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1187-93-5

Basic Information
CAS No.: 1187-93-5
Name: Trifluoromethyl trifluorovinyl ether
Article Data: 21
Molecular Structure:
Molecular Structure of 1187-93-5 (Trifluoromethyl trifluorovinyl ether)
Formula: C3F6O
Molecular Weight: 166.023
Synonyms: Ethene,trifluoro(trifluoromethoxy)- (9CI);Ether, trifluoromethyl trifluorovinyl(7CI,8CI);3-Oxaperfluorobutene;Perfluoro(methyl vinyl ether);Perfluorovinyl perfluoromethyl ether;Trifluoro(trifluoromethoxy)ethylene;Trifluoromethoxytrifluoroethylene;
EINECS: 214-703-7
Density: 1.504 g/cm3
Boiling Point: 14.649 °C at 760 mmHg
Flash Point: -32.898 °C
Solubility: Insoluble in water
Appearance: Colorless gas
Hazard Symbols: FlammableF
Risk Codes: 20
Safety: 23-38
Transport Information: UN 3153
PSA: 9.23000
LogP: 2.55790
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Chemistry

Molecular Structure of Trifluoromethyl trifluorovinyl ether (CAS NO.1187-93-5): 
 
IUPAC Name: 1,1,2-trifluoro-2-(trifluoromethoxy)ethene
Molecular Formula: C3F6O
Molecular Weight: 166.02
CAS Registry Number:  1187-93-5
EINECS: 214-703-7
H bond acceptors: 1
H bond donors: 0
Freely Rotating Bonds: 1
Polar Surface Area: 9.23 Å2
Index of Refraction: 1.264
Molar Refractivity: 18.38 cm3
Molar Volume: 110.3 cm3
Surface Tension: 11.4 dyne/cm
Density: 1.504 g/cm3
Enthalpy of Vaporization: 25.13 kJ/mol
Boiling Point: 14.6 °C at 760 mmHg
Vapour Pressure: 1090 mmHg at 25°C
Product Categories: Fluoromonomer
InChI
InChI=1/C3F6O/c4-1(5)2(6)10-3(7,8)9
Smiles
C(O\C(=C(/F)F)F)(F)(F)F

Toxicity Data With Reference

1.    

ihl-mus LC50:46 µg/m3/2H

    85JCAE    Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague, Czechoslovakia.: Avicenum,1986,540.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Hazard Codes: F
Risk Statements: 20 
20:Harmful by inhalation.
Safety Statements: 23-38
23:  Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer)  
38:In case of insufficient ventilation, wear suitable respiratory equipment.
RIDADR: 3153
RTECS: KO4350000
Hazard Note: Flammable gas
TSCA: T

Specification

 Trifluoromethyl trifluorovinyl ether , with CAS number of 347-55-7, can be called 1,1,2-Trifluoro-2-(trifluoromethoxy)ethene ; ethene, 1,1,2-trifluoro-2-(trifluoromethoxy)- . Trifluoromethyl trifluorovinyl ether (CAS NO.1187-93-5) is a colorless gas. Heavier than air, easily liquefied. Contact with the liquid may cause frost bite by evaporative cooling. May asphyxiate by displacing air. A flame may flash back from the source of ignition to the source of a leak. Under prolonged exposure to fire or heat containers it may rupture violently and rocket.