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| CAS No.: | 109-53-5 |
|---|---|
| Name: | Isobutyl vinyl ether |
| Article Data: | 17 |
| Cas Database | |
| Molecular Structure: | |
|
|
|
| Formula: | C6H12O |
| Molecular Weight: | 100.161 |
| Synonyms: | Isobutyl vinyl ether;Lutonal LR 8500;NSC 8265;Vinoflex MO 400;Vinyl isobutyl ether;iso-Butyl vinyl ether;Ether,isobutyl vinyl (8CI);1-(Ethenyloxy)-2-methylpropane;IVE;Isobutanol vinylether;Isobutoxyethene; |
| EINECS: | 203-678-8 |
| Density: | 0.773 g/cm3 |
| Melting Point: | -112 °C |
| Boiling Point: | 83 °C at 760 mmHg |
| Flash Point: | 8°F |
| Solubility: | Insoluble (soluble in alcohol and ether) |
| Appearance: | clear colourless liquid |
| Hazard Symbols: |
 F, Xi
|
| Risk Codes: | 11-38 |
| Safety: | 16-23-24/25-33-37 |
| Transport Information: | UN 1304 3/PG 2 |
| PSA: | 9.23000 |
| LogP: | 1.80250 |
- 1095382-05-03H-Imidazo[4,5-b]pyridine, 6-bromo-7-[4-[(5-methyl-3-isoxazolyl)methyl]-1-piperazinyl]-2-[4-(4-methyl-1-piperazinyl)phenyl]-
- 109543-53-52-Methylthiazolo(4,5-c)quinoline ethanesulfonate
- 109545-01-9ETHYL-D3 ACETATE
- 109545-84-8b-D-Mannopyranoside,O-(1R)-4-O-(2,4-dihydroxy-6-methylbenzoyl)-2,3-O-methylene-D-xylopyranosylidene-(1®3-4)-a-L-lyxopyranosyl O-2,3,6-trideoxy-3-C-methyl-4-O-methyl-3-nitro-a-L-arabino-hexopyranosyl-(1®3)-O-2,6-dideoxy-4-O-(3,5-dichloro-4-hydroxy-2-methoxy-6-methylbenzoyl)-b-D-arabino-hexopyranosyl-(1®4)-O-(1R)-2,6-dideoxy-D-arabino-hexopyranosylidene-(1®3-4)-O-6-deoxy-3-C-methyl-b-D-mannopyranosyl-(1®3)-O-6-deoxy-4-O-methyl-b-D-galactopyranosyl-(1®4)-2,6-di-O-methyl-
- 109-54-63-Chloro-1-(N,N-dimethyl)propylamine
- 109552-15-0Phosphonic acid,(3-amino-1-hydroxypropylidene)bis-, disodium salt, pentahydrate (9CI)
- 109555-87-5Methanone,1H-indol-3-yl-1-naphthalenyl-
- 1095565-81-34(5H)-Thiazolone, 2-[(1S,2S,4R)-bicyclo[2.2.1]hept-2-ylamino]-5-methyl-5-(1-methylethyl)-, (5S)-
- 1095565-87-94(5H)-Thiazolone, 2-[(1S,2S,4R)-bicyclo[2.2.1]hept-2-ylamino]-5-methyl-5-(1-methylethyl)-, (5S)- (methanesulfonate)
- 109-55-73-Dimethylaminopropylamine
| Conditions | Yield |
|---|---|
| With sodium hydroxide; cesium fluoride at 135 - 140℃; under 7600 - 10640 Torr; for 2h; | 82% |
| With potassium hydroxide at 135 - 155℃; | |
| at 140℃; under 4500.45 Torr; |
| Conditions | Yield |
|---|---|
| With sodium hydrogen sulfate | |
| With quinoline; phosphorus pentoxide |
- 19865-33-9
α-chloroethyl isobutyl ether
- 109-53-5
isobutyl vinyl ether
| Conditions | Yield |
|---|---|
| With pyridine |
| Conditions | Yield |
|---|---|
| With N,N-diethylaniline at 185 - 190℃; |
| Conditions | Yield |
|---|---|
| With zinc diacetate at 210 - 220℃; | |
| With copper(I) monacetylide at 210 - 220℃; |
| Conditions | Yield |
|---|---|
| Stage #1: 2-methyl-propan-1-ol; acetaldehyde With hydrogenchloride In dibutyl ether at 10 - 15℃; Stage #2: With 3-Methylpyridine In dibutyl ether at 50℃; for 1h; |
| Conditions | Yield |
|---|---|
