanganese decacarbonyl

B: 16972-33-1
pentacarbonylhydridomanganese

Conditions

Conditions	Yield
In tetrahydrofuran N2-atmosphere; closed vessel, 48 bar CO/H2, 60°C, 8 h; cooling to room temp., solvent removal (vac.), dissoln. in 25% CH2Cl2/pentane, chromy. (SiO2, 5% CH2Cl2/pentane), evapn., drying (vac.);	A 95% B 5%

...Expand

: 600-00-0
ethyl 2-bromoisobutyrate

: 52542-59-3, 192520-17-5
bis(triphenylphosphineiminium) pentacarbonylmanganate(1-)

A: 14516-54-2
bromopentacarbonylmanganese(I)

B: 10170-69-1
dimanganese decacarbonyl

C: 16972-33-1
pentacarbonylhydridomanganese

Conditions

Conditions	Yield
In chloroform-d1 (N2 or Ar); 25°C, rapid mixing; determination by NMR;	A 5% B 95% C 0%
In tetrahydrofuran (N2 or Ar); 25°C, rapid mixing; determination by NMR;	A >99 B 0% C 0%

...Expand

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Specification

The Manganese,decacarbonyldi-, (Mn-Mn) , with the CAS registry number 10170-69-1, is also known as Manganese, decacarbonyldi-. Its EINECS number is 233-445-6. This chemical's molecular formula is C₁₀Mn₂O₁₀ and molecular weight is 389.98. What's more, its systematic name is carbon monooxide - manganese (5:1). The product should be sealed and stored in a cool and dry place. It should be ensured that the workshop is well ventilated or equipped with exhaust devices.

When you are using this chemical, please be cautious about it as the following:
It is toxic by inhalation, in contact with skin and if swallowed. You need not breathe dust. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice, besides, in case of accident or if you feel unwell seek medical advice immediately (show the label where possible). When using it, you should wear suitable protective clothing, gloves and eye/face protection.

You can still convert the following datas into molecular structure:
(1)Canonical SMILES: [Mn].[Mn].[C-]#[O+].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-]
(2)InChI: InChI=1/10CO.2Mn/c10*1-2;;
(3)InChIKey: QFEOTYVTTQCYAZ-UHFFFAOYAD