CAS No.10361-46-3,Bismuth nitrate oxide Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	10361-46-3
Name:	Bismuth nitrate oxide
Article Data:	16

Formula:	BiNO₄
Molecular Weight:	286.985
Synonyms:	Bismuthnitrate (BiO(NO3)) (6CI);Bismuth nitrate oxide (BiO(NO3)) (7CI,8CI);Bismuthine, (nitrooxy)oxo- (9CI);Bismuth nitrate oxide(Bi(NO3)O);
EINECS:	233-792-3
Density:	4.93
Melting Point:	260, decomposing [HAW93]
Boiling Point:	83oC at 760 mmHg
Solubility:	Insoluble in water. Soluble in acids.
Appearance:	White powder
Hazard Symbols:	O, Xi
Risk Codes:	8-36/37/38
Safety:	17-26-36/37/39
Transport Information:	UN 1477
PSA:	419.34000
LogP:	-0.98120

Synthetic route

: 1304-76-3
bismuth(III) oxide

A: 10361-46-3
bismuth subnitrate

B: bismutum subnitricum

Conditions

Conditions	Yield
In nitric acid aq. HNO3; formation of the sparingly soluble basic salts; solution of the salts if H(1+)-activity exceeds 0.06;;
In nitric acid aq. HNO3; formation of the sparingly soluble basic salts; solution of the salts if H(1+)-activity exceeds 0.06;;

: bismuth (III) nitrate pentahydrate

: 10361-46-3
bismuth subnitrate

Conditions

Conditions	Yield
In neat (no solvent) drying over H2SO4 or in a stream of CO2 or dry air to constant weight;;
In neat (no solvent) storage of the pentahydrate in a desiccator until 19 % loss of weight, then heating at 50-100°C in a dry stream of air without melting;; constant weight after 6 days;;

: bismuth(III) nitrate

A: 10361-46-3
bismuth subnitrate

B: Bi12O18*9H2O*5N2O5

C: bismuth oxide nitrate 0.5-hydrate

D: bismuth oxide nitrate dihydrate

Conditions

Conditions	Yield
With H2O In nitric acid aq. HNO3; slow diffusion of H2O into a saturated solution of Bi nitrate in HNO3;; separation of different crystals;;

...Expand

: 2Bi2O3*2CrO3

: 7697-37-2
nitric acid

: 10361-46-3
bismuth subnitrate

Conditions

Conditions	Yield
In nitric acid dissoln. in dild. HNO3 (excess); addn. of H2O; pptn.;;
In nitric acid aq. HNO3; dissoln. in dild. HNO3 (excess); addn. of H2O; pptn.;;

: bismuth chromate

: 7697-37-2
nitric acid

A: 10361-46-3
bismuth subnitrate

B: Bi2O3*2CrO3

C: Bi2O3*4CrO3

Conditions

Conditions	Yield
In nitric acid boiling with a small amt. of concd. HNO3; evapn.;;
In nitric acid aq. HNO3; boiling with a small amt. of concd. HNO3; evapn.;;

...Expand

: BiO0.5(2+)*2NO3(1-)=BiO0.5(NO3)2

: 10361-46-3
bismuth subnitrate

Conditions

Conditions	Yield
In neat (no solvent, solid phase) byproducts: N2O5; heating at 440-500°C;

: 7440-69-9
bismuth

: 7697-37-2
nitric acid

: 10361-46-3
bismuth subnitrate

Conditions

Conditions	Yield
With water In nitric acid byproducts: N oxide; preparation of a layer of 165 g remolten Bi (description of method given) and solvation at 60-70°C in 1040 ml 25% HNO3; vigorous reaction, form. of N oxide; filtration and evaporation in porcelain crucibles; addition of 800 ml H2O under stirring;; addition of the mass to hot water and washing the precipitate with H2O; drying with alcohol and heating at 45°C;;
With H2O In nitric acid byproducts: N oxide; aq. HNO3; preparation of a layer of 165 g remolten Bi (description of method given) and solvation at 60-70°C in 1040 ml 25% HNO3; vigorous reaction, form. of N oxide; filtration and evaporation in porcelain crucibles; addition of 800 ml H2O under stirring;; addition of the mass to hot water and washing the precipitate with H2O; drying with alcohol and heating at 45°C;;

Yield

With water In nitric acid byproducts: N oxide; preparation of a layer of 165 g remolten Bi (description of method given) and solvation at 60-70°C in 1040 ml 25% HNO3; vigorous reaction, form. of N oxide; filtration and evaporation in porcelain crucibles; addition of 800 ml H2O under stirring;; addition of the mass to hot water and washing the precipitate with H2O; drying with alcohol and heating at 45°C;;

With H2O In nitric acid byproducts: N oxide; aq. HNO3; preparation of a layer of 165 g remolten Bi (description of method given) and solvation at 60-70°C in 1040 ml 25% HNO3; vigorous reaction, form. of N oxide; filtration and evaporation in porcelain crucibles; addition of 800 ml H2O under stirring;; addition of the mass to hot water and washing the precipitate with H2O; drying with alcohol and heating at 45°C;;

: 7440-69-9
bismuth

: 10361-46-3
bismuth subnitrate

Conditions

Conditions	Yield
With nitric acid In nitric acid byproducts: NO; Bi metal was dissolved in 11 M HNO3; evapd. to dryness, baked at 115°C for several h, elem. anal.;

: 13520-71-3
basic bismuth nitrate

: 10361-46-3
bismuth subnitrate

Conditions

Conditions	Yield
In neat (no solvent) dehydration;;
In neat (no solvent) heating in a dry stream of CO2 at 100°C for 6 hours with formation of Bi2O3N2O5H2O and finally with formation of Bi2O3*N2O5;;

: bismuth oxide nitrate 0.5-hydrate

: 10361-46-3
bismuth subnitrate

Conditions

Conditions	Yield
In neat (no solvent) dehydration;;

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Chemistry

Molecular Structure:

Molecular Formula: BiNO₄
Molecular Weight: 286.9847
IUPAC Name: Oxobismuthanyl nitrate
Synonyms of Bismuth nitrate oxide (CAS NO.10361-46-3): EINECS 233-792-3 ; (Nitrooxy)oxobismuthine
CAS NO: 10361-46-3
Product Categories: Inorganic Chemicals ; API's
H bond acceptors: 4
H bond donors: 1
Polar Surface Area: 66.05 Å²
Enthalpy of Vaporization: 37.72 kJ/mol
Boiling Point: 83 °C at 760 mmHg
Vapour Pressure: 49.8 mmHg at 25°C

Uses

Bismuth nitrate oxide (CAS NO.10361-46-3) is used in treating the stomach and duodenal ulcer and the diarrhea.

Safety Profile

Hazard Codes of Bismuth nitrate oxide (CAS NO.10361-46-3): Oxidizing O, Irritant Xi
Risk Statements: 8-36/37/38
R8: Contact with combustible material may cause fire.
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements: 17-26-36/37/39
S17: Keep away from combustible material.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
RIDADR: UN 1477 5.1/PG 2
WGK Germany: 3
F: 8
HazardClass: 5.1
PackingGroup: II