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12036-21-4

Basic Information
CAS No.: 12036-21-4
Name: VANADIUM(IV) OXIDE
Article Data: 7
Molecular Structure:
Molecular Structure of 12036-21-4 (VANADIUM(IV) OXIDE)
Formula: O2V
Molecular Weight: 82.9403
Synonyms: Divanadiumtetraoxide;Divanadium tetroxide;Vanadium dioxide;Vanadium oxide (V2O4);Vanadium oxide (V4O8);Vanadium oxide (V6O12);Vanadium(IV) oxide;
EINECS: 234-841-1
Density: 4.339 g/mL at 25oC(lit.)
Melting Point: 1967°C
Solubility: Insoluble in water.
Hazard Symbols:
Risk Codes: 36/38
Safety:
Hazard Codes Xi
Risk Statements 36/38
Safety Statements 26-37/39
RIDADR UN3285
WGK Germany 3
10-23
HazardClass 6.1
PackingGroup II
PSA: 34.14000
LogP: -0.23760
Synthetic route
12035-98-2

oxovanadium(IV)

10102-43-9

nitrogen(II) oxide

A

12036-21-4

vanadium dioxide

B

VONO

Conditions
ConditionsYield
In gaseous matrix Kinetics; byproducts: N; Ar bath gas; VO was produced by multiphoton dissociation of VOCl3 at 193 nm; 297, 394 and 531 K; laser-induced fluorescence;
12035-98-2

oxovanadium(IV)

12036-21-4

vanadium dioxide

Conditions
ConditionsYield
In gaseous matrix Kinetics; byproducts: O; Ar bath gas; VO was produced by multiphoton dissociation of VOCl3 at 193 nm; 297, 394 and 531 K; laser-induced fluorescence;
12035-98-2

oxovanadium(IV)

124-38-9

carbon dioxide

12036-21-4

vanadium dioxide

Conditions
ConditionsYield
In gaseous matrix Kinetics; byproducts: CO; Ar bath gas; VO was produced by multiphoton dissociation of VOCl3 at 193 nm; 297, 394 and 531 K; laser-induced fluorescence;

vanadia

12036-21-4

vanadium dioxide

Conditions
ConditionsYield
Stage #1: vanadia In water at 180℃; for 24h; Autoclave;
Stage #2: at 550℃; for 2h; Inert atmosphere;

ammonium metavanadate

12036-21-4

vanadium dioxide

Conditions
ConditionsYield
With hydrogen at 380℃; for 6h;

C30H28N2O7V*2H2O

12036-21-4

vanadium dioxide

Conditions
ConditionsYield
at 50.5 - 528.9℃;

gallium(III) oxide

tellurium oxide

12036-21-4

vanadium dioxide

GaVTe2O8

Conditions
ConditionsYield
With hydrogenchloride In water at 200℃; for 72h; Autoclave;21%
1333-84-2, 1344-28-1

aluminum oxide

tellurium oxide

12036-21-4

vanadium dioxide

AlVTe2O8

Conditions
ConditionsYield
With hydrogenchloride In water at 230℃; for 96h; Autoclave;10%
12036-21-4

vanadium dioxide

potassium hydrogenphosphate trihydrate

potassium phosphate tribasic trihydrate

0.94K(1+)*OV*0.92O4P(3-)*0.08O4V(3-)*1.5H2O

Conditions
ConditionsYield
Stage #1: vanadium dioxide; water With sulfuric acid
Stage #2: potassium hydrogenphosphate trihydrate; potassium phosphate tribasic trihydrate for 0.166667h;
Stage #3: at 160℃; for 12h; Autoclave;
12036-21-4

vanadium dioxide

potassium hydrogenphosphate trihydrate

2OV*2K(1+)*2HO4P(2-)*1.125H2O

Conditions
ConditionsYield
Stage #1: vanadium dioxide; water With sulfuric acid
Stage #2: potassium hydrogenphosphate trihydrate for 0.166667h;
Stage #3: at 160℃; for 12h; Autoclave;
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