CAS No.105-16-8,2-(Diethylamino)ethyl methacrylate Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	105-16-8
Name:	2-(Diethylamino)ethyl methacrylate

Formula:	C₁₀H₁₉NO₂
Molecular Weight:	185.266
Synonyms:	Methacrylicacid, 2-(diethylamino)ethyl ester (6CI,8CI);2-(N,N-Diethylamino)ethylmethacrylate;2-Diethylaminoethyl methacrylate;Daktose B;Diethyl[2-(methacryloyloxy)ethyl]amine;Diethylaminoethyl methacrylate;GE 710;Light Ester DE;N,N-Diethylaminoethyl methacrylate;NSC 14490;Polydeam;[2-(Methacryloyloxy)ethyl]diethylamine;b-(Diethylamino)ethyl methacrylate;b-(N,N-Diethylamino)ethylmethacrylate;
EINECS:	203-275-7
Density:	0.93 g/cm³
Melting Point:	-60 °C
Boiling Point:	239.327 °C at 760 mmHg
Flash Point:	80.975 °C
Appearance:	clear light colored liquid
Hazard Symbols:	Xn
Risk Codes:	20-36/38-43
Safety:	26
PSA:	29.54000
LogP:	1.44750

Synthetic route

: 80-62-6
methacrylic acid methyl ester

: 100-37-8
2-(Diethylamino)ethanol

: 105-16-8
2-(diethylamino)ethyl methacrylate

Conditions

Conditions	Yield
With 10H-phenothiazine; lithium hydroxide In hexane at 65 - 73℃; for 5h; Reagent/catalyst;	94.1%
With hydroquinone; lithium hydroxide at 50 - 85℃; under 600 Torr; for 3.5h; Reagent/catalyst;	94%
With sodium methylate; 1,4-phenylenediamine; benzene

: 105-16-8
2-(diethylamino)ethyl methacrylate

: C14H17BrO5

: C24H36NO7(1+)*Br(1-)

Conditions

Conditions	Yield
With hydroquinone In acetonitrile at 70℃; for 10h;	100%

: 5281-20-9
acetone hydrazone

: 105-16-8
2-(diethylamino)ethyl methacrylate

: C13H25NO2

Conditions

Conditions	Yield
With iodosylbenzene In ethyl acetate at 20℃; for 1h; Green chemistry;	100%

: 31469-15-5
1-methoxy-2-methyl-1-trimethylsiloxy-1-propene

: 2867-47-2
2-(dimethylamino)ethyl methacrylate

: 105-16-8
2-(diethylamino)ethyl methacrylate

poly[2-(diethylamino)ethyl methacrylate]-block-poly[2-(dimethylamino)ethyl methacrylate], Mw 1.98E4 Da, PDI 1.23; monomer(s): 2-(diethylamino)ethyl methacrylate; 2-(dimethylamino)ethyl methacrylate; 1-methoxy-1-(trimethylsilyloxy)-2-methyl-1-propene: poly[2-(diethylamino)ethyl methacrylate]-block-poly[2-(dimethylamino)ethyl methacrylate], Mw 1.98E4 Da, PDI 1.23; monomer(s): 2-(diethylamino)ethyl methacrylate; 2-(dimethylamino)ethyl methacrylate; 1-methoxy-1-(trimethylsilyloxy)-2-methyl-1-propene

Conditions

Conditions	Yield
Stage #1: 1-methoxy-2-methyl-1-trimethylsiloxy-1-propene; 2-(diethylamino)ethyl methacrylate With tetra-n-butylammonium bibenzoate In tetrahydrofuran Stage #2: 2-(dimethylamino)ethyl methacrylate With tetra-n-butylammonium bibenzoate In tetrahydrofuran Stage #3: With methanol In tetrahydrofuran	98%

...Expand

: 542-69-8
1-iodo-butane

: 105-16-8
2-(diethylamino)ethyl methacrylate

: N-butyl-N,N-diethyl-N-[2-(methacryloyloxy)ethyl]ammonium iodide

Conditions

Conditions	Yield
In acetonitrile at 60℃; for 72h; Inert atmosphere;	97.5%

: 105-16-8
2-(diethylamino)ethyl methacrylate

: 75-03-6
ethyl iodide

: 6293-67-0
N,N,N-triethyl-N-[2-(methacryloyloxy)ethyl]ammonium iodide

Conditions

Conditions	Yield
In acetonitrile at 45℃; for 24h; Inert atmosphere;	96.4%
With hydroquinone

