CAS No.10378-01-5,CIS-9-HEXADECENOL Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	10378-01-5
Name:	CIS-9-HEXADECENOL
Article Data:	21

Formula:	C₁₆H₃₂O
Molecular Weight:	240.429
Synonyms:	9-Hexadecen-1-ol,(Z)- (8CI);(Z)-9-Hexadecen-1-ol;9-cis-Hexadecenol;Palmitoleyl alcohol;cis-9-Hexadecen-1-ol;cis-9-Hexadecenol;cis-D9-Hexadecenol;
EINECS:	233-831-4
Density:	0.847 g/cm³
Boiling Point:	340 °C at 760 mmHg
Flash Point:	115.4 °C
PSA:	20.23000
LogP:	5.23600

Synthetic route

: 373-49-9
cis-9-hexadecenoic acid

: 10378-01-5
palmitoleyl alcohol

Conditions

Conditions	Yield
With lithium aluminium tetrahydride In tetrahydrofuran at 0℃; Reflux;	98%
With lithium aluminium tetrahydride In diethyl ether at 20℃; for 24h;	97%
Multi-step reaction with 2 steps 1: 0.19 g / conc. H2SO4 / 6 h / Heating 2: 0.14 g / LiAlH4 / tetrahydrofuran / 24 h / Ambient temperature View Scheme

: 88109-73-3
9-hexadecyn-1-ol

: 10378-01-5
palmitoleyl alcohol

Conditions

Conditions	Yield
With hydrogen; ethylendiamine poisoned P-2 Ni In ethanol	97%
With hydrogen; Ni-P2	88%
With bis(cyclopentadienyl)titanium dichloride; di-iso-butylmagnesium; ammonium chloride 1.) Et2O, 20 deg C, 30 min, 2.) H2O; Yield given. Multistep reaction;

: 1120-25-8
(Z)-9-hexadecenoic acid methyl ester

: 10378-01-5
palmitoleyl alcohol

Conditions

Conditions	Yield
With lithium aluminium tetrahydride In tetrahydrofuran at -10 - 20℃; for 5h;	96%
With lithium aluminium tetrahydride In tetrahydrofuran at 0℃; for 2h;	92%
With lithium aluminium tetrahydride In tetrahydrofuran for 24h; Ambient temperature;	0.14 g
With lithium aluminium tetrahydride In diethyl ether for 2h; Reflux;	2.3 g

: 60037-69-6
9-tetradecyn-1-ol

: 10378-01-5
palmitoleyl alcohol

Conditions

Conditions	Yield
With hydrogen; P2Ni	86%

: 34010-20-3
(Z)-hexadec-9-en-1-yl acetate

: 10378-01-5
palmitoleyl alcohol

Conditions

Conditions	Yield
With lithium aluminium tetrahydride In diethyl ether at 20℃; for 5h;	82%
With sodium hydroxide In methanol

: (Z)-tert-butyl(hexadec-9-en-1-yloxy)dimethylsilane

: 10378-01-5
palmitoleyl alcohol

Conditions

Conditions	Yield
With tetrabutyl ammonium fluoride In tetrahydrofuran at 0 - 20℃; for 3h;	82%

: 111-71-7
heptanal

: 73945-70-7
(9-hydroxynonyl)(triphenyl)phosphonium bromide

A: 64437-47-4
trans-hexadec-9-en-1-ol

B: 10378-01-5
palmitoleyl alcohol

Conditions

Conditions	Yield
With sodium hydride; dimethyl sulfoxide In tetrahydrofuran for 0.5h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

...Expand

: (Z)-16-(1-Ethoxy-ethoxy)-hexadec-7-ene

: 10378-01-5
palmitoleyl alcohol

Conditions

Conditions	Yield
With toluene-4-sulfonic acid In methanol; water at 20℃; for 15h; Yield given;

: 99159-88-3
2-[((Z)-Hexadec-9-enyl)oxy]-tetrahydro-pyran

: 10378-01-5
palmitoleyl alcohol

Conditions

Conditions	Yield
With toluene-4-sulfonic acid In methanol for 3h; Heating; Yield given;
With toluene-4-sulfonic acid In methanol at 20℃; for 16h;

: 21676-07-3
(Z)-4-undecene-1-ol

: 10378-01-5
palmitoleyl alcohol

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: 96 percent / triphenylphosphine, Br2 / CCl4 / 16 h / Ambient temperature 2: 1.) cuprous iodide, 2,2' bipyridyl / 1.) THF, 2 deg C, 10 min, 2.) THF, a) 2 deg C, 2 h, b) RT, 15 h 3: p-toluenesulfonic acid / methanol; H2O / 15 h / 20 °C View Scheme
Multi-step reaction with 3 steps 1: 82 percent / PBr3, pyridine / diethyl ether / 1) rt, overnight, 2) reflux, 2 h 2: 1) Mg / 3) Li2CuCl4 / 1) THF, 2) THF, -10 deg C, 30 min, 3) a) 0 to -10 deg C, 6 h, b) rt, overnight 3: p-toluenesulphonic acid / methanol / 3 h / Heating View Scheme

Downstream Products

56219-04-6

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Specification

The 9-Hexadecen-1-ol, (9Z)-, with the CAS registry number 10378-01-5, is also known as cis-9-Hexadecenol. Its EINECS registry number is 233-831-4. This chemical's molecular formula is C₁₆H₃₂O and molecular weight is 240.42. Its IUPAC name is called (Z)-hexadec-9-en-1-ol.

Physical properties of 9-Hexadecen-1-ol, (9Z)-: (1)ACD/LogP: 6.73; (2)# of Rule of 5 Violations: 1; (3)#H bond acceptors: 1; (4)#H bond donors: 1; (5)#Freely Rotating Bonds: 14; (6)Index of Refraction: 1.46; (7)Molar Refractivity: 77.76 cm³; (8)Molar Volume: 283.7 cm³; (9)Surface Tension: 31.5 dyne/cm; (10)Density: 0.847 g/cm³; (11)Flash Point: 115.4 °C; (12)Enthalpy of Vaporization: 67.6 kJ/mol; (13)Boiling Point: 340 °C at 760 mmHg; (14)Vapour Pressure: 5.88E-06 mmHg at 25°C.

You can still convert the following datas into molecular structure:
(1)Canonical SMILES: CCCCCCC=CCCCCCCCCO
(2)Isomeric SMILES: CCCCCC/C=C\CCCCCCCCO
(3)InChI: InChI=1S/C16H32O/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17/h7-8,17H,2-6,9-16H2,1H3/b8-7-
(4)InChIKey: LBIYNOAMNIKVKF-FPLPWBNLSA-N