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12005-86-6

Basic Information
CAS No.: 12005-86-6
Name: SODIUM HEXAFLUOROARSENATE(V)
Article Data: 7
Molecular Structure:
Molecular Structure of 12005-86-6 (SODIUM HEXAFLUOROARSENATE(V))
Formula: AsF6 . Na
Molecular Weight: 211.902
Synonyms: Arsenate(1-),hexafluoro-, sodium (9CI); Sodium fluoarsenate(V) (NaAsF6) (6CI); Sodiumhexafluoroarsenate(V) (7CI); Sodium hexafluoroarsenate; Sodiumhexafluoroarsenate (NaAsF6)
EINECS: 215-608-3
Density: g/cm3
Melting Point: 160 °C
Boiling Point: °Cat760mmHg
Flash Point: °C
Solubility: Soluble in water.
Appearance: solid
Hazard Symbols:
Risk Codes: 23/25-50/53
Safety: Confirmed human carcinogen. Poison by intravenous route. When heated to decomposition it emits very toxic fumes of As, F, and Na2O. See also FLUORIDES and ARSENIC COMPOUNDS.
PSA: 0.00000
LogP: 2.14040
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Chemistry

IUPAC Name: Sodium hexafluoroarsenic(1-)
Synonyms of Sodium hexafluoroarsenate (CAS NO.12005-86-6): Sodium hexafluoroarsenate(v) ; Sodiumhexafluoroarsenate(v),99% ; Sodiumhexafluorarsenate
Product Categories: ArsenicMetal and Ceramic Science;Catalysis and Inorganic Chemistry;Chemical Synthesis;Salts;Sodium Salts
CAS NO: 12005-86-6
Molecular Formula: AsF6Na
Molecular Weight : 211.9017892
Molecular Structure:
EINECS: 215-608-3 
Form: solid
Stability: Sodium hexafluoroarsenate (CAS NO.12005-86-6) is stable, incompatible with strong oxidizing agents.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intravenous 56mg/kg (56mg/kg)   U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#00127,
rat LD50 oral 880mg/kg (880mg/kg) GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA" National Technical Information Service. Vol. OTS0540137,

Consensus Reports

Arsenic and its compounds are on the Community Right-To-Know List.

Safety Profile

Hazard Codes: ToxicT,DangerousN
Risk Statements: 23/25-50/53
R23/25: Toxic by inhalation and if swallowed 
R50/53: Sodium hexafluoroarsenate (CAS NO.12005-86-6) is very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements: 20/21-28-45-60-61
S20/21: When using, do not eat, drink or smoke 
S28: After contact with skin, wash immediately with plenty of soap-suds. 
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S60: This material and its container must be disposed of as hazardous waste. 
S61: Avoid release to the environment. Refer to special instructions / safety data sheets. 
RIDADR: 1557
WGK Germany: 3
RTECS: WB2775000
HazardClass: 6.1
PackingGroup: II

Confirmed human carcinogen. Poison by intravenous route. When heated to decomposition it emits very toxic fumes of As, F, and Na2O. See also FLUORIDES and ARSENIC COMPOUNDS.

Standards and Recommendations

OSHA PEL: OSHA: Cancer Hazard
ACGIH TLV: TWA 0.01 mg/m3; Confirmed Human Carcinogen; BEI: 35 µ (As)/L inorganic arsenic and methylated metabolites in urine
NIOSH REL: (Arsenic, Inorganic) CL 2 µg/m3/15M