CAS No.10196-18-6,Zinc nitrate hexahydrate Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	10196-18-6
Name:	Zinc nitrate hexahydrate
Article Data:	68

Formula:	Zn(NO₃)₂^.6(H₂O)
Molecular Weight:	189.4
Synonyms:	Nitricacid, zinc salt, hexahydrate (8CI,9CI);Nitric acid, zinc salt,hydrate (2:1:6);Zincnitrate (Zn(NO3)2), hexahydrate;Zinc nitratehexahydrate (Zn(NO3)2.6H2O);
EINECS:	231-943-8
Density:	2.065 g/mL at 25 °C(lit.)
Melting Point:	36 °C(lit.)
Boiling Point:	105～131oC (-6H2O)
Solubility:	1800 g/L (20 °C) in water
Appearance:	white crystal
Hazard Symbols:	O, Xn
Risk Codes:	8-22-36/37/38-38
Safety:	17-26-24/25
Transport Information:	UN 1514 5.1/PG 2
PSA:	193.14000
LogP:	0.17990

Synthetic route

: C56H88N12O16Zn2

: 10196-18-6
zinc(II) nitrate

Conditions

Conditions	Yield
at 20 - 800℃;	69.8%

: aluminum(III) nitrate nonahydrate

: 7440-66-6
zinc

A: 10196-18-6
zinc(II) nitrate

B: [Al13(μ3-OH)6(μ-OH)18(H2O)24](NO3)15

Conditions

Conditions	Yield
In water aq. soln. of Al(NO3)3*9H2O treated with Zn, stirred overnight; filtered, evapd., washed with isopropanol; monitored by XRD;	A n/a B 55.2%

...Expand

: 7697-37-2
nitric acid

: 743369-26-8
zinc(II) carbonate

: 10196-18-6
zinc(II) nitrate

Conditions

Conditions	Yield
In nitric acid prepn. by treating of metal carbonate with 70% HNO3 at room temp.; washed (petroleum ether); recrystd. (H2O); dried over fused CaCl2 in desiccator;

: zinc nitrite

: 80937-33-3
oxygen

: 10196-18-6
zinc(II) nitrate

Conditions

Conditions	Yield
In water formation from Zn(NO2)2 in aq. soln. with O2 or O2 containing gases under pressure above 150°C;;
In water formation from Zn(NO2)2 in aq. soln. with O2 or O2 containing gases under pressure above 150°C;;

: zinc(II) nitrate hydrate

: 10196-18-6
zinc(II) nitrate

Conditions

Conditions	Yield
In neat (no solvent) byproducts: basic zinc nitrates; on dehydration on monohydrate on heating or at room temp. in vacuum, insol. basic zinc nitrates are formed;;	0%
In neat (no solvent) byproducts: basic zinc nitrates; on dehydration on monohydrate on heating or at room temp. in vacuum, insol. basic zinc nitrates are formed;;	0%

: 7697-37-2
nitric acid

: zinc(II) oxide

: 10196-18-6
zinc(II) nitrate

Conditions

Conditions	Yield
In nitric acid aq. HNO3; oxide dissoln. soln. evapn. to dryness; residue dissoln. in water, soln. evapn. (excess acid removal);
In water
In water

: ammonium nitrate

: zinc(II) oxide

: 10196-18-6
zinc(II) nitrate

Conditions

Conditions	Yield
In further solvent(s) byproducts: NH3, H2O; on dissolving of ZnO in molten ammonium nitrate;;
byproducts: NH3; H2O;

: silver nitrate

: zinc(II) oxide

A: 10196-18-6
zinc(II) nitrate

B: 80937-33-3
oxygen

C: 7440-22-4
silver

Conditions

Conditions	Yield
In water Irradiation (UV/VIS); addition of solid ZnO to a solution of AgNO3 in H2O; sun light (day light) irradiation;;

...Expand

: silver nitrate

: zinc(II) oxide

: 10196-18-6
zinc(II) nitrate

Conditions

Conditions	Yield
byproducts: Ag, O2; Irradiation (UV/VIS); irradiated ZnO is reacting with AgNO3;;

: 10102-03-1
dinitrogen pentoxide

: zinc(II) oxide

A: 10196-18-6
zinc(II) nitrate

B: zinc nitrite

Conditions

Conditions	Yield
on react. of N2O5 in a closed apparatus;; small amt. of ZnO and Zn(NO2)2;;
on react. of N2O5 in a closed apparatus;; small amt. of ZnO and Zn(NO2)2;;