| With potassium fluoride; water; potassium hydroxide In neat (no solvent) at 160℃; for 13h; Temperature; Autoclave; | 75.8 %Spectr. |
- 109-53-5
isobutyl vinyl ether
- 59938-06-6
(E)-4-Ethoxy-1,1,1-trifluoro-3-buten-2-one
- 1214317-50-6
4-Ethoxy-2-isobutoxy-6-trifluoromethyl-3,4-dihydro-2H-pyran
| Conditions | Yield |
|---|---|
| With hydroquinone at 80℃; for 30h; | 100% |
- 109-53-5
isobutyl vinyl ether
| Conditions | Yield |
|---|---|
| In phosgene | 100% |
- 109-53-5
isobutyl vinyl ether
| Conditions | Yield |
|---|---|
| With toluene-4-sulfonic acid In tetrahydrofuran at 20℃; for 4h; Cooling; Large scale; | 100% |
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Chemistry
IUPAC Name: 1-ethenoxy-2-methylpropane
Empirical Formula: C6H12O
Molecular Weight: 100.1589g/mol
Structure of Propane,1-(ethenyloxy)-2-methyl- (CAS NO.109-53-5):
EINECS: 203-678-8
Index of Refraction: 1.398
Molar Refractivity: 31.27 cm3
Molar Volume: 129.4 cm3
Polarizability: 12.39×10-24 cm3
Surface Tension: 20.9 dyne/cm
Density: 0.773 g/cm3
vapor density 3.45 (vs air)
Melting point: -112 °C
Boiling Point: 83 °C at 760 mmHg
Enthalpy of Vaporization: 31.01 kJ/mol
Vapour Pressure: 85.6 mmHg at 25°C
storage temp.: Flammables area
Water Solubility: 0.7 g/L (25 oC)
Canonical SMILES: CC(C)COC=C
InChI: InChI=1S/C6H12O/c1-4-7-5-6(2)3/h4,6H,1,5H2,2-3H3
InChIKey: OZCMOJQQLBXBKI-UHFFFAOYSA-N
Toxicity Data With Reference
| 1. | orl-rat LD50:17 g/kg | AIHAAP American Industrial Hygiene Association Journal. 23 (1962),95. | ||
| 2. | ihl-rat LCLo:16,000 ppm/4H | AIHAAP American Industrial Hygiene Association Journal. 23 (1962),95. | ||
| 3. | skn-rbt LD50:20 g/kg | AIHAAP American Industrial Hygiene Association Journal. 23 (1962),95. |
Consensus Reports
Reported in EPA TSCA Inventory.
Safety Profile
Very mildly toxic by ingestion, inhalation, and skin contact. A very dangerous fire hazard when exposed to heat, flame, oxidizers. Severe explosion hazard when exposed to sparks or open flame. Can react vigorously with oxidizing materials. When heated to decomposition it emits acrid smoke and fumes. To fight fire, use alcohol foam, CO2, dry chemical. See also ETHERS.
Hazard Codes: 
F,
Xi
Risk Statements: 11-38
R11:Highly flammable.
R38:Irritating to skin.
Safety Statements: 16-23-24/25-33-37
S16:Keep away from sources of ignition.
S23:Do not breathe vapour.
S24/25:Avoid contact with skin and eyes.
S33:Take precautionary measures against static discharges.
S37:Wear suitable gloves.
RIDADR: UN 1304 3/PG 2
WGK Germany: 1
RTECS: KO1300000
F: 9
HazardClass: 3.1
PackingGroup: II
Standards and Recommendations
DOT Classification: 3; Label: Flammable Liquid
Specification
Propane,1-(ethenyloxy)-2-methyl- , its cas register number is 64058-30-6. It also can be called 2-Methyl-1-vinyloxypropane ; 4-01-00-02054 (Beilstein Handbook Reference) ; AI3-18425 ; IVE ; Isobutanol vinyl ether ; Isobutoxyethene ; Isobutyl vinyl ether ; Lutanol LR 8500 ; NSC 8265 ; Vinyl isobutyl ether .
Propane,1-(ethenyloxy)-2-methyl- (CAS NO.109-53-5) is a clear colourless liquid.