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106-44-5

Basic Information
CAS No.: 106-44-5
Name: Phenol,4-methyl-
Molecular Structure:
Molecular Structure of 106-44-5 (Phenol,4-methyl-)
Formula: C7H8O
Molecular Weight: 108.14
Synonyms: 4-Methylphenol;Para-cresol;p-Cresol;1-Hydroxy-4-methylbenzene;1-Methyl-4-hydroxybenzene;4-Hydroxytoluene;Paramethyl phenol;FEMA Number 2337;FEMA No. 2337;UNII-1MXY2UM8NV;p-Cresylic acid;p-Hydroxytoluene;p-Tolyl alcohol;p-Toluol;
EINECS: 203-398-6
Density: 1.034 g/cm3
Melting Point: 32-34 °C(lit.)
Boiling Point: 202 °C at 760 mmHg
Flash Point: 81 °C
Solubility: 20 g/L (20 ºC)
Appearance: colourless to pink crystalline
Hazard Symbols: ToxicT,IrritantXi
Risk Codes: 24/25-34-39/23/24/25-23/24/25
Safety: 36/37/39-45-36/37
Transport Information: UN 3455 6.1/PG 2
PSA: 20.23000
LogP: 1.70060
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    Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns

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    Business Type:Manufacturers

    Tel:0731-85567275

    Address:No.10048, xiangjiang centry bulding ,kaifu district ,changsha city ,Hunan

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  • p-Cresol

  • Casno:

    106-44-5

    p-Cresol

    Min.Order: 1 Gram

    FOB Price:  USD $ 0.0-0.0/Gram

    Hangzhou KieRaychem Co.,Ltd.is located in Yuhang District of Hangzhou City and specialized in the chemical product customization, development, sales, import and export. Current business is focused on fine chemicals, pharmaceutical materials and int

    Hangzhou KieRaychem Co.,Ltd.is located in Yuhang District of Hangzhou City and specialized in the chemical product customization, development, sales, import and export. Current bus

  •  Hangzhou KieRay Chem Co.,Ltd.

     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:+86-15336573147

    Address:Room 260, Building 3, No. 76 Xingqiao North Road, Xingqiao Street, Yuhang District, Hangzhou City, Zhejiang Province, China

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  • SAGECHEM/4-methylphenol

  • Casno:

    106-44-5

    SAGECHEM/4-methylphenol

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0/

    SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe

    SAGECHEM is a chemical R&D, manufacturing and distribution company since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and

  •  SAGECHEM LIMITED

     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:+86-571-86818502

    Address:5Fl. 501Room, Tower A, New Youth Plaza, 8 Jia Shan Road, Hangzhou, China

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  • 4-methylphenol

  • Casno:

    106-44-5

    4-methylphenol

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0/

    Capability on chemical synthesis1. Beijing High-Tech Enterprises2. Strong R&D Team3. 8 years of experiences in R & D of high-tech Catalyst;4. 5000 production techniques, 69 items of national patents, and 360 kinds of products on sales;5. The producti

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  •  Beijing Greenchem Technology Co.,Ltd.(Qingdao Greenchem international Trading Co.,Ltd)

    China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:010-82156189/60281050

    Address:Room 538 Expert International Mansion, No. 26, Houtunnan Roada, Haidian District, Beijing

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  • Phenol,4-methyl-

  • Casno:

    106-44-5

    Phenol,4-methyl-

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0/

    1, High quality with competitive price:2, Fast and safe delivery3.Excellent pre-sales and after-sales service4. Well-trained and professional technologist and sales with rich experience in the field for 5-10 yearsAppearance:see detailed specification

    Hangzhou Clap Technology Co., Ltd is a leading manufacturer and supplier of API, Pharma intermediates, organic and inorganic compounds, rare earth, pesticide, raw drugs, fine chemi

  •  HANGZHOU CLAP TECHNOLOGY CO,.LTD

     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:86-571-56972507

    Address:Room 4198,Floor 4,No.4,ShanXian Road XiaCheng District,HangZhou city,ZheJiang province,China

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  • p-Cresol

  • Casno:

    106-44-5

    p-Cresol

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0/

    high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

    Kono Chem Co.,Ltd is a leading producer of standardized herbal extracts, natural active ingredients and APIs for pharmaceutical, health food and cosmetic industries. Annually, mo

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     China (Mainland)  |  Contact Details

    Business Type:Other

    Tel:86-29-86107037-8015

    Address:No.11 Daqing Road,Lianhu District,Xi’an 710082,China

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  • p-Cresol

  • Casno:

    106-44-5

    p-Cresol

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0/

    high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,or Intermediates,fine chemicals Transportation:air,sea,courier

    GIHI CHEMICALS CO.,LIMITED, its former company is a small manufacturer who is specialized in the production of ester products which are used in the daily chemicals ,cosmetic produc

  •  GIHI CHEMICALS CO.,LIMITED

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    Business Type:Lab/Research institutions

    Tel:571-86217390

    Address:Huacai International Building,Sandun,Westlake District,Hangzhou 310030,Zhejiang,China

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  • Para-Cresol

  • Casno:

    106-44-5

    Para-Cresol

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0/

    Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

    Xiamen Aeco Chemical Industrial Co., Ltd(same as Aecochem Corp.) An ISO 9001:2015 Certified Company Your Partner in China, a Professional chemical raw material supplier, our

  •  Aecochem Corp.

