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| CAS No.: | 108-60-1 |
|---|---|
| Name: | BIS(2-CHLOROISOPROPYL)ETHER |
| Article Data: | 10 |
| Molecular Structure: | |
|
|
|
| Formula: | C6H12 Cl2 O |
| Molecular Weight: | 171.067 |
| Synonyms: | Ether,bis(2-chloro-1-methylethyl) (6CI,7CI,8CI);2,2'-Dichlorodiisopropyl ether;2,2'-Oxybis(1-chloropropane);Bis(1-chloro-2-propyl) ether;Bis(2-chloro-1-methylethyl) ether;DCIP;DCIP (nematocide);NSC 2849;b,b'-Dichlorodiisopropyl ether; |
| EINECS: | 203-598-3 |
| Density: | 1.086 g/cm3 |
| Melting Point: | -97 to -102ºC |
| Boiling Point: | 187 °C at 760 mmHg |
| Flash Point: | 36.4 °C |
| Solubility: | Solubility in water, g/100 ml at 20ºC: 0.2, poor |
| Appearance: | COLOURLESS TO BROWN, OILY LIQUID |
| Hazard Symbols: | Toxic by ingestion and inhalation, strong irritant. |
| Risk Codes: | 22-36/37/38-39/23/24/25-23/24/25-11 |
| Safety: | Poison by ingestion. Moderately toxic by skin contact and inhalation. An eye irritant. Questionable carcinogen. Mutation data reported. A corrosive material. Moderate fire hazard when exposed to heat, flame, or powerful oxidizers. Incompatible with oxidizing materials. To fight fire, use water to blanket fire; foam, CO2, dry chemical. When heated to decomposition it emits highly toxic fumes of Cl−. See also ETHERS. |
| PSA: | 9.23000 |
| LogP: | 2.95280 |
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- 187737-37-7
propene
- 108-60-1
bis(1-chloro-2-propyl) ether
| Conditions | Yield |
|---|---|
| With metal salt; water; chlorine |
- 77-78-1
dimethyl sulfate
- 127-00-4
1-Chloro-2-propanol
A
- 5390-72-7
2-methoxy-1-chloropropane
B
- 108-60-1
bis(1-chloro-2-propyl) ether
| Conditions | Yield |
|---|---|
| With sulfuric acid |
| Conditions | Yield |
|---|---|
| With water; chlorine | |
| With water; chlorine |
- 187737-37-7
propene
A
- 26198-63-0, 78-87-5
1,2-Dichloropropane
B
- 629-36-7
bis(3-chloropropyl)ether
C
- 108-60-1
bis(1-chloro-2-propyl) ether
D
- 127-00-4
1-Chloro-2-propanol
| Conditions | Yield |
|---|---|
| With hypochloric acid; chlorine In butanone at 20℃; for 0.00833333h; in a rotor-pulsation apparatus; Title compound not separated from byproducts; | A 15.8 % Spectr. B n/a C n/a D 68.6 % Spectr. |
| With hypochloric acid; chlorine In butanone at 20℃; for 0.00833333h; Product distribution; Mechanism; yield of products at different temperatures and in different solvents, in a rotor-pulsation apparatus; | A 15.8 % Spectr. B n/a C n/a D 68.6 % Spectr. |
- 187737-37-7
propene
- 127-00-4
1-Chloro-2-propanol
A
- 26198-63-0, 78-87-5
1,2-Dichloropropane
B
- 108-60-1
bis(1-chloro-2-propyl) ether
C
- 83270-31-9
1-chloro-2-propyl 2-chloro-1-propyl ether
| Conditions | Yield |
|---|---|
| With chlorine In dichloromethane at -20℃; Yield given. Yields of byproduct given; |
- 187737-37-7
propene
- 75-56-9, 16033-71-9
methyloxirane
A
- 26198-63-0, 78-87-5
1,2-Dichloropropane
B
- 108-60-1
bis(1-chloro-2-propyl) ether
C
- 54460-96-7
bis-(2-chloro-propyl) ether
D
- 83270-31-9
1-chloro-2-propyl 2-chloro-1-propyl ether
| Conditions | Yield |
|---|---|
| With chlorine In dichloromethane at -20℃; Yield given. Further byproducts given. Yields of byproduct given; |
| Conditions | Yield |
|---|---|
| durch Propylenoxyd; |
- 187737-37-7
propene
- 7732-18-5
water
- 7782-50-5
chlorine
A
- 26198-63-0, 78-87-5
1,2-Dichloropropane
B
- 108-60-1
bis(1-chloro-2-propyl) ether
C
- 78-95-5
chloroacetone
D
- 127-00-4
1-Chloro-2-propanol
| Conditions | Yield |
|---|---|
| at 34 - 43℃; |
- 187737-37-7
propene
- 7732-18-5
water
- 7782-50-5
chlorine
A
- 26198-63-0, 78-87-5
1,2-Dichloropropane
B
- 108-60-1
bis(1-chloro-2-propyl) ether
| Conditions | Yield |
|---|---|
| at 60℃; | |
| at 60℃; |
- Total:11 Page 1 of 1 1
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Chemistry
Bis(2-chloroisopropyl) ether ,its CAS register number is 108-60-1,it's called for DCIP ; Dichloroisopropyl ether ; Bis-(2-chloro-1-methylethyl)ether ; (2-Chloro-1-methylethyl) ether ; (2-Chloro-1-methylethyl)ether ; 1-Chloro-2-(2-chloro-1-methylethoxy)propane ; 2,2’-Dichlorodiisopropylether ; Nemamol ; Isopropylchlorex ; Pichloram ,and so on. Bis(2-chloroisopropyl) ether (CAS No.108-60-1 ) is colorless to light brown liquid.
