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111011-80-4

Basic Information
CAS No.: 111011-80-4
Name: 2-Propanone, 1-(5,5-dimethyl-1,3,2-dioxaphosphorinan-2-yl)-, P-oxide
Article Data: 8
Molecular Structure:
Molecular Structure of 111011-80-4 (2-Propanone, 1-(5,5-dimethyl-1,3,2-dioxaphosphorinan-2-yl)-, P-oxide)
Formula: C8H15O4P
Molecular Weight: 206.178
Synonyms: 2-Propanone, 1-(5,5-dimethyl-1,3,2-dioxaphosphorinan-2-yl)-, P-oxide;
PSA: 62.41000
LogP: 1.84150
Synthetic route
1005-69-2

2-methoxy-5,5-dimethyl-1,3,2-dioxaphosphorinane

3019-04-3

iodoacetone

111011-80-4

2-acetonyl-5,5-dimethyl-2-oxo-1,3,2-dioxaphosphorinane

Conditions
ConditionsYield
In diethyl ether for 7h; Heating;65.8%
1005-69-2

2-methoxy-5,5-dimethyl-1,3,2-dioxaphosphorinane

598-31-2

1-bromoacetone

A

873-97-2

2,5,5-trimethyl-1,3,2-dioxaphosphorinan-2-one

B

116944-17-3

5,5-dimethyl-2-oxo-2-(2-propenyloxy)-1,3,2-dioxaphosphorinane

C

111011-80-4

2-acetonyl-5,5-dimethyl-2-oxo-1,3,2-dioxaphosphorinane

Conditions
ConditionsYield
stirred at 20 deg C, causing an exothermic reaction, tepm. rose to 120 deg C;A 7%
B 35%
C 55%
at 60℃; for 1h;A 22%
B 20%
C 45%
Product distribution; effect of temperature;
1005-69-2

2-methoxy-5,5-dimethyl-1,3,2-dioxaphosphorinane

598-31-2

1-bromoacetone

111011-80-4

2-acetonyl-5,5-dimethyl-2-oxo-1,3,2-dioxaphosphorinane

Conditions
ConditionsYield
at 80℃; for 1h;51%
110907-85-2

5,5-dimethyl-2-trimethylsilyloxy-1,3,2-dioxaphosphorinane

3019-04-3

iodoacetone

111011-80-4

2-acetonyl-5,5-dimethyl-2-oxo-1,3,2-dioxaphosphorinane

Conditions
ConditionsYield
With cyclohexane-1,2-epoxide In acetonitrile Heating;43%
110907-85-2

5,5-dimethyl-2-trimethylsilyloxy-1,3,2-dioxaphosphorinane

3019-04-3

iodoacetone

A

116944-17-3

5,5-dimethyl-2-oxo-2-(2-propenyloxy)-1,3,2-dioxaphosphorinane

B

111011-80-4

2-acetonyl-5,5-dimethyl-2-oxo-1,3,2-dioxaphosphorinane

Conditions
ConditionsYield
With methyloxirane for 16h; Ambient temperature;A 4%
B 27%
533-58-4

2-Iodophenol

119713-39-2

5,5-dimethyl-2-oxo-2-(propa-1',2'-diene)-1,3,2-dioxaphosphorinane

A

2-(5,5-dimethyl-2-oxo-2λ5-[1,3,2]dioxaphosphinan-2-ylmethyl)-benzofuran

B

111011-80-4

2-acetonyl-5,5-dimethyl-2-oxo-1,3,2-dioxaphosphorinane

Conditions
ConditionsYield
With cesium fluoride; palladium diacetate In N,N-dimethyl-formamide at 90℃; for 24h;
40891-03-0

3-(dimorpholinomethyl)-1-nitrobenzene

111011-80-4

2-acetonyl-5,5-dimethyl-2-oxo-1,3,2-dioxaphosphorinane

111011-78-0

5,5-dimethyl-2-<1-(3-nitrophenyl)-3-oxo-1-buten-2-yl>-2-oxo-1,3,2-dioxaphosphorinane

