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118-33-2

Basic Information
CAS No.: 118-33-2
Name: 2-Naphthylamine-5,7-disulfonic acid
Article Data: 14
Molecular Structure:
Molecular Structure of 118-33-2 (2-Naphthylamine-5,7-disulfonic acid)
Formula: C10H9NO6S2
Molecular Weight: 303.317
Synonyms: 6-aminonaphthalene-1,3-disulfonic acid;2-Amino-5, 7-naphthalenedisulfonic acid;2-Naphthylamine, 5,7-disulfo-;Kyselina amino-i;.beta.-Naphthylamine-5,7-disulfonic acid;6-AMINO-NAPHTHALENE-1,3-DISULFONIC ACID;Naphthalene-1,3-disulfonic acid, 6-amino-;6-Amino-1, 3-naphthalenedisulfonic acid;Amino-J-acid;Amino-I acid;1,3-Naphthalenedisulfonic acid,6-amino-;2-Aminonaphthalene-5,7-disulfonic acid;6-Amino-1,3-naphthalenedisulfonic acid;2-Naphthylamine-5, 7-disulfonic acid;2-Naftylamin-5,7-disulfonan sodny;Amino-J acid;1, 3-Naphthalenedisulfonic acid, 6-amino-;
EINECS: 204-246-1
Density: 1.77 g/cm3
Boiling Point: 568.34℃[at 101 325 Pa]
Solubility: 229g/L at 15℃
Transport Information: UN 1759
PSA: 151.52000
LogP: 3.65820
Synthetic route
81-05-0

6-aminonaphthalene-1-sulfonic acid

A

118-33-2

6-amino-naphthalene-1,3-disulfonic acid

B

117-62-4

2-amino-1,5-naphthalenedisulfonic acid

Conditions
ConditionsYield
With sulfuric acid at 20℃;
With sulfuric acid
55524-84-0

2-Aminonaphthalene-1,5,7-trisulfonic acid

118-33-2

6-amino-naphthalene-1,3-disulfonic acid

Conditions
ConditionsYield
With mineral acid
7664-93-9

sulfuric acid

494-44-0

7-aminonaphthalene-2-sulfonic acid

A

118-33-2

6-amino-naphthalene-1,3-disulfonic acid

B

78887-55-5

6-amino-1,4-naphthalene disulfonic acid

C

46968-48-3

2-Aminonaphthalene-1,7-disulfonic acid

91-59-8

naphthalen-2-ylamine

oleum

oleum

A

118-33-2

6-amino-naphthalene-1,3-disulfonic acid

B

86-65-7

2-aminonaphthalene-6,8-disulfonate

Conditions
ConditionsYield
at 50 - 85℃; Eingiessen in Eiswasser, Filtrieren und Erhitzen des Filtrats zum Sieden;
Giessen in Eiswasser;
494-44-0

7-aminonaphthalene-2-sulfonic acid

A

118-33-2

6-amino-naphthalene-1,3-disulfonic acid

B

naphthylamine-(2)-disulfonic acid-(1.7); naphthylamine-(2)-disulfonic acid-(4.7)

naphthylamine-(2)-disulfonic acid-(1.7); naphthylamine-(2)-disulfonic acid-(4.7)

Conditions
ConditionsYield
With sulfuric acid
55524-84-0

2-Aminonaphthalene-1,5,7-trisulfonic acid

diluted mineral acid

diluted mineral acid

118-33-2

6-amino-naphthalene-1,3-disulfonic acid

7664-93-9

sulfuric acid

81-05-0

6-aminonaphthalene-1-sulfonic acid

A

118-33-2

6-amino-naphthalene-1,3-disulfonic acid

B

117-62-4

2-amino-1,5-naphthalenedisulfonic acid

81-16-3

2-aminonaphthalenesulfonic acid

A

118-33-2

6-amino-naphthalene-1,3-disulfonic acid

B

86-65-7

2-aminonaphthalene-6,8-disulfonate

Conditions
ConditionsYield
With sulfuric acid; sulfur trioxide In waterA n/a
B 9.5 %.
118-33-2

6-amino-naphthalene-1,3-disulfonic acid

sodium 6-iodonaphthalene-1,3-disulfonate

Conditions
ConditionsYield
Stage #1: 6-amino-naphthalene-1,3-disulfonic acid With hydrogenchloride; sodium nitrite In water at 0 - 5℃;
Stage #2: With hydrogenchloride; sodium iodide In water at 0 - 50℃;
33%
75-44-5

phosgene

118-33-2

6-amino-naphthalene-1,3-disulfonic acid

104954-42-9

6,6'-ureylene-bis-naphthalene-1,3-disulfonic acid

Conditions
ConditionsYield
With sodium carbonate
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Chemistry

IUPAC Name: 6-Aminonaphthalene-1,3-disulfonic acid
Synonyms : 6-Amino-1,3-naphthalenedisulfonic acid
Molecular Structure :
Molecular Formula : C10H9NO6S2
Molecular Weight : 303.30
CAS NO: 118-33-2
EINECS : 204-246-1
Index of Refraction: 1.733
Density: 1.769 g/cm3
Mol File: 118-33-2.mol
Appearance: 6-Aminonaphthalene-1,3-disulfonic acid (CAS NO. 118-33-2) is white shiny long prismatic needle-like crystal,
Product Categories: Intermediates of Dyes and Pigments;Anilines, Aromatic Amines and Nitro Compounds;Organic acids

Uses

 6-Aminonaphthalene-1,3-disulfonic acid (CAS NO. 118-33-2) is used for dye intermediates,mainly is the intermediates to produce J acid, double-J Acid, Phenyl J acid and scarlet acid.

Production

Production methods: 6-Aminonaphthalene-1,3-disulfonic acid (CAS NO. 118-33-2) is derived from hydrolysis of 2 - Naphthylamine -1,5,7 - 3-sulfonic acid . put sulfuric acid, sodium sulfate and 2 - naphthylamine -1,5,7 - 3-sulfonic acid in water at 110-120 °C  4h, cooling and filtering, washing in sodium sulfate solution, filtered cake obtained , which is  6-Aminonaphthalene-1,3-disulfonic acid (CAS NO. 118-33-2).

Toxicity Data With Reference

1.    

skn-rbt 2 mg/24H SEV

    85JCAE    Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague, Czechoslovakia.: Avicenum,1986,1059.
2.    

eye-rbt 750 µg/24H SEV

    28ZPAK    Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku Marhold, J.V.,Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha,Czechoslovakia.: 1972,189.
3.    

orl-rat LD50:2000 mg/kg

    28ZPAK    Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku Marhold, J.V.,Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha,Czechoslovakia.: 1972,189.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

RIDADR 1759
HazardClass 8
PackingGroup III