: 105-16-8
2-(diethylamino)ethyl methacrylate

: 638-45-9
1-Iodohexane

: N,N-diethyl-N-hexyl-N-[2-(methacryloyloxy)ethyl]ammonium iodide

Conditions

Conditions	Yield
In acetone at 56℃; for 120h; Solvent; Inert atmosphere;	95.9%

: 105-16-8
2-(diethylamino)ethyl methacrylate

: 141-43-5
ethanolamine

polymer, Mn 2.5 kDa, PDI 1.3; monomer(s): 2-(N,N-diethylamino)ethyl methacrylate; 2-ethanolamine: polymer, Mn 2.5 kDa, PDI 1.3; monomer(s): 2-(N,N-diethylamino)ethyl methacrylate; 2-ethanolamine

Conditions

Conditions	Yield
With Naphthalene anion ( K(1+) is the counterion) In tetrahydrofuran at 20℃; for 5h;	93.4%

: 629-27-6
1-Iodooctane

: 105-16-8
2-(diethylamino)ethyl methacrylate

: N,N-diethyl-N-[2-(methacryloyloxy)ethyl]-N-octylammonium iodide

Conditions

Conditions	Yield
With 10H-phenothiazine In acetonitrile at 75℃; for 72h; Inert atmosphere;	93.2%

: 105-16-8
2-(diethylamino)ethyl methacrylate

poly(ethylene oxide) bis(2-bromoisobutyrate), DP 45, Mn 3900 Da, Mw/Mn 1.05: poly(ethylene oxide) bis(2-bromoisobutyrate), DP 45, Mn 3900 Da, Mw/Mn 1.05

poly[(ethylene oxide)-block-(2-(diethylamino)ethyl methacrylate)], poly(ethylene oxide) block DP 45, Mn 7000 Da, Mw/Mn 1.19: poly[(ethylene oxide)-block-(2-(diethylamino)ethyl methacrylate)], poly(ethylene oxide) block DP 45, Mn 7000 Da, Mw/Mn 1.19

Conditions

Conditions	Yield
With [2,2]bipyridinyl; copper(I) bromide In methanol at 20℃; for 5h;	93%

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Consensus Reports

Reported in EPA TSCA Inventory.

Specification

The 2-(Diethylamino)ethyl methacrylate, with the CAS registry number 105-16-8, is also known as 2-(N,N-Diethylamino)ethyl methacrylate. It belongs to the product categories of Monomer; Amine Photochemical Coinitiators Carbonyl Compounds; C10 to C11 Monomers; Acrylic Monomers; Esters; Methacrylate; Polymer Science; Polymerization Initiators. Its EINECS registry number is 203-275-7. This chemical's molecular formula is C₁₀H₁₉NO₂ and molecular weight is 185.26. What's more, its IUPAC name is called 2-(Diethylamino)ethyl 2-methylprop-2-enoate. This chemical can be prepared by methacrylic acid with diethylaminoethanol. It can be used to prepare thermosetting coating, antistatic agents, dyeing additives, lubricant additives, adhesives, leather processing agents, combustion-supporting agent, and others.

Physical properties about 2-(Diethylamino)ethyl methacrylate are: (1)ACD/LogP: 2.125; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -0.87; (4)ACD/LogD (pH 7.4): 0.36; (5)ACD/BCF (pH 5.5): 1.00; (6)ACD/BCF (pH 7.4): 1.00; (7)ACD/KOC (pH 5.5): 1.00; (8)ACD/KOC (pH 7.4): 5.88; (9)#H bond acceptors: 3; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 7; (12)Polar Surface Area: 29.54 Å²; (13)Index of Refraction: 1.449; (14)Molar Refractivity: 53.442 cm³; (15)Molar Volume: 199.233 cm³; (16)Polarizability: 21.186×10^-24cm³; (17)Surface Tension: 29.83 dyne/cm; (18)Density: 0.93 g/cm³; (19)Flash Point: 80.975 °C; (20)Enthalpy of Vaporization: 47.621 kJ/mol; (21)Boiling Point: 239.327 °C at 760 mmHg; (22)Vapour Pressure: 0.040 mmHg at 25 °C.

When you are dealing with this chemical, you should be very careful. This chemical may cause damage to health and cause sensitisation by skin contact. It is harmful by inhalation and irritating to eyes and skin. In case of contacting with eyes, you should rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1) SMILES: CCN(CC)CCOC(=O)C(=C)C
(2) InChI: InChI=1S/C10H19NO2/c1-5-11(6-2)7-8-13-10(12)9(3)4/h3,5-8H2,1-2,4H3
(3) InChIKey: SJIXRGNQPBQWMK-UHFFFAOYSA-N

The toxicity data is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Source
mouse	LC50	inhalation	12100mg/m³/2H (12100mg/m³)	"Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 51, 1982.
rat	LC50	inhalation	11gm/m³/4H (11000mg/m³)	"Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 51, 1982.
rat	LD50	oral	4696mg/kg (4696mg/kg)	"Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 51, 1982.