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12031-80-0

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Basic Information
CAS No.: 12031-80-0
Name: Lithium peroxide
Article Data: 4
Molecular Structure:
Molecular Structure of 12031-80-0 (Lithium peroxide)
Formula: Li2O2
Molecular Weight: 45.8808
Synonyms: Dilithiumperoxide;Lithium oxide (Li2O2);Lithium peroxide;
EINECS: 234-758-0
Density: g/cm3
Melting Point: 340°C (dec.)
Boiling Point: 150.2°Cat760mmHg
Flash Point: °C
Solubility: solubility in H2O is 8% (20°C); solubility in acetic acid is 5.6% (20°C); insoluble absolute alcohol (20°C) [HAW93]
Appearance: White to pale yellow powder
Hazard Symbols: Dangerous fire and explosion risk in contact with organic materials. Strong oxidizing agent.
Risk Codes: 8-35
Safety: A powerful oxidizer and irritant to skin, eyes, and mucous membranes. A very dangerous fire hazard because it is an extremely powerful oxidizing agent. Will react with water or steam to produce heat; on contact with reducing materials, can react vigorously. See also LITHIUM COMPOUNDS, PEROXIDES, INORGANIC; PEROXIDES, ORGANIC, and PEROXIDES, INORGANIC.
PSA: 46.12000
LogP: -0.23760
Synthetic route
90076-65-6

bis(trifluoromethane)sulfonimide lithium

12031-80-0

lithium peroxide

Conditions
ConditionsYield
With 1-butyl-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide Electrochemical reaction;

lithium perchlorate

62205-77-0

tetramethylammonium superoxide

12031-80-0

lithium peroxide

Conditions
ConditionsYield
In acetonitrile at 20℃; for 1h; Glovebox; Inert atmosphere;

lithium perchlorate

12031-80-0

lithium peroxide

Conditions
ConditionsYield
With ruthenium oxide nanoparticle decorated mesoporous boron doped carbon nitride electrode In dimethyl sulfoxide at 80℃; for 48h; Mitsunobu Displacement; Electrochemical reaction; Glovebox;
1310-66-3

lithium hydroxide monohydrate

7722-84-1

dihydrogen peroxide

12031-80-0

lithium peroxide

Conditions
ConditionsYield
for 1h;
7647-01-0

hydrogenchloride

12031-80-0

lithium peroxide

lithium chloride

1310-65-2

lithium hydroxide

7440-18-8

ruthenium

Li8Ru2OCl14

Conditions
ConditionsYield
Stage #1: lithium peroxide; lithium hydroxide; ruthenium In melt at 600℃; for 0.5h;
Stage #2: hydrogenchloride; lithium chloride
60%
12031-80-0

lithium peroxide

neptunium(IV) dioxide

NpO6(5-)*5Li(1+)=Li5NpO6

Conditions
ConditionsYield
In solid NpO2 and Li2O2 ground together, heated at 400°C for 24-72 h under O2; cooled, analyzed, reground, reheated until const. Np(VII) content (about 80-85%), not pure material(!);
12031-80-0

lithium peroxide

cesium oxo terbate (IV)

A

cesium oxide

B

Cs2Li14{Tb3O14}

C

octalithium oxo terbate (IV)

Conditions
ConditionsYield
In neat (no solvent) byproducts: O2; tempering (ratio Tb:Li 1:5, 550°C, closed Au-tube, 3 weeks, heating rate 10°C/h);
12031-80-0

lithium peroxide

terbium oxide

cesium oxo terbate (IV)

Cs2Li14{Tb3O14}

Conditions
ConditionsYield
In neat (no solvent) byproducts: O2; tempering (560°C, closed Au-tube, 10 d or 8 weeks);
12031-80-0

lithium peroxide

copper(II) oxide

12527-46-7

lithium cuprate

Conditions
ConditionsYield
With oxygen heating (platinum crucible, oxygen flow, 500°C, 5 d);
450°C for 5 d;
1313-99-1

nickel(II) oxide

12031-80-0

lithium peroxide

lithium nickelate(III)

Conditions
ConditionsYield
educts were ground together in an argon grove box and were pelletized, pellets were heated to 850°C very slowly under a stream of pure dried O2 passed through liquid N2 (24-48 h); cooling to room temp. very slowly;
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    New supplier

This product is a nationally controlled contraband, and the Lookchem platform doesn't provide relevant sales information.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

A powerful oxidizer and irritant to skin, eyes, and mucous membranes. A very dangerous fire hazard because it is an extremely powerful oxidizing agent. Will react with water or steam to produce heat; on contact with reducing materials, can react vigorously. See also LITHIUM COMPOUNDS, PEROXIDES, INORGANIC; PEROXIDES, ORGANIC, and PEROXIDES, INORGANIC.

Standards and Recommendations

DOT Classification:  5.1; Label: Oxidizer