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Chemistry

Molecule structure of Zinc nitrate hexahydrate (CAS NO.10196-18-6):

IUPAC Name: Zinc dinitrate hexahydrate
Molecular Weight: 297.51048 g/mol
Molecular Formula: H₁₂N₂O₁₂Zn
Density: 2.065 g/mL at 25 °C(lit.)
Melting Point: 36 °C(lit.)
Water Solubility: 1800 G/L (20 °C)
H-Bond Donor: 6
H-Bond Acceptor: 12
Exact Mass: 295.96817
MonoIsotopic Mass: 295.96817
Topological Polar Surface Area: 138
Heavy Atom Count: 15
Canonical SMILES: [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].O.O.O.O.O.O.[Zn+2]
InChI: InChI=1S/2NO3.6H2O.Zn/c2*2-1(3)4;;;;;;;/h;;6*1H2;/q2*-1;;;;;;;+2
InChIKey: JGPSMWXKRPZZRG-UHFFFAOYSA-N
EINECS: 231-943-8
Product Categories: Essential Chemicals; Reagent Grade; Routine Reagents

Uses

Zinc nitrate hexahydrate (CAS NO.10196-18-6) is mainly used for machines and bicycle parts galvanized, preparation of steel phosphating agent. It is also used as a mordant in dyeing. And it's used as analytical reagent, but also for the pharmaceutical industry.

Production

The following is the reaction fomular of preparation of Zinc nitrate hexahydrate .
ZnO +2 HNO₃ → Zn (NO₃) ₂ + H₂O

Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mouse	LD50	intraperitoneal	110mg/kg (110mg/kg)	SENSE ORGANS AND SPECIAL SENSES: CONJUNCTIVE IRRITATION: EYE VASCULAR: BP ELEVATION NOT CHARACTERIZED IN AUTONOMIC SECTION SKIN AND APPENDAGES (SKIN): HAIR: OTHER	Veterinary and Human Toxicology. Vol. 30, Pg. 224, 1988.
mouse	LD50	oral	926mg/kg (926mg/kg)	SENSE ORGANS AND SPECIAL SENSES: CONJUNCTIVE IRRITATION: EYE VASCULAR: BP ELEVATION NOT CHARACTERIZED IN AUTONOMIC SECTION SKIN AND APPENDAGES (SKIN): HAIR: OTHER	Veterinary and Human Toxicology. Vol. 30, Pg. 224, 1988.
rat	LD50	intraperitoneal	133mg/kg (133mg/kg)	SENSE ORGANS AND SPECIAL SENSES: MIOSIS (PUPILLARY CONSTRICTION): EYE VASCULAR: BP ELEVATION NOT CHARACTERIZED IN AUTONOMIC SECTION	Veterinary and Human Toxicology. Vol. 30, Pg. 224, 1988.
rat	LD50	oral	1190mg/kg (1190mg/kg)		"Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha, Czechoslovakia, 1972Vol. -, Pg. 10, 1972.

Consensus Reports

Zinc and its compounds are on the Community Right-To-Know List.

Safety Profile

Hazard Codes: Oxidizing O, Harmful Xn
Risk Statements: 8-22-36/37/38-38
R8 :Contact with combustible material may cause fire.
R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin.
R38:Irritating to skin.
Safety Statements: 17-26-24/25
S17:Keep away from combustible material.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S24/25:Avoid contact with skin and eyes.
RIDADR: UN 1514 5.1/PG 2
WGK Germany: 3
RTECS: ZH4775000
HazardClass: 5.1
PackingGroup: II
Moderately toxic by ingestion. A severe skin and eye irritant. Can react violently with carbon; copper; metal sulfides; organic matter; phosphorus; sulfur. When heated to decomposition it emits toxic fumes of NO_x and ZnO. See also ZINC COMPOUNDS and NITRATES.

Specification

Zinc nitrate hexahydrate (CAS NO.10196-18-6) is also named as CCRIS 8894 ; Dusicnan zinecnaty ; Dusicnan zinecnaty [Czech] ; Nitric acid, zinc salt, hexahydrate ; Zinc(II) nitrate, hexahydrate (1:2:6) . Zinc nitrate hexahydrate (CAS NO.10196-18-6) is white crystal. It is soluble in water and ethanol .