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| CAS No.: | 12069-69-1 |
|---|---|
| Name: | Cupric carbonate basic |
| Molecular Structure: | |
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| Formula: | CuCO3.Cu.(OH)2 |
| Molecular Weight: | 221.11 |
| Synonyms: | Copper, (carbonato)dihydroxydi- (8CI);Copper, [m-[carbonato(2-)-O:O']]dihydroxydi-;Carbonic acid, copper complex;Basic copper carbonate;Basic copper carbonate(Cu2(CO3)(OH)2);Basic copper(II)carbonate;Basic cupric carbonate;Carbonatodihydroxodicopper;Carbonic acid,copper(2+) salt (1:1), basic;Cheshunt compound;Copper basic carbonate;Coppercarbonate hydroxide (Cu2CO3(OH)2);Cupriccarbonate, basic;Dicopper dihydroxycarbonate;Dicopper(2+) carbonatedihydroxide; |
| EINECS: | 235-113-6 |
| Density: | 4.0 g/cm3 |
| Melting Point: | 200 °C |
| Boiling Point: | 333.6 °C at 760 mmHg |
| Flash Point: | 169.8 °C |
| Solubility: | Insoluble in water |
| Appearance: | Fine green powder |
| Hazard Symbols: |
 Xn
|
| Risk Codes: | 22-36/37/38 |
| Safety: | 26-36 |
| PSA: | 103.65000 |
| LogP: | -2.80560 |
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Consensus Reports
Copper and its compounds are on the Community Right-To-Know List. Copper(II) carbonate basic (CAS NO.12069-69-1) is reported in EPA TSCA Inventory.
Standards and Recommendations
ACGIH TLV: TWA (fume) 0.2 mg/m3; (dust, mist) 1 mg(Cu)/m3
Specification
The IUPAC name of Copper(II) carbonate basic is dicopper carbonate dihydroxide. With the CAS registry number 12069-69-1, it is also named as (Carbonato(2-))dihydroxydicopper. The classification codes are Agricultural Chemical; Fungicide, bactericide, wood preservative; Molluscicide. It is fine green powder which is insoluble in cold water and alcohol, soluble in acid forming the corresponding copper, soluble in cyanide, ammonia, ammonium salt and alkali metal carbonate solution. Additionally, this chemical should be stored in the ventilate, low-temperature and dry place.
The other characteristics of this product can be summarized as: (1)#H bond acceptors: 5; (2)#H bond donors: 4; (3)#Freely Rotating Bonds: 2; (4)Polar Surface Area: 103.65 ?2; (5)Rotatable Bond Count: 0; (6)Exact Mass: 219.849425; (7)MonoIsotopic Mass: 219.849425; (8)Topological Polar Surface Area: 65.2; (9)Heavy Atom Count: 8; (10)Complexity: 18.8; (11)Covalently-Bonded Unit Count: 5.
Preparation of Copper(II) carbonate basic: It can be obtained by the following reaction equations.
Cu+4HNO3→Cu(NO3)2+2NO2↑+2H2O
2Cu(NO3)2+2Na2CO3+H2O→CuCO3·Cu(OH)2+4NaNO3+CO2↑
2Cu(NO3)2+4NaHCO3→CuCO3·Cu(OH)2+4NaNO3+3CO2↑+H2O
Uses of Copper(II) carbonate basic: It is used in the fireworks, pesticides, paint, animal feed, fungicides, anti-corrosion and other industries. And it is also used in the manufacturing of copper compounds. In addition, this chemical can be used as analysis reagents and pesticides.
When you are using this chemical, please be cautious about it as the following:
It is not only harmful if swallowed, but also irritating to eyes, respiratory system and skin. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. If you want to contact this product, you must wear suitable protective clothing.
People can use the following data to convert to the molecule structure.
1. Smiles: C(=O)([O-])[O-].[OH-].[OH-].[Cu+2].[Cu+2]
2. InChI: InChI=1/CH2O3.2Cu.2H2O/c2-1(3)4;;;;/h(H2,2,3,4);;;2*1H2/q;2*+2;;/p-4
The following are the toxicity data which has been tested.
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| bird - domestic | LD50 | oral | 900mg/kg (900mg/kg) | Pesticide Chemicals Official Compendium, Association of the American Pesticide Control Officials, Inc., 1966. Vol. -, Pg. 258, 1966. | |
| duck | LDLo | oral | 900mg/kg (900mg/kg) | BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) BEHAVIORAL: COMA | Australian Veterinary Journal. Vol. 16, Pg. 147, 1940. |
| pigeon | LDLo | oral | 1gm/kg (1000mg/kg) | BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) BEHAVIORAL: COMA | Australian Veterinary Journal. Vol. 16, Pg. 147, 1940. |
| rabbit | LD50 | oral | 159mg/kg (159mg/kg) | Guide to the Chemicals Used in Crop Protection. Vol. 6, Pg. 128, 1973. | |
| rat | LD50 | oral | 1350mg/kg (1350mg/kg) | BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA" BLOOD: NORMOCYTIC ANEMIA | Shokuhin Eiseigaku Zasshi. Food Hygiene Journal. Vol. 26, Pg. 605, 1985. |