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1119-34-2

Basic Information
CAS No.: 1119-34-2
Name: L-ARGININE HCL
Molecular Structure:
Molecular Structure of 1119-34-2 (L-ARGININE HCL)
Formula: C6H14N4O2.HCl
Molecular Weight: 210.70
Synonyms: Arginine,monohydrochloride, L- (8CI);L-Arginine, monohydrochloride (9CI);Argamine;L-Arginine HCl;
EINECS: 214-275-1
Density: 1.46 g/cm3
Melting Point: 226-230 °C
Boiling Point: 409.1 °C at 760 mmHg
Flash Point: 201.2 °C
Solubility: water: 100 mg/mL
Appearance: White crystalline powder
Hazard Symbols: IrritantXi,HarmfulXn
Risk Codes: 36/37/38-20/21/22
Safety: 36/37/39-26-24/25
Transport Information:
PSA: 125.22000
LogP: 1.35480
Synthetic route
914606-75-0

micropeptin MZ845

B

138-15-8

l-glutamic acid hydrochloride

C

1119-34-2

L-arginine hydrochloride

D

66866-67-9

N-methyl-L-phenylalanine hydrochloride

E

17694-98-3

L-isoleucine hydrochloride

Conditions
ConditionsYield
Stage #1: micropeptin MZ845 With Jones reagent In acetone at 0℃; for 0.166667h;
Stage #2: With hydrogenchloride; water at 110℃; for 16h; Sealed glass bomb;
914606-75-0

micropeptin MZ845

B

1119-34-2

L-arginine hydrochloride

C

66866-67-9

N-methyl-L-phenylalanine hydrochloride

D

17694-98-3

L-isoleucine hydrochloride

Conditions
ConditionsYield
With hydrogenchloride; water at 110℃; for 16h; Sealed glass bomb;
1207348-70-6

micropeptin MZ859

B

138-15-8

l-glutamic acid hydrochloride

C

1119-34-2

L-arginine hydrochloride

D

66866-67-9

N-methyl-L-phenylalanine hydrochloride

E

17694-98-3

L-isoleucine hydrochloride

Conditions
ConditionsYield
Stage #1: micropeptin MZ859 With Jones reagent In acetone at 0℃; for 0.166667h;
Stage #2: With hydrogenchloride; water at 110℃; for 16h; Sealed glass bomb;
1207348-70-6

micropeptin MZ859

B

1119-34-2

L-arginine hydrochloride

C

66866-67-9

N-methyl-L-phenylalanine hydrochloride

D

17694-98-3

L-isoleucine hydrochloride

Conditions
ConditionsYield
With hydrogenchloride; water at 110℃; for 16h; Sealed glass bomb;
1207348-72-8

micropeptin MZ939A

B

138-15-8

l-glutamic acid hydrochloride

C

1119-34-2

L-arginine hydrochloride

D

66866-67-9

N-methyl-L-phenylalanine hydrochloride

E

17694-98-3

L-isoleucine hydrochloride

Conditions
ConditionsYield
Stage #1: micropeptin MZ939A With Jones reagent In acetone at 0℃; for 0.166667h;
Stage #2: With hydrogenchloride; water at 110℃; for 16h; Sealed glass bomb;
1207348-72-8

micropeptin MZ939A

B

1119-34-2

L-arginine hydrochloride

C

66866-67-9

N-methyl-L-phenylalanine hydrochloride

D

17694-98-3

L-isoleucine hydrochloride

Conditions
ConditionsYield
With hydrogenchloride; water at 110℃; for 16h; Sealed glass bomb;
1207348-74-0

micropeptin MZ925

B

138-15-8

l-glutamic acid hydrochloride

C

1119-34-2

L-arginine hydrochloride

D

66866-67-9

N-methyl-L-phenylalanine hydrochloride

E

17694-98-3

L-isoleucine hydrochloride

Conditions
ConditionsYield
Stage #1: micropeptin MZ925 With Jones reagent In acetone at 0℃; for 0.166667h;
Stage #2: With hydrogenchloride; water at 110℃; for 16h; Sealed glass bomb;
1207348-74-0