IUPAC Name: 1-Chloro-2-(1-chloropropan-2-yloxy)propane
CAS: 108-60-1
Molecular Formula: C6H12Cl2O
Molecular Weight: 171.06
Molecular structure:
EINECS: 203-598-3
Storage temp.: 0-6°C
ACD/LogD (pH 5.5): 1.88
ACD/LogD (pH 7.4): 1.88
ACD/BCF (pH 5.5): 15.84
ACD/BCF (pH 7.4): 15.84
ACD/KOC (pH 5.5): 251.45
ACD/KOC (pH 7.4): 251.45
H bond acceptors: 1
H bond donors: 0
Freely Rotating Bonds: 4
Index of Refraction: 1.436
Molar Refractivity: 41.2 cm3
Molar Volume: 157.4 cm3
Polarizability: 16.33 10-24cm3
Surface Tension: 27.9 dyne/cm
Density: 1.086 g/cm3
Flash Point: 36.4 °C
Enthalpy of Vaporization: 40.59 kJ/mol
Boiling Point: 187 °C at 760 mmHg
Vapour Pressure: 0.887 mmHg at 25°C
Uses
Bis(2-chloroisopropyl) ether (CAS No.108-60-1 ) is commonly used as the standard agent for analysis.
Toxicity Data With Reference
| 1. | eye-rbt 500 mg open | AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 4 (1951),119. | ||
| 2. | mmo-sat 1 mL/plate/3H | DHEFDK HEW Publication (FDA. United States). (Washington, DC) 19??-1979(?). FDA-78-1046 ,1978. | ||
| 3. | mma-sat 333 µg/plate | ENMUDM Environmental Mutagenesis. 8 (Suppl 7)(1986),1. | ||
| 4. | orl-rat LD50:240 mg/kg | AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 4 (1951),119. | ||
| 5. | skn-rat LD50:>2 g/kg | PEMNDP Pesticide Manual. 9 (1991),83. | ||
| 6. | orl-mus LD50:503 mg/kg | FMCHA2 Farm Chemicals Handbook .(Meister Publishing, 37841 Euclid Ave.,Willoughy, OH.: 44094)1991,C216. | ||
| 7. | ihl-rat LCLo:700 ppm/5H | BJIMAG British Journal of Industrial Medicine. 27 (1970),1. | ||
| 8. | skn-rbt LD50:3000 mg/kg | AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 4 (1951),119. |
Consensus Reports
IARC Cancer Review: Group 3 IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man 7 (1987),p. 56.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Limited Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man 41 (1986),p. 149.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . NCI Carcinogenesis Bioassay (gavage); No Evidence: rat NCITR* National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD 20014) No. NCI-CG-TR-191 ,1979. . Community Right-To-Know List. Reported in EPA TSCA Inventory.
Safety Profile
Poison by ingestion. Moderately toxic by skin contact and inhalation. An eye irritant. Questionable carcinogen. Mutation data reported. A corrosive material. Moderate fire hazard when exposed to heat, flame, or powerful oxidizers. Incompatible with oxidizing materials. To fight fire, use water to blanket fire; foam, CO2, dry chemical. When heated to decomposition it emits highly toxic fumes of Cl−.
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Risk Statements: 22-36/37/38-39/23/24/25-23/24/25-11 (R22:Harmful if swallowed. R36/37/38:Irritating to eyes, respiratory system and skin. R23/24/25:Toxic by inhalation, in contact with skin and if swallowed. R11:Highly flammable.)
Safety Statements: 26-45-36/37-16-7 (S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S36/37:Wear suitable protective clothing and gloves. S16:Keep away from sources of ignition. S7:Keep container tightly closed.)
RIDADR: 2490
RTECS: KN1750000
HazardClass: 6.1(a)
PackingGroup: II
Standards and Recommendations
DOT Classification: 6.1; Label: Poison
Specification
Removal in wastewater treatment of Bis(2-chloroisopropyl) ether (CAS No.108-60-1 ) can be stated as follows:
Total removal:8.29 percent
Total biodegradation:0.10 percent
Total sludge adsorption:2.83 percent
Total to Air:5.37 percent
(using 10000 hr Bio P,A,S)