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119-67-5

Basic Information
CAS No.: 119-67-5
Name: 2-Carboxybenzaldehyde
Article Data: 89
Molecular Structure:
Molecular Structure of 119-67-5 (2-Carboxybenzaldehyde)
Formula: C8H6O3
Molecular Weight: 150.134
Synonyms: Phthalaldehydicacid (6CI,7CI,8CI);2-Formylbenzoic acid;NSC 5045;o-Carboxybenzaldehyde;o-Formylbenzoic acid;
EINECS: 204-342-3
Density: 1,404 g/cm3
Melting Point: 94-96 °C(lit.)
Boiling Point: 321.8 °C at 760 mmHg
Flash Point: 162.6 °C
Solubility: Soluble in water
Appearance: white crystal powder
Hazard Symbols: IrritantXi
Risk Codes: 36/37/38-20/21/22
Safety: 26-36-24/25
PSA: 54.37000
LogP: 1.19730
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Chemistry

Molecular Formula: C8H6O3
Formula Weight: 150.13
mp of 2-FORMYLBENZOIC ACID (119-67-5): 94-96 °C(lit.)
Flash Point: 162.6 °
Boiling Point: 321.8 °C at 760 mmHg 
Density of 2-FORMYLBENZOIC ACID (119-67-5): 1.321 g/cm3 
Vapour Pressure: 0.00012 mmHg at 25°
Water Solubility : 2-FORMYLBENZOIC ACID (119-67-5) is soluble
Index of Refraction: 1.62  
Sensitive : Air Sensitive
Appearance: Solid. (Solid powder.)

Uses

2-FORMYLBENZOIC ACID (119-67-5) is used for pharmaceutical intermediate.

Production

2-FORMYLBENZOIC ACID (119-67-5) is synthesized from phenol  by bromination and ydrolysis.

Toxicity Data With Reference

1.    

orl-rat LD50:7500 mg/kg

    JANTAJ    Journal of Antibiotics. 27 (1974),665.
2.    

scu-rat LD50:2430 mg/kg

    JANTAJ    Journal of Antibiotics. 27 (1974),665.
3.    

orl-mus LD50:4480 mg/kg

    JANTAJ    Journal of Antibiotics. 27 (1974),665.
4.    

scu-mus LD50:1860 mg/kg

    JANTAJ    Journal of Antibiotics. 27 (1974),665.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Safety: WARNING: Irritates lungs, eyes, skin
Hazard Codes : Xi,Xn (Harmful; Irritant)
Risk Statements : 36/37/38-20/21/22 (Irritating to eyes, respiratory system and skin; Harmful by inhalation, in contact with skin and if swallowed)
Safety Statements : 26-36-24/25 (In case of contact with eyes, rinse immediately with plenty of water and seek medical advice; Wear suitable protective clothing; Avoid contact with skin and eyes)
RIDADR : PG2
WGK Germany : 2
RTECS : TH7015000
Hazard Note : Irritant
HS Code : 29183000
Moderately toxic by subcutaneous route. Mildly toxic by ingestion. When heated to decomposition it emits acrid smoke and irritating vapors.

Specification

Storage: Keep container in a cool, well-ventilated area. Keep container tightly closed.