Conditions
ConditionsYield
With trifluoroacetic acid In toluene 1.) 60 deg C, 30 min, 2.) 0-10 deg C, 3 h;93%
With trifluoroacetic acid In toluene for 2.5h; Ambient temperature;93.2%
119672-83-2

Isobutyl-[1-(3-nitro-phenyl)-meth-(E)-ylidene]-amine

111011-80-4

2-acetonyl-5,5-dimethyl-2-oxo-1,3,2-dioxaphosphorinane

115578-86-4

(E)-2,2-dimethyl-1,3-propanediyl α-acetyl-3-nitrostyrylphosphonate

Conditions
ConditionsYield
With acetic anhydride In benzene for 4h; Heating;91%
126597-33-9

9-oxo-9H-xanthene-4-carbaldehyde

14205-39-1

methyl (E)-3-aminocrotonate

111011-80-4

2-acetonyl-5,5-dimethyl-2-oxo-1,3,2-dioxaphosphorinane

5-(5,5-Dimethyl-2-oxo-2λ5-[1,3,2]dioxaphosphinan-2-yl)-2,6-dimethyl-4-(9-oxo-9H-xanthen-4-yl)-1,4-dihydro-pyridine-3-carboxylic acid methyl ester

Conditions
ConditionsYield
In isopropyl alcohol for 10h; Heating;70%
1078138-42-7

5,5-dimethyl-2-(1-phenylpropa-1,2-dien-1-yl)-1,3,2-dioxaphosphinane 2-oxide

111011-80-4

2-acetonyl-5,5-dimethyl-2-oxo-1,3,2-dioxaphosphorinane

(E)-3,5-bis(5,5-dimethyl-2-oxido-1,3,2-dioxaphosphinan-2-yl)-4-methyl-5-phenylpent-4-en-2-one

Conditions
ConditionsYield
With potassium carbonate In dimethyl sulfoxide at 90℃; for 8h; Schlenk technique; Sealed tube; Inert atmosphere;68%
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    2-Propanone, 1-(5,5-dimethyl-1,3,2-dioxaphosphorinan-2-yl)-, P-oxide 111011-80-4 Storage:Seal to avoid light preservation Application:2-Propanone, 1-(5,5-dimethyl-1,3,2-dioxaphosphorinan-2-yl)-, P-oxide 111011-80-4

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    2-Propanone, 1-(5,5-dimethyl-1,3,2-dioxaphosphorinan-2-yl)-, P-oxide Application:2-Propanone, 1-(5,5-dimethyl-1,3,2-dioxaphosphorinan-2-yl)-, P-oxide 111011-80-4

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    FOB Price:  USD $ 0.0-0.0

    Supply top quality products with a reasonable price Application:api

    Hebei Ruishun Trade Co.,Ltd registered capital one million, we have a production of pharmaceutical raw materials, pharmaceutical raw materials factory reagent r&d center, we do

  • Hebei Ruishun Trade Co.,Ltd

    China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:+86-311-68037669

    Address:WanDa commerce building ,yuhua district

       Inquiry Now

  • 2-Acetonyl-5,5-dimethyl-2-oxo-1,3,2-dioxaphosphorinane

  • Casno:

    111011-80-4

    2-Acetonyl-5,5-dimethyl-2-oxo-1,3,2-dioxaphosphorinane

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0

    Known for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers.Appearance:yellow to white solid Storage:keep sealed and keep from direct light Package:According client's requirements Application:Food

    Jinan YSPharma Biotechnology Co., Ltd is a large group specializing in contract manufacturing to the pharmaceutical, agrochemical and Fine chemicals with top quality products and s

  • coolpharm Ltd

    China (Mainland)  |  Contact Details

    Business Type:Other

    Tel:86-531-8233381 86-18678657237

    Address:Room 302,Building 1,Union Fortune Square, No. 2117,Tianchen Road,High-tech Zone,Jinan,Shandong,China

       Inquiry Now

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