CAS No.106-25-2,2,6-Octadien-1-ol,3,7-dimethyl-, (2Z)- Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	106-25-2
Name:	2,6-Octadien-1-ol,3,7-dimethyl-, (2Z)-
Article Data:	188

Formula:	C₁₀H₁₈O
Molecular Weight:	154.252
Synonyms:	cis-Geraniol;b-Nerol;2,6-Octadien-1-ol,3,7-dimethyl-, (Z)- (8CI);Nerol (6CI);(2Z)-3,7-Dimethyl-2,6-octadien-1-ol;(Z)-3,7-Dimethyl-2,6-octadien-1-ol;(Z)-Geraniol;(Z)-Nerol;2-cis-3,7-Dimethyl-2,6-octadien-1-ol;3,7-Dimethyl-cis-2,6-octadien-1-ol;Nerol900;Neryl alcohol;cis-3,7-Dimethyl-2,6-octadien-1-ol;
EINECS:	203-378-7
Density:	0.866 g/cm³
Melting Point:	< -10oC
Boiling Point:	229.5 °C at 760 mmHg
Flash Point:	76.7 °C
Solubility:	1.311g/L(25 oC)
Appearance:	Clear colorless to almost colorless liquid
Hazard Symbols:	Xi
Risk Codes:	36/37/38
Safety:	26-36
PSA:	20.23000
LogP:	2.67140

Synthetic route

: Carbonic acid allyl ester (Z)-3,7-dimethyl-octa-2,6-dienyl ester

: 106-25-2
Nerol

Conditions

Conditions	Yield
With palladium diacetate; sodium azide; trisodium tris(3-sulfophenyl)phosphine In water; acetonitrile at 25℃; for 1h;	98%

: 5392-40-5
(E/Z)-3,7-dimethyl-2,6-octadienal

: 106-25-2
Nerol

Conditions

Conditions	Yield
With isopropyl alcohol; zirconium(IV) oxide for 6h; Rate constant; Heating;	97%
With isopropyl alcohol; zirconium(IV) oxide for 6h; Heating;	97%
With sodium formate; RuCl2(m-SPPh2)2 In water at 80℃; for 7h;	95%

: 80873-76-3
1-(tert-butyldimethylsiloxy)-3,7-dimethyl-2,6-octadiene

: 106-25-2
Nerol

Conditions

Conditions	Yield
With acetonyltriphenylphosphonium bromide In methanol; dichloromethane at 20℃; for 0.0833333h;	95%
In methanol; dichloromethane for 3.66667h; Irradiation;
In methanol; dichloromethane for 3.66667h; Product distribution; Irradiation; other silyl ethers; phenanthrene, var. time;

: 2-((Z)-3,7-Dimethyl-octa-2,6-dienyloxymethyl)-1,3-dimethyl-benzene

: 106-25-2
Nerol

Conditions

Conditions	Yield
With lithium; ethylenediamine In tetrahydrofuran at -10℃; for 2h;	93%

: 52537-25-4
(Z)-1-(allyloxy)-3,7-dimethylocta-2,6-diene

: 106-25-2
Nerol

Conditions

Conditions	Yield
With samarium diiodide; water; isopropylamine In tetrahydrofuran at 20℃; for 0.0333333h;	88%

: 106-26-3
cis-3,7-dimethyl-2,6-octadienal

: 106-25-2
Nerol

Conditions

Conditions	Yield
With indium tri-isopropoxide supported on mesoporous SBA-15 In isopropyl alcohol at 80℃; for 7h; Reagent/catalyst; Meerwein-Ponndorf-Verley Reduction; Inert atmosphere; Schlenk technique; chemoselective reaction;	87.6%
With potassium hydroxide; isopropyl alcohol; dichlorotetrakis(dimethylsulfoxide)ruthenium at 20℃; for 3h;	86.8%
With Triisopropyl borate; isopropyl alcohol at 27℃; for 20h; Kinetics; Reagent/catalyst; Meerwein-Ponndorf-Verley reduction; Inert atmosphere; chemoselective reaction;	83.1%

: 70473-31-3
neryl 2-tetrahydropyranyl ether

: 106-25-2
Nerol

Conditions

Conditions	Yield
ammonium cerium(IV) nitrate In alkaline aq. solution; acetonitrile at 70℃; for 2h; pH=8; Decomposition;	86%
With tin(ll) chloride In methanol Substitution;	80%
With boron trifluoride diethyl etherate; dimethylthio-dimethyl-tin In toluene at -20 - 0℃; for 12h;	82 % Chromat.

: 13058-12-3
ethyl 3,7-dimethyl-2,6-octadienoate

: 106-25-2
Nerol

Conditions

Conditions	Yield
With lithium aluminium tetrahydride	81%
With diisobutylaluminium hydride In diethyl ether; hexane at -78 - 20℃; for 12.5h;	0.9 g

: 74323-42-5
morpholide of 1-hydroxy-3,7-dimethylocta-2Z,6-diene-4-sulfonic acid

A: 106-25-2
Nerol

B: 16750-94-0
2,6-dimethyl-2,5-octadien-8-ol

Conditions

Conditions	Yield
With dibenzo-18-crown-6; sodium In tetrahydrofuran; benzene-d6 at -70℃; for 0.0333333h;	A 75% B 4%
With dibenzo-18-crown-6; sodium In ammonia at -70℃; for 2h;	A 75% B 4%
With sodium; tert-butyl alcohol In benzene-d6 at -70℃; Yield given. Yields of byproduct given;
With lithium; tert-butyl alcohol In ammonia at -70℃; Product distribution; also Na, (DB18C6) or Na, tBuOH in NH3;
With lithium In diethyl ether; ammonia at -65℃; Product distribution; other reagent, solvent, temperature;

: 141-12-8
neryl acetate

: 106-25-2
Nerol

Conditions

Conditions	Yield
With tris(2,4,6-trimethoxyphenyl)phosphine In methanol at 50℃; for 24h;	73%

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Chemistry

MF: C₁₀H₁₈O
Synonyms: (2Z)-3,7-Dimethyl-2,6-octadien-1-ol;(Z)-Geraniol;2,6-Octadien-1-ol,3,7-dimethyl-,(Z)-;2-cis-3,7-Dimethyl-2,6-octadien-1-ol;3,7-dimethyl-octa-2cis,6-dien-1-ol;6-Octadien-1-ol,3,7-dimethyl-,(Z)-2;7-dimethyl-6-octadien-1-o(z)-3;beta-nerol
MW: 154.25
EINECS: 203-378-7
bp : 103-105 °C9 mm Hg(lit.)
density : 0.876 g/mL at 25 °C(lit.)
refractive index : n20/D 1.474(lit.)
FEMA : 2770
Fp : 226 °F
Merck : 14,6475
BRN : 1722455

Uses

NEROL is used in perfumery.

Safety Profile

Hazard Codes : Xi
Risk Statements : 36/37/38
Safety Statements : 26-36
WGK Germany : 2
RTECS : RG5840000