micropeptin MZ925

B

1119-34-2

L-arginine hydrochloride

C

66866-67-9

N-methyl-L-phenylalanine hydrochloride

D

17694-98-3

L-isoleucine hydrochloride

Conditions
ConditionsYield
With hydrogenchloride; water at 110℃; for 16h; Sealed glass bomb;
1207348-76-2

micropeptin MZ939B

B

138-15-8

l-glutamic acid hydrochloride

C

1119-34-2

L-arginine hydrochloride

D

66866-67-9

N-methyl-L-phenylalanine hydrochloride

E

17694-98-3

L-isoleucine hydrochloride

Conditions
ConditionsYield
Stage #1: micropeptin MZ939B With Jones reagent In acetone at 0℃; for 0.166667h;
Stage #2: With hydrogenchloride; water at 110℃; for 16h; Sealed glass bomb;
1207348-76-2

micropeptin MZ939B

B

1119-34-2

L-arginine hydrochloride

C

66866-67-9

N-methyl-L-phenylalanine hydrochloride

D

17694-98-3

L-isoleucine hydrochloride

Conditions
ConditionsYield
With hydrogenchloride; water at 110℃; for 16h; Sealed glass bomb;
1207348-78-4

micropeptin MZ1019

B

138-15-8

l-glutamic acid hydrochloride

C

1119-34-2

L-arginine hydrochloride

D

66866-67-9

N-methyl-L-phenylalanine hydrochloride

E

17694-98-3

L-isoleucine hydrochloride

Conditions
ConditionsYield
Stage #1: micropeptin MZ1019 With Jones reagent In acetone at 0℃; for 0.166667h;
Stage #2: With hydrogenchloride; water at 110℃; for 16h; Sealed glass bomb;
1207348-78-4

micropeptin MZ1019

B

1119-34-2

L-arginine hydrochloride

C

66866-67-9

N-methyl-L-phenylalanine hydrochloride

D

17694-98-3

L-isoleucine hydrochloride

Conditions
ConditionsYield
With hydrogenchloride; water at 110℃; for 16h; Sealed glass bomb;
1207348-80-8

micropeptin MZ771

A

138-15-8

l-glutamic acid hydrochloride

B

1119-34-2

L-arginine hydrochloride

C

66866-67-9

N-methyl-L-phenylalanine hydrochloride

D

17694-98-3

L-isoleucine hydrochloride

Conditions
ConditionsYield
Stage #1: micropeptin MZ771 With Jones reagent In acetone at 0℃; for 0.166667h;
Stage #2: With hydrogenchloride; water at 110℃; for 16h; Sealed glass bomb;
1207348-80-8

micropeptin MZ771

A

1119-34-2

L-arginine hydrochloride

B

66866-67-9

N-methyl-L-phenylalanine hydrochloride

C

17694-98-3

L-isoleucine hydrochloride

Conditions
ConditionsYield
With hydrogenchloride; water at 110℃; for 16h; Sealed glass bomb;
74-79-3

L-arginine

1119-34-2

L-arginine hydrochloride

Conditions
ConditionsYield
With hydrogenchloride In 1,4-dioxane
With hydrogenchloride In 1,4-dioxane
24424-99-5

di-tert-butyl dicarbonate

1119-34-2

L-arginine hydrochloride

13726-76-6

t-butyloxycarbonyl-L-arginine

Conditions
ConditionsYield
With sodium hydroxide In 1,4-dioxane at 20℃; for 21h;92%
1119-34-2

L-arginine hydrochloride

N-(3-cyanopropyl)-guanidine monohydrochloride

Conditions
ConditionsYield
With ammonium bromide In water for 15h; Electrochemical reaction;91%
1119-34-2

L-arginine hydrochloride

4083-64-1

Tosyl isocyanate

α-4-toluenesulfonylureido-L-arginine hydrochloride

Conditions
ConditionsYield
at 4℃;90%
1043921-27-2

C22H23N3O10

1119-34-2

L-arginine hydrochloride

1043921-29-4

Boc-Glu(Arg)-Arg

Conditions
ConditionsYield
With 4-methyl-morpholine; sodium hydrogencarbonate In 1,4-dioxane; water pH=8.5 - 9.0;85%
1119-34-2

