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10415-75-5

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Basic Information
CAS No.: 10415-75-5
Name: MERCUROUS NITRATE
Molecular Structure:
Molecular Structure of 10415-75-5 (MERCUROUS NITRATE)
Formula: HN O3 . Hg
Molecular Weight: 262.595
Synonyms: Nitricacid, mercury(1+) salt (8CI,9CI); Dimercury dinitrate; Dimercury(1+) dinitrate;Mercurous nitrate; Mercury nitrate (Hg2(NO3)2); Mercury nitrate (HgNO3);Mercury(I) nitrate; Monomercury nitrate
Density: g/cm3
Melting Point: decomposes at 70℃ [HAW93]
Boiling Point: 83°Cat760mmHg
Flash Point: °C
Solubility: sensitive to H2O: soluble in small quantities of warm H2O, but hydrolyzes in larger amounts [HAW93]
Hazard Symbols: May be explosive if shocked or heated. Highly toxic. TLV: TWA 0.1 mg(Hg)/m3.
Safety: Poison by ingestion and intraperitoneal routes. Moderately toxic by skin contact. A powerful oxidizer. Explodes on contact with red-hot carbon. Mixtures with phosphorus are impact-sensitive explosives. When heated to decomposition it emits very toxic fumes of Hg and NOx. See also MERCURY COMPOUNDS, INORGANIC; MERCURY COMPOUNDS, ORGANIC.
PSA: 68.88000
LogP: 0.28160
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Chemistry

Molecular Structure of Mercury(i) nitrate (1:1) (CAS NO.10415-75-5):

IUPAC Name: mercury(1+) nitrate 
Empirical Formula: HgNO3
Molecular Weight: 262.5949 
Boiling Point: 83 °C at 760 mmHg
Vapour Pressure: 49.8 mmHg at 25°C
Product Categories:Inorganics
Synonyms of Mercury(i) nitrate (1:1 (CAS NO.10415-75-5): mercury (I) nitrate; Mercury (I) Nitrate (1:1); Mercurous Nitrate, 98%; mercury protonitrate ; Nitric Acid, Mercury (1+) salt; Mercury(II)nitratedihydrate ; Mercurous nitrate 2-hydrate; Mercury(i) nitrate ; Mercury(i) nitrate 2-hydrate ; Mercury(i) nitrate dihydrate ; Mercury (i) nitrate, hydrous ; Mercurous nitrate, dihydrate

Toxicity Data With Reference

1.    

orl-rat LD50:170 mg/kg

     GISAAA    Gigiena i Sanitariya. 46 (8)(1981),12.
2.    

skn-rat LD50:2330 mg/kg

     GTPZAB    Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 25 (7)(1981),27.
3.    

orl-mus LD50:49,300 µg/kg

     GISAAA    Gigiena i Sanitariya. 46 (8)(1981),12.
4.    

ipr-mus LD50:5 mg/kg

     ATXKA8    Archiv fuer Toxikologie. 20 (1964),226.
5.    

orl-mam LD50:238 mg/kg

     GISAAA    Gigiena i Sanitariya. 49 (9)(1984),11.

Consensus Reports

Mercury and its compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory.

Safety Profile

Poison by ingestion and intraperitoneal routes. Moderately toxic by skin contact. A powerful oxidizer. Explodes on contact with red-hot carbon. Mixtures with phosphorus are impact-sensitive explosives. When heated to decomposition it emits very toxic fumes of Hg and NOx. See also MERCURY COMPOUNDS, INORGANIC; MERCURY COMPOUNDS, ORGANIC.

Standards and Recommendations

OSHA PEL: CL 0.1 mg(Hg)/m3 (skin)
ACGIH TLV: TWA 0.1 mg(Hg)/m3 (skin); BEI: 35 µg/g creatinine total inorganic mercury in urine preshift; 15 µg/g creatinine total inorganic mercury in blood at end of shift at end of workweek.
NIOSH REL: (Mercury, Aryl and Inorganic) CL 0.1 mg/m3 (skin)
DOT Classification:  6.1; Label: Poison

Specification

 Mercury(i) nitrate (1:1) (CAS NO.10415-75-5) is a highly toxic colorless crystals with nitric acid odor ，can be used as analytical reagent and the oxidant，besides can be used in the pharmaceutical. Its production methods is to dilute nitric acid by adding acid reactor, heating to 40 ~ 50 ℃, the slow reaction of added mercury by evaporation, cooling crystallization, centrifugal separation, mercury nitrate dihydrate obtained.The reaction is 2Hg +2 HNO3 +2 H2O → 2HgNO3 · 2H2O + H2 ↑

 Heating decomposition will produce toxic mercury vapor and nitrogen oxide fumes, should not be fixed with organic matter, reducing agents, combustible sulfur and phosphorus combustible. Storage and transport characteristics of Mercury(i) nitrate (1:1) (CAS NO.10415-75-5) are low-temperature, drying, light pack light unloaded; separated with organic matter, reducing agents, sulfur, phosphorus combustible, food raw materials.Fire-extinguishing agent mist of water, sand, foam can be used if emergency.