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12124-97-9

Basic Information
CAS No.: 12124-97-9
Name: Ammonium bromide
Molecular Structure:
Molecular Structure of 12124-97-9 (Ammonium bromide)
Formula: NH4Br
Molecular Weight: 97.96
Synonyms: Sulfamic acid,monoammonium salt;Ammonium Bromide, Granular, Reagent;Identifier;FR-11;
EINECS: 235-183-8
Density: 2.429 g/cm3
Melting Point: 452 °C(lit.)
Boiling Point: 49.2 °C at 760 mmHg
Flash Point:
Solubility: water: 1 M at 20 °C, clear, colorless
Appearance: white crystals
Hazard Symbols: IrritantXi
Risk Codes: 22-36/37/38
Safety: 22-24/25
Transport Information:
PSA: 3.24000
LogP: 1.28200
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Chemistry

Molecular Structure:

Molecular Formula: H4BrN
Molecular Weight: 97.9425
IUPAC Name: Dibromozinc
Synonyms of Ammonium bromide (cas no.12124-97-9): Ammonii bromidum ; Ammonium bromatum ; EINECS 235-183-8 ; HSDB 207 ; Hydrobromic acid monoammoniate ; Nervine ; UNII-R0JB3224WS ; Ammonium bromide ((NH4)Br)
CAS NO: 12124-97-9
Product Categories: Inorganic Chemicals ; Inorganics ; A-B, Puriss p.a. ACS ; Analytical Reagents for General Use ; Puriss p.a. ACS ; ACS GradeSynthetic Reagents ; Ammonium ; Essential Chemicals ; Routine Reagents ; Ammonium Salts ; AmmoniumMetal and Ceramic Science ; Inorganic Salts ; Salts ; Synthetic Reagents
Melting point: 452 °C
H bond acceptors: 1
H bond donors: 3
Enthalpy of Vaporization: 23.33 kJ/mol
Boiling Point: 49.2 °C at 760 mmHg
Vapour Pressure: 5990 mmHg at 25 °C

Uses

 Ammonium bromide (cas no.12124-97-9) is used for photography in films, plates and papers;in corrosion inhibitors;in lithography and process engraving;in fireproofing of wood;  and in pharmaceutical preparations.

Production

 Ammonium bromide (cas no.12124-97-9) can  be prepared by the reaction of ammonia with iron(II) bromide or iron(III) bromide, which may be obtained by passing aqueous bromine solution over iron filings.
  2 NH3 + FeBr2 + H2