L-arginine hydrochloride

108-24-7

acetic anhydride

155-84-0

N-acetyl-L-arginine

Conditions
ConditionsYield
With sodium hydrogencarbonate81%
1119-34-2

L-arginine hydrochloride

1043921-06-7

BOC-asn-PNP

1043921-08-9

Boc-Asp(Arg)-Arg

Conditions
ConditionsYield
With 4-methyl-morpholine; sodium hydrogencarbonate In 1,4-dioxane; water pH=8.5 - 9.0;80%
1119-34-2

L-arginine hydrochloride

2937-50-0

Allyl chloroformate

176230-35-6

(S)-2-Allyloxycarbonylamino-5-guanidino-pentanoic acid

Conditions
ConditionsYield
With sodium hydroxide at 0℃;79%
1119-34-2

L-arginine hydrochloride

28252-61-1

Z-Asn(Mbh)-ONSu

80647-49-0

Z-Asn(Mbh)-Arg-OH

Conditions
ConditionsYield
With sodium hydroxide In water; N,N-dimethyl-formamide for 96h;77%
1809-20-7

diisopropyl hydrogenphosphonate

1119-34-2

L-arginine hydrochloride

N-(diisopropylphosphoryl)arginine

Conditions
ConditionsYield
With triethylamine In tetrachloromethane; ethanol; water 1.) -15 deg C, 2 h, 2.) RT, 0.5 h;72%

oxovanadium(IV) sulfate

66-71-7

1,10-Phenanthroline

1119-34-2

L-arginine hydrochloride

90-02-8

salicylaldehyde

[VO(N-salicylidene-L-arginine(-1H))(1,10-phenanthroline)]Cl

Conditions
ConditionsYield
With NaOH In methanol; water (N2); a mixt. of L-arginine hydrochloride and NaOH in H2O added to a MeOH soln. of salicylaldehyde, refluxed for 1 h, aq. soln. of VOSO4 added, refluxed for 30 min, C12H8N2 in MeOH added, refluxed for 30 min; concd. (vac.), filtered, washed (cold MeOH), dried (vac., P4O10), crystd. from aq. MeOH; elem. anal.;72%

oxovanadium(IV) sulfate

1119-34-2

L-arginine hydrochloride

90-02-8

salicylaldehyde

217-90-3

dipyrazine[2,3-f:2’,3’-h]quinoxaline

[VO(N-salicylidene-L-arginine(-1H))(dipyrido[3,2-d:2',3'-f]quinoxaline)]Cl

Conditions
ConditionsYield
With NaOH In methanol; water (N2); a mixt. of L-arginine hydrochloride and NaOH in H2O added to a MeOH soln. of salicylaldehyde, refluxed for 1 h, aq. soln. of VOSO4 added, refluxed for 30 min, C14H8N4 in MeOH added, refluxed for 30 min; concd. (vac.), filtered, washed (cold MeOH), dried (vac., P4O10), crystd. from aq. MeOH; elem. anal.;68%
22980-09-2

indolyl-3-glyoxylyl chloride

1119-34-2

L-arginine hydrochloride

76-05-1

trifluoroacetic acid

(+)-leptoclinidamine A trifluoroacetic acid salt

Conditions
ConditionsYield
Stage #1: indolyl-3-glyoxylyl chloride; L-arginine hydrochloride With perdeuteriopyridine In d7-N,N-dimethylformamide at 20 - 80℃;
Stage #2: trifluoroacetic acid In water
67%

oxovanadium(IV) sulfate

19535-47-8

dipyridil[3,2-a:2',3'-c]phenazine

1119-34-2

L-arginine hydrochloride

90-02-8

salicylaldehyde

[VO(N-salicylidene-L-arginine(-1H))(dipyrido[3,2-a:2',3'-c]phenazine)]Cl

Conditions
ConditionsYield
With NaOH In methanol; water (N2); a mixt. of L-arginine hydrochloride and NaOH in H2O added to a MeOH soln. of salicylaldehyde, refluxed for 1 h, aq. soln. of VOSO4 added, refluxed for 30 min, C18H10N4 in MeOH added, refluxed for 30 min; concd. (vac.), filtered, washed (cold MeOH), dried (vac., P4O10), crystd. from aq. MeOH; elem. anal.;65%
16774-21-3

