Products Categories
CAS No.: | 1117-97-1 |
---|---|
Name: | N-methoxymethylamine |
Article Data: | 28 |
Molecular Structure: | |
Formula: | C2H7NO |
Molecular Weight: | 61.0837 |
Synonyms: | Hydroxylamine, N,O-dimethyl-;Methoxyamine, N-methyl-;Methylmethoxyamine;N,O-Dimethylhydroxylamine;N-Methoxy-N-methylamine;N-Methoxymethanamine;N-Methoxymethylamine;N-Methylmethoxyamine;O,N-Dimethylhydroxylamine;Methylamine,N-methoxy- (6CI,7CI,8CI);(Methoxyamino)methane; |
EINECS: | 214-255-2 |
Density: | 0.796 g/cm3 |
Melting Point: | 97℃ |
Boiling Point: | 2.908 °C at 760 mmHg |
Flash Point: | -28.618 °C |
PSA: | 21.26000 |
LogP: | 0.15810 |
Conditions | Yield |
---|---|
With sodium hydroxide In N,N-dimethyl-formamide distillation; | 92% |
With triethanolamine at 150℃; | 81% |
With triethanolamine In ethylene glycol at 150℃; | 81% |
Conditions | Yield |
---|---|
With hydrogenchloride |
Conditions | Yield |
---|---|
With aniline at 150℃; |
N,O-Dimethylhydroxymethan
N,0-dimethylhydroxylamine
Conditions | Yield |
---|---|
With potassium hydroxide |
Conditions | Yield |
---|---|
at 298℃; Thermodynamic data; rearrangement of N-oxide to O-alkyl hydroxylamines , ΔH, ΔS, ΔG; |
N-nitroso-N,O-dimethylhydroxylamine
N,0-dimethylhydroxylamine
Conditions | Yield |
---|---|
With perchloric acid; ammonium sulfamate; sodium thiocyanide at 50℃; Rate constant; | |
With 2,2-dicloroethanol In cyclohexane at 25℃; Kinetics; Equilibrium constant; Decomposition; |
β-(N-methyl-N-methoxyamine)-α-nitrostilbene
A
(E)-β-Methoxy-α-nitrostilbene
B
N,0-dimethylhydroxylamine
Conditions | Yield |
---|---|
In water; dimethyl sulfoxide at 20℃; Equilibrium constant; |
N,0-dimethylhydroxylamine
Conditions | Yield |
---|---|
With potassium hydroxide durch Verseifung; |
Conditions | Yield |
---|---|
Verseifung; |
N-Methoxy-N-methylacetamide
N,0-dimethylhydroxylamine
Conditions | Yield |
---|---|
In ethanol | |
With sulfuric acid at 76℃; for 5h; |
What can I do for you?
Get Best Price
The Methoxymethylamine, with the CAS registry number 1117-97-1, is also known as O,N-Dimethylhydroxylamine. Its EINECS number is 214-255-2. This chemical's molecular formula is C2H7NO and molecular weight is 61.08. What's more, its systematic name is N-Methoxymethanamine.
Physical properties of Methoxymethylamine are: (1)ACD/LogP: 0.13; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 0.06; (4)ACD/LogD (pH 7.4): 0.13; (5)ACD/BCF (pH 5.5): 1.00; (6)ACD/BCF (pH 7.4): 1.00; (7)ACD/KOC (pH 5.5): 23.82; (8)ACD/KOC (pH 7.4): 27.99; (9)#H bond acceptors: 2; (10)#H bond donors: 1; (11)#Freely Rotating Bonds: 1; (12)Polar Surface Area: 21.26 Å2; (13)Index of Refraction: 1.353; (14)Molar Refractivity: 16.655 cm3; (15)Molar Volume: 76.728 cm3; (16)Polarizability: 6.602×10-24cm3; (17)Surface Tension: 18.6 dyne/cm; (18)Density: 0.796 g/cm3; (19)Flash Point: -28.618 °C; (20)Enthalpy of Vaporization: 25.189 kJ/mol; (21)Boiling Point: 2.908 °C at 760 mmHg; (22)Vapour Pressure: 1706.8 mmHg at 25°C.
Preparation: this chemical can be prepared by N,O-dimethyl-hydroxylamine; hydrochloride by distillation. This reaction will need reagent NaOH and solvent dimethylformamide. The yield is about 92%.
Uses of Methoxymethylamine: it can be used to produce N-methoxy-N-methyl-a-monohydrohexafluoroisobutyramide at the temperature of 20 °C. It will need solvent diethyl ether with the reaction time of 48 hours. The yield is about 78.1%.
You can still convert the following datas into molecular structure:
(1)SMILES: O(NC)C
(2)Std. InChI: InChI=1S/C2H7NO/c1-3-4-2/h3H,1-2H3
(3)Std. InChIKey: KRKPYFLIYNGWTE-UHFFFAOYSA-N