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    Business Type:Manufacturers

    Tel:+86-592 599 8717

    Address:No 611 Sishui Road,Huli

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Consensus Reports

Community Right-To-Know List. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.

Standards and Recommendations

OSHA PEL: TWA 5 ppm (skin)
ACGIH TLV: TWA 5 ppm
NIOSH REL: (Cresol) TWA 10 mg/m3
DOT Classification:  6.1; Label: Poison

Analytical Methods

For occupational chemical analysis use NIOSH: Cresols, 2001; Phenol and p-Cresol in Urine, 8305.

Specification

The P-cresol, with the CAS register number 106-44-5, has other names as 1-methyl-4-hydroxybenzene;4-cresol;4-methyl-pheno;cresol, para;cresol,para-isomer;femanumber2337;paracresol;para-cresol .

The physical properties of this kind of chemcial are as followings: (1)#H bond acceptors:  1  ; (2)#H bond donors:  1  ; (3)#Freely Rotating Bonds:  1  ; (4)Polar Surface Area:  20.23  ; (5)Index of Refraction:  1.545  ; (6)Molar Refractivity:  32.95 cm3  ; (7)Molar Volume:  104.1 cm3  ; (8)Polarizability:  13.06 ×10-24 cm ; (9)Surface Tension:  38.8 dyne/cm  ; (10)Density:  1.038 g/cm3  ; (11)Flash Point:  81 °C  ; (12)Enthalpy of Vaporization:  45.61 kJ/mol  ; (13)Boiling Point:  202 °C at 760 mmHg  ; (14)Vapour Pressure:  0.211 mmHg at 25°C .

It is a kind of colourless to pink crystalline with smoky and herb smellings. It is soluble in water and aqueouscaustic and other organic solvent. Natuals exsit in Ylang Ylang oil, strawberry, cheese, coffee, and cocoa.

As for its usage, it is usually used in organic synthesis, and also be the material for making the antioxidant 264 and rubber antioxidant. When in plastic industry, it could be used as phenolic resin and plasticizer and then as the disinfectant in pharmaceutics. Besides, it is used as the raw material of dyeing and pesticide. Its product categories are including the following: industrial/fine chemicals;building blocks for liquid crystals;functional materials;phenols (building blocks for liquid crystals).
 
Being a kind of toxic chemical, it at low levels cause damage to health and if in contact with skin or swallowed or by inhalation, it will be very dangerous. Besides, it is irritant as it may cause inflammation to the skin or other mucous membranes and may causes burns. Then, it has danger of very serious irreversible effects. So while dealing with this chemical, you should be very cautious. Wear suitable protective clothing, gloves and eye/face protection and if in case of accident or if you feel unwell seek medical advice immediately (show the label where possible). You could also get the safety information from refering to WGK Germany 1.

In addition, you could refer to the following data information to get the molecular structure:
SMILES:Cc1ccc(O)cc1
InChI:InChI=1/C7H8O/c1-6-2-4-7(8)5-3-6/h2-5,8H,1H3
InChIKey:IWDCLRJOBJJRNH-UHFFFAOYAN

Below are the toxicity information of this kind of chemcial:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
cat LDLo subcutaneous 80mg/kg (80mg/kg)   Journal of Pharmacology and Experimental Therapeutics. Vol. 80, Pg. 233, 1944.
frog LDLo subcutaneous 150mg/kg (150mg/kg)   "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1361, 1935.
guinea pig LDLo subcutaneous 200mg/kg (200mg/kg)   "Handbook of Toxicology," 4 vols., Philadelphia, W.B. Saunders Co., 1956-59Vol. 5, Pg. 58, 1959.
mouse LD50 intraperitoneal 25mg/kg (25mg/kg)   "Handbook of Toxicology," 4 vols., Philadelphia, W.B. Saunders Co., 1956-59Vol. 5, Pg. 58, 1959.
mouse LD50 oral 344mg/kg (344mg/kg)   Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 18(2), Pg. 58, 1974.
mouse LD50 unreported 160mg/kg (160mg/kg)   British Journal of Cancer. Vol. 6, Pg. 160, 1952.
 
mouse LDLo subcutaneous 150mg/kg (150mg/kg)   "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1361, 1935.
rabbit LD50 skin 301mg/kg (301mg/kg) BEHAVIORAL: TREMOR

KIDNEY, URETER, AND BLADDER: OTHER CHANGES

GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS
BIOFAX Industrial Bio-Test Laboratories, Inc., Data Sheets. Vol. 5-5/1969,
rabbit LDLo intravenous 180mg/kg (180mg/kg)   Journal of Pharmacology and Experimental Therapeutics. Vol. 80, Pg. 233, 1944.
rabbit LDLo oral 620mg/kg (620mg/kg)   Journal of Pharmacology and Experimental Therapeutics. Vol. 80, Pg. 233, 1944.
rabbit LDLo subcutaneous 300mg/kg (300mg/kg)   "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1361, 1935.