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120-54-7

Basic Information
CAS No.: 120-54-7
Name: Methanethione,1,1'-tetrathiobis[1-(1-piperidinyl)-
Molecular Structure:
Molecular Structure of 120-54-7 (Methanethione,1,1'-tetrathiobis[1-(1-piperidinyl)-)
Formula: C12H20N2S6
Molecular Weight: 384.70
Synonyms: Piperidine,1,1'-(tetrathiodicarbonothioyl)bis- (9CI);Tetrasulfide,bis(piperidinothiocarbonyl) (6CI,8CI);Accel TRA;Bis(pentamethylene)thiuramtetrasulfide;Dipentamethylenethiuramtetrasulfide;NSC 4823;Nocceler TRA;Sanceler TRA;Sanceler TRA-C;SoxinolTRA;Sulfads;Tetron A;Tetrone A;Thiuram MT;
EINECS: 204-406-0
Density: 1.437 g/cm3
Melting Point: 118.0 to 122.0 °C
Boiling Point: 510.1 °C at 760 mmHg
Flash Point: 262.3 °C
Solubility:
Appearance: white or yellow powder
Hazard Symbols: N
Risk Codes: 20/21/22
Safety: 26-36/37/39
Transport Information:
PSA: 171.86000
LogP: 5.08160
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  • Bis(pentamethylene)thiuram tetrasulfide cas  120-54-7

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Chemistry

IUPAC Name of TETRONE A(120-54-7): piperidine-1-carbothioylsulfanyldisulfanyl piperidine-1-carbodithioate
MF: C12H20N2S6
MW: 384.69
Appearance: white or yellow  powder
Melting Point:115°C
relative density:1.50
Solubility:carbon bisulfide,chloroform,carbon tetrachloride
Insolubility:water
Synonyms of TETRONE A(120-54-7): Bis(pentamethylene)thiuram tetrasulfide;BIS(PENTAMETHYLENETHIOCARBAMOYL) TETRASULFIDE;Bis(pentamethylene)thiuram tetrasulfide;BIS(PIPERIDINOTHIOCARBONYL) TETRASULFIDE;DPTT;DIPENTAMETHYLENETHIURAM TETRASULFIDE;1,1'-(tetrathiodicarbonothioyl)-bis-piperidine;1,1’-(tetrathiodicarbonothioyl)bis-piperidin;Accelerator(tra)
EINECS: 204-406-0
Product Categories: Pharmaceutical Intermediates;Rubber Accelerator;Organics
CAS DataBase Reference 120-54-7(CAS DataBase Reference)
EPA Substance Registry System 120-54-7(EPA Substance)

Uses

TETRONE A(120-54-7) is used as rubber accelerator.

Production

TETRONE A(120-54-7) is synthesized in two steps.Fist,sodium pentamethylene dithiocarbamate is synthesized by the reaction of hexahydropyridine,sodium carbonate and carbon bisulfide. Second,sodium pentamethylene dithiocarbamate is treated by sulfur monochloride to get TETRONE A(120-54-7).

Toxicity Data With Reference

1.    

ipr-mus LD50:200 mg/kg

    NTIS**    National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) AD277-689 .

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

safety information of TETRONE A(120-54-7):
Poison by intraperitoneal route. When heated to decomposition it emits very toxic fumes of NOx and SOx. See also SULFIDES.
Risk Statements  20/21/22
Harmful by inhalation, in contact with skin and if swallowed
Safety Statements  26-36/37/39
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Wear suitable protective clothing, gloves and eye/face protection
RTECS  TN4221000