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1066-40-6

Basic Information
CAS No.: 1066-40-6
Name: hydroxytrimethylsilane
Article Data: 125
Molecular Structure:
Molecular Structure of 1066-40-6 (hydroxytrimethylsilane)
Formula: C3H10 O Si
Molecular Weight: 90.1973
Synonyms: Silanol,trimethyl- (6CI,8CI,9CI); Hydroxytrimethylsilane; Trimethylhydroxysilane;Trimethylsilanol; Trimethylsilyl alcohol
Density: 0.81g/cm3
Melting Point: -4.5 °C
Boiling Point: 75°Cat760mmHg
Flash Point: °C
Solubility: Soluble in water (1.00 mg/ml).
Hazard Symbols: F
Risk Codes: 11
PSA: 20.23000
LogP: 0.81360
Synthetic route
81631-74-5

4-n-butyl-1-trimethylsilylbenzene

A

1066-40-6

Trimethylsilanol

B

104-51-8

1-butylbenzene

Conditions
ConditionsYield
With Montmorillonite KSF In water at 20℃;A n/a
B 99%
121386-65-0, 145428-84-8, 145428-85-9

trimethylsilyl-2-hydroxypropane

A

1066-40-6

Trimethylsilanol

B

187737-37-7

propene

C

107-46-0

Hexamethyldisiloxane

Conditions
ConditionsYield
With hydrogenchloride In methanol at 40℃; Rate constant; var. +>;A n/a
B 98%
C n/a
3768-55-6

N-trimethylsilylaniline

A

1066-40-6

Trimethylsilanol

B

369-57-3

benzenediazonium tetrafluoroborate

Conditions
ConditionsYield
With nitrosonium tetrafluoroborate In dichloromethane Ambient temperature;A n/a
B 98%
14642-79-6

benzyloxy-trimethylsilane

1066-40-6

Trimethylsilanol

Conditions
ConditionsYield
With palladium-platinum; hydrogen; aniline In N,N-dimethyl acetamide at 20℃; for 2h;97%
3768-55-6

N-trimethylsilylaniline

A

1066-40-6

Trimethylsilanol

B

100-34-5

benzene diazonium chloride

Conditions
ConditionsYield
With nitrosylchloride In dichloromethane for 0.166667h; Ambient temperature;A n/a
B 96%
3768-55-6

N-trimethylsilylaniline

A

1066-40-6

Trimethylsilanol

B

71290-63-6

benzenediazonium bromide

Conditions
ConditionsYield
With nitrosyl bromide In dichloromethane for 0.166667h; Ambient temperature;A n/a
B 94%
3768-55-6

N-trimethylsilylaniline

14848-27-2

nitrosonium trifluoromethanesulfonate

A

1066-40-6

Trimethylsilanol

B

90756-34-6

benzenediazonium trifluoromethanesulfonate

Conditions
ConditionsYield
In dichloromethane Ambient temperature;A n/a
B 93%

0.5C4H10O2*C6H18NSi2(1-)*2Cl(1-)*Pr(3+)

A

1066-40-6

Trimethylsilanol

B

praseodymium(III) hydroxide

C

107-46-0

Hexamethyldisiloxane

Conditions
ConditionsYield
With water In hexane deaerated water addn. to Pr-compd. soln., soln. decanting from ppt.; GLC, IR spectroscopy;A <1
B 92.3%
C 73.8%
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

26456-05-3

10-methylacridinium perchlorate

A

1066-40-6

Trimethylsilanol

B

4217-54-3

9,10-dihydro-10-methylacridine

Conditions
ConditionsYield
With water In [D3]acetonitrile; acetonitrile for 4h; Irradiation;A n/a
B 88%
201230-82-2

carbon monoxide

2170-06-1

1-Phenyl-2-(trimethylsilyl)acetylene

A

1066-40-6

Trimethylsilanol

B

83-33-0

inden-1-one

Conditions
ConditionsYield
With water; triethylamine; triphenylphosphine; chloro(1,5-cyclooctadiene)rhodium(I) dimer In tetrahydrofuran at 160℃; under 51485.6 Torr; for 4h; Product distribution; other phosphine ligand, other rhodium complex, other temp., other additives, other solv.;A n/a
B 86%
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Chemistry

Molecular Structure:

Molecular Formula: C3H10OSi
Molecular Weight: 90.1964
IUPAC Name: Hydroxy(trimethyl)silane
Synonyms of Hydroxytrimethylsilane (CAS NO.1066-40-6): CCRIS 1320 ; EINECS 213-914-1 ; Hydroxytrimethylsilane ; Silanol, 1,1,1-trimethyl- ; Silanol, trimethyl- ; Trimethylsilanol
CAS NO: 1066-40-6
Product Categories: TSCA Flag P [A commenced PMN (Premanufacture Notice) substance] 
Index of Refraction: 1.386
Molar Refractivity: 26.19 cm3
Molar Volume: 111.2 cm3
Surface Tension: 17.4 dyne/cm
Density: 0.81 g/cm3
Enthalpy of Vaporization: 36.86 kJ/mol
Boiling Point: 75 °C at 760 mmHg
Vapour Pressure of Hydroxytrimethylsilane (CAS NO.1066-40-6): 73.9 mmHg at 25°C