ammonium cerium (IV) nitrate

499-83-2

Pyridine-2,6-dicarboxylic acid

1119-34-2

L-arginine hydrochloride

C21H9CeN3O12(2-)*C6H14N4O2*2H(1+)*7H2O

Conditions
ConditionsYield
Stage #1: ammonium cerium (IV) nitrate; Pyridine-2,6-dicarboxylic acid In methanol for 0.5h;
Stage #2: water; L-arginine hydrochloride In methanol
55%
1041182-97-1

7-methoxy-3-dimethylaminomethylen-2,3-dihydro-benzo[3',2':5,6]thiopyran-4(4H)-one

1119-34-2

L-arginine hydrochloride

1041183-04-3

2-(5N-ornithinyl)-8-methoxy-5H-benzo[3',2':5,6]thiopyrano[4,3-d]pyrimidine

Conditions
ConditionsYield
Stage #1: L-arginine hydrochloride With sodium ethanolate In ethanol at 20℃; for 0.25h;
Stage #2: 7-methoxy-3-dimethylaminomethylen-2,3-dihydro-benzo[3',2':5,6]thiopyran-4(4H)-one In ethanol Heating; Further stages.;
38%
1119-34-2

L-arginine hydrochloride

76-05-1

trifluoroacetic acid

3,8-bis-phenoxycarbamate-ethidium dihydrophosphate

3,8-bis-urea-arginine-ethidium tris(trifluoroacetate)

Conditions
ConditionsYield
Stage #1: L-arginine hydrochloride; 3,8-bis-phenoxycarbamate-ethidium dihydrophosphate With 2,4,6-trimethyl-pyridine In dimethyl sulfoxide at 90℃; for 1h;
Stage #2: trifluoroacetic acid In water; acetonitrile
31%
Stage #1: L-arginine hydrochloride; 3,8-bis-phenoxycarbamate-ethidium dihydrophosphate With 2,4,6-trimethyl-pyridine In water; dimethyl sulfoxide at 90℃; for 1h;
Stage #2: trifluoroacetic acid In water; acetonitrile
31%

copper(II) nitrate trihydrate

1119-34-2

L-arginine hydrochloride

{Cu(L-Arg)2}(NO3)2*3H2O

Conditions
ConditionsYield
With NaOH In water soln. of Cu salt added to a soln. of the acid hydrochloride, pH adjusted to 6.5 with NaOH, standing at room temp., crystn.; collected, dried;28%
67-56-1

methanol

1119-34-2

L-arginine hydrochloride

2577-94-8, 65160-70-5

L-arginine methyl ester

Conditions
ConditionsYield
With thionyl chloride
57-48-7

D-Fructose

1119-34-2

L-arginine hydrochloride

α-D-Fructose-L-arginin

Conditions
ConditionsYield
In dimethyl sulfoxide
57-48-7

D-Fructose

1119-34-2

L-arginine hydrochloride

N-(2-deoxy-D-glucos-2-yl)-L-arginine

Conditions
ConditionsYield
In dimethyl sulfoxide
590-28-3

potassium cyanate

1119-34-2

L-arginine hydrochloride

15920-89-5

Nα-carbamoyl-L-arginine

Conditions
ConditionsYield
(i) CuCO3, H2O, (ii) /BRN= 3560091/; Multistep reaction;
1119-34-2

L-arginine hydrochloride

29427-58-5

O-methylisourea hemisulfate

Nα-Guanyl-arginin, Nα,Nδ-Diguanyl-ornithin

Conditions
ConditionsYield
With barium dihydroxide
1119-34-2

L-arginine hydrochloride

2149-70-4

N-nitro-L-arginine

Conditions
ConditionsYield
With sulfuric acid; sulfur trioxide; nitric acid; Nitrogen dioxide
With ammonium nitrate; sulfuric acid
1119-34-2

L-arginine hydrochloride

30219-13-7

bufalin 3-hemisuberate

35455-33-5

bufalitoxin

Conditions
ConditionsYield
With triethylamine; isobutyl chloroformate Yield given. Multistep reaction;
1119-34-2

L-arginine hydrochloride

372-75-8

Citrulline

Conditions
ConditionsYield
With dipotassium hydrogenphosphate; phosphoric acid; water at 25 - 37℃; Thermodynamic data; ΔH; aginine deiminase (EC 3.5.3.6) from Pseudomonas putida; var. pH and ionic strength;
1119-34-2

L-arginine hydrochloride

220144-84-3

dl-arginine hydrochloride

Conditions
ConditionsYield
salicylaldehyde In acetic acid at 100℃; for 1h;100 % Turnov.
1119-34-2

L-arginine hydrochloride

83544-67-6

R-(-)-(1-(2)H)agmatine sulfate

Conditions
ConditionsYield
L-arginine decarboxylase In water-d2 at 36℃; for 40h;72 mg
Multi-step reaction with 4 steps
1: 81 percent / aq. sodium bicarbonate
2: 1) deuterium oxide; 2) acetic anhydride; 3) deuterium oxide / 2) perdeuterio acetic acid, reflux, 2 h; 3) reflux, 30 min
3: hog kidney acylase I
4: 100 mg / 40 h / 36 °C / enzymic decarboxylation with L-arginine decarboxylase
View Scheme
Multi-step reaction with 4 steps
1: 81 percent / aq. sodium bicarbonate
2: 1) deuterium oxide; 2) acetic anhydride; 3) deuterium oxide / 2) perdeuterio acetic acid, reflux, 2 h; 3) reflux, 30 min
4: 100 mg / 40 h / 36 °C / enzymic decarboxylation with L-arginine decarboxylase
View Scheme
1119-34-2

L-arginine hydrochloride

83544-65-4

R-(-)-(1-(2)H)agmatine sulfate

Conditions
ConditionsYield
With d(3)-acetic acid; sulfuric acid; water-d2; sodium carbonate 2) deuterium oxide, enzymic decarboxylation with L-arginine decarboxylase, 36 deg C, 30-40 h; 2) water; Yield given. Multistep reaction;
1119-34-2

L-arginine hydrochloride

A

3184-13-2

L-ornithine hydrochloride

B

57-13-6

urea

Conditions
ConditionsYield
With dipotassium hydrogenphosphate; phosphoric acid; water at 25 - 37.1℃; Thermodynamic data; ΔH; arginase (EC 3.5.3.1); var. pH and ionic strength;
1119-34-2

L-arginine hydrochloride

1058650-87-5

4-Isobutoxycarbonyloxy-4-oxo-butyric acid (3S,8R,9S,10R,13R,14S,17R)-14-hydroxy-10,13-dimethyl-17-(6-oxo-6H-pyran-3-yl)-2,3,6,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yl ester

scillarenin 3-succinyl-L-arginine ester

Conditions
ConditionsYield
In tetrahydrofuran; methanol at 0℃; for 2h; Yield given;
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    L-ARGININE HCL

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    1119-34-2

    L-Arginine HCl,1119-34-2

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    CAS No.: 1119-34-2 Other Names: L-Arginine HCl MF: C6H15ClN4O2 EINECS No.: 214-275-1 Place of Origin: Shanghai China (Mainland) Type: Vita

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    L-ARGININE HCL

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    Product name: L-Arginine HCL CAS No.:1119-34-2 Molecule Formula:C6H14N4O2·HCl Molecule Weight:210.66 Purity: 99.5% Description:White crystals or crystalline powder Manufacture Standards:FCCIV,AJI,USP,EP Items

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    L-ARGININE HCL

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    1119-34-2 Basic information More.. Product Name: 2-Amino-5-guanidinovaleric acid monohydrochloride Synonyms: argininemonohydrochloride;argivene;deto… Founded in 2014, as a professional international pharmaceutical corporation, headquartere

