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12116-66-4

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CAS No.: 12116-66-4
Name: BIS(CYCLOPENTADIENYL)HAFNIUM DICHLORIDE
Article Data: 21
Molecular Structure:
Molecular Structure of 12116-66-4 (BIS(CYCLOPENTADIENYL)HAFNIUM DICHLORIDE)
Formula: C10H10 Cl2 Hf
Molecular Weight: 379.585
Synonyms: Dicyclopentadienylhafniumdichloride (6CI);Hafnium, dichlorodi-p-cyclopentadienyl- (8CI);Bis(cyclopentadienyl)hafniumdichloride;Bis(cyclopentadienyl)hafnium(IV) dichloride;Dichlorobis(cyclopentadienyl)hafnium;Dichlorobis(h-cyclopentadienyl)hafnium;Dichlorobis(h5-cyclopentadienyl)hafnium;Dichlorodi-p-cyclopentadienylhafnium;Dichlorodicyclopentadienylhafnium;Dichlorohafnocene;Hafnium dicyclopentadienedichloride;Hafnocene dichloride;NSC 102788;
EINECS: 235-177-5
Density: 12.7g/cm3
Melting Point: 230-233 ºC
Boiling Point: 339.81°C (rough estimate)
Appearance: Gray powder
Hazard Symbols:
Risk Codes: R20/21/22   
Safety: A poison by intravenous route. See also HAFNIUM. When heated to decomposition it emits very toxic fumes such as Cl−.
PSA: 0.00000
LogP: 3.29540
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Chemistry

IUPAC Name: Bis(cyclopentadienyl)hafnium dichloride
The MF of Bis(cyclopentadienyl)hafnium dichloride (CAS NO.12116-66-4) is C10H12Cl2Hf.

                                        
The MW of Bis(cyclopentadienyl)hafnium dichloride (CAS NO.12116-66-4) is 381.59828.
Synonyms of Bis(cyclopentadienyl)hafnium dichloride (CAS NO.12116-66-4): Cyclopenta-1,3-dien-dichlorhafnium(2:1) ; Hafnocene dichloride
Product Categories: Biochemistry;Classes of Metal Compounds;Hf (Hafnium) Compounds;Metallocenes;Reagents for Oligosaccharide Synthesis;Titanocene, etc.
Apperance: white to light brown crystals or crystalline
Sensitive: Air & Moisture Sensitive
Melting Point: 230-233 °C
EINECS: 235-177-5

Uses

  Bis(cyclopentadienyl)hafnium dichloride (CAS NO.12116-66-4) is used as Chemical reagents, organic intermediates, fine chemicals, pharmaceutical research and development.

Toxicity Data With Reference

1.    

ivn-mus LD50:100 mg/kg

     CSLNX*    U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) NX#04787 .

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

A poison by intravenous route. See also HAFNIUM. When heated to decomposition it emits very toxic fumes such as Cl−.Safety information of Bis(cyclopentadienyl)hafnium dichloride (CAS NO.12116-66-4):
Hazard Codes  IrritantXi,Xn
Risk Statements 
36/37/38 Irritating to eyes, respiratory system and skin
20/21/22 Harmful by inhalation, in contact with skin and if swallowed
Safety Statements 
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36/37/39 Wear suitable protective clothing, gloves and eye/face protection
RIDADR  UN3261
WGK Germany  3
RTECS  MG4815000
F  10-21
TSCA  Yes
HazardClass  8
PackingGroup  III