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102-81-8

Basic Information
CAS No.: 102-81-8
Name: 2-(DIBUTYLAMINO)ETHANOL
Article Data: 12
Molecular Structure:
Molecular Structure of 102-81-8 (2-(DIBUTYLAMINO)ETHANOL)
Formula: C10H23 N O
Molecular Weight: 173.299
Synonyms: 2-(Dibutylamino)ethanol;2-Di-N-butylaminoethyl alcohol; Amino Alcohol 2B; Dibutylaminoethanol;Dibutylethanolamine; N,N-Dibutyl-2-hydroxyethylamine;N,N-Dibutyl-N-(2-hydroxyethyl)amine; N,N-Dibutylaminoethanol;N,N-Dibutylethanolamine; N-(2-Hydroxyethyl)dibutylamine; NSC 6330
EINECS: 203-057-1
Density: 0.873g/cm3
Melting Point: -70°C(lit.)
Boiling Point: 229.5°Cat760mmHg
Flash Point: 91.7°C
Solubility: negligible
Appearance: colourless liquid
Hazard Symbols: Toxic by ingestion and skin absorption. TLV: 0.5 ppm.
Risk Codes: 21/22-34
Safety: Poison by intraperitoneal route. Moderately toxic by ingestion and skin contact. A severe eye and skin irritant. Combustible; can react with oxidizing materials. To fight fire, use CO2, dry chemical. When heated to decomposition it emits toxic fumes of NOx. See also AMINES and ALCOHOL, DENATURED; ALCOHOLS, C6-12; ALCOHOLS, C9-11; ALCOHOLS, C12-13, ETHOXYLATED; ALCOHOLS, C12-15, ETHOXYLATED; ALCOHOLS, C12-16, ETHOXYLATED; ALCOHOLS, C14-15, ETHOXYLATED; ALCOHOLS, C16-18, ETHOXYLATED; ALCOHOLS, C8-10, ETHOXYLATED PROPOXYLATED; ALCOHOLS, C12-15, ETHOXYLATED PROPOXYLATED; ALCOHOLS, N.O.S..

Analytical Methods:

   

For occupational chemical analysis use NIOSH: Aminoethanol Compounds, 2007.

PSA: 23.47000
LogP: 1.88090
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Chemistry

IUPAC: 2-(Dibutylamino)ethanol 
Molecular Formula: C10H23NO
Molecular Weight: 173.34g/mol
EINECS: 203-057-1
Liansport Information: UN 2873 6.1/PG
Density: 0.873g/cm3
Boiling Point: 229.5°C at760mmHg
Flash Point: 91.7°C
Solubility: negligible
Appearance: colourless liquid
Freely Rotating Bonds: 9 
Polar Surface Area: 12.47 Å2 
Index of Refraction: 1.453 
Molar Refractivity: 53.63 cm3 
Molar Volume: 198.3 cm3 
Polarizability: 21.26 ×10-24 cm3 
Surface Tension: 32.1 dyne/cm  
Enthalpy of Vaporization: 54.19 kJ/mol 
Vapour Pressure: 0.0133 mmHg at 25°C
Stability: stable, combustible,incompatible with strong oxidizing agents
 2-N-Dibutylaminoethanol ,its Cas Register Number is 102-81-8.The chemical synonyms of 2-N-Dibutylaminoethanol (CAS No.102-81-8) are 2-(dibutylamino)-ethano ; 2-Ethamolamine, N,N-dibutyl- ; 2-N-Dibutylaminoethanol ; beta-N-Dibutylaminoethyl alcohol ; Beta-n-dibutylaminoethylalcohol ; Bu2ae ; Di(n-Butyl)ethanolamine ; N,N-Dibutyl-2-hydroxyethylamine .The molecular structure of 2-N-Dibutylaminoethanol (CAS No.102-81-8) is.

Uses

It is used as acatalyst for polyurethane, fiber additive, and emulsifier.

Toxicity Data With Reference

1.    

skn-rbt 10 mg/24H open

    AMIHBC    AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61.
2.    

skn-rbt 5 mg/24H SEV

    85JCAE    Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague, Czechoslovakia.: Avicenum,1986,695.
3.    

eye-rbt 20 mg/24H open SEV

    AMIHBC    AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61.
4.    

orl-rat LD50:1070 mg/kg

    AMIHBC    AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61.
5.    

ipr-rat LD50:144 mg/kg

    TXAPA9    Toxicology and Applied Pharmacology. 12 (1968),486.
6.    

ipr-mus LD50:52 mg/kg

    RCRVAB    Russian Chemical Reviews. 38 (1969),975.
7.    

skn-rbt LD50:1680 mg/kg

    AMIHBC    AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61.
8.    

ipr-mam LD50:120 mg/kg

    TXAPA9    Toxicology and Applied Pharmacology. 8 (1966),344.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Poison by intraperitoneal route. Moderately toxic by ingestion and skin contact. A severe eye and skin irritant. Combustible; can react with oxidizing materials. To fight fire, use CO2, dry chemical. When heated to decomposition it emits toxic fumes of NOx. See also AMINES and ALCOHOL, DENATURED; ALCOHOLS, C6-12; ALCOHOLS, C9-11; ALCOHOLS, C12-13, ETHOXYLATED; ALCOHOLS, C12-15, ETHOXYLATED; ALCOHOLS, C12-16, ETHOXYLATED; ALCOHOLS, C14-15, ETHOXYLATED; ALCOHOLS, C16-18, ETHOXYLATED; ALCOHOLS, C8-10, ETHOXYLATED PROPOXYLATED; ALCOHOLS, C12-15, ETHOXYLATED PROPOXYLATED; ALCOHOLS, N.O.S..
Hazard Codes:  C
C:  Corrosive
Risk Statements:  21/22-34
34:  Causes burns 
21/22:  Harmful in contact with skin and if swallowed 
Safety Statements:  26-36/37/39-45
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 
45:  In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) 
36/37/39:  Wear suitable protective clothing, gloves and eye/face protection 
HazardClass:  6.1(b)

Standards and Recommendations

OSHA PEL: TWA 2 ppm
ACGIH TLV: TWA 0.5 ppm (skin)
DOT Classification:  6.1; Label: KEEP AWAY FROM FOOD

Analytical Methods

For occupational chemical analysis use NIOSH: Aminoethanol Compounds, 2007.

Specification

 2-N-Dibutylaminoethanol (CAS No.102-81-8) is an aminoalcohol. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides.It may burn but does not ignite readily. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.