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    1119-34-2 L-ARGININE HCL

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  • L-ARGININE HCL CAS NO.1119-34-2

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    L-ARGININE HCL CAS NO.1119-34-2

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Specification

1. Introduction of L-ARGININE HCL

L-ARGININE HCL, with the IUPAC Name of 2-Amino-5-(diaminomethylideneamino)pentanoic acid hydrochloride, is one kind of white crystals or crystalline powder. And it belongs to the Product Categories which include chiral; Amino Acid Derivatives; Amino Acids 13C, 2H, 15N; alpha-Amino Acids; Amino Acids; Biochemistry; for Resolution of Acids; Optical Resolution; Synthetic Organic Chemistry; Nutritional Supplements; L-Amino Acids; Amino Acids; Amino Acids, Peptides and Proteins; Life Sciences Standards.

2. Properties of L-ARGININE HCL

L-ARGININE HCL has the following properties: (1)H bond acceptors: 6; (2)H bond donors: 7; (3)Freely Rotating Bonds: 6; (4)Polar Surface Area: 48.38; (5)Index of Refraction: 1.601; (6)Molar Refractivity: 40.69 cm3; (7)Molar Volume: 118.7 cm3; (8)Flash Point: 201.2 °C; (9)Enthalpy of Vaporization: 72.55 kJ/mol; (10)Boiling Point: 409.1 °C at 760 mmHg; (11)Vapour Pressure: 7.7E-08 mmHg at 25°C; (12)Melting point: 226-230 °C(lit.); (13)Alpha : 22 o (c=8,6N HCl); (14)Density: 1.42; (15)Storage temp: 2-8 °C; (16)Solubility : H2O: 100 mg/mL.

3. Structure Descriptors of L-ARGININE HCL

1). SMILES: O=C(O)[C@H](N)CCC/N=C(\N)N
2). InChI: InChI=1/C6H14N4O2/c7-4(5(11)12)2-1-3-10-6(8)9/h4H,1-3,7H2,(H,11,12)(H4,8,9,10)/t4-/m1/s1
3). InChIKey: ODKSFYDXXFIFQN-SCSAIBSYBP
4). Std. InChI: InChI=1S/C6H14N4O2/c7-4(5(11)12)2-1-3-10-6(8)9/h4H,1-3,7H2,(H,11,12)(H4,8,9,10)/t4-/m1/s1
5). Std. InChIKey: ODKSFYDXXFIFQN-SCSAIBSYSA-N

4. Use of L-ARGININE HCL

L-ARGININE HCL (CAS NO.1119-34-2) is used as nutritional supplements, pharmaceutical raw materials and food additives.

5. Safety information of L-ARGININE HCL
Hazard Codes: IrritantXi,Xn
Risk Statements: 36/37/38-20/21/22
R20/21/22: Harmful by inhalation, in contact with skin and if swallowed. 
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements: 36/37/39-26-24/25
S24/25: Avoid contact with skin and eyes. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
WGK Germany: 2
RTECS: CF1995500
F: 3-10
HS Code: 29252000

6. Toxicity of L-ARGININE HCL

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
child LDLo intravenous 3900mg/kg/30M (3900mg/kg) CARDIAC: OTHER CHANGES

BRAIN AND COVERINGS: OTHER DEGENERATIVE CHANGES
Journal of Toxicology, Clinical Toxicology. Vol. 35, Pg. 621, 1997.
 
rat LD50 intraperitoneal 3793mg/kg (3793mg/kg) BEHAVIORAL: COMA

LUNGS, THORAX, OR RESPIRATION: DYSPNEA
Archives of Biochemistry and Biophysics. Vol. 58, Pg. 253, 1955.
 
rat LD50 oral 12gm/kg (12000mg/kg) BEHAVIORAL: ATAXIA

BEHAVIORAL: ALTERED SLEEP TIME (INCLUDING CHANGE IN RIGHTING REFLEX)

LUNGS, THORAX, OR RESPIRATION: DYSPNEA
Journal of Pharmaceutical Sciences. Vol. 62, Pg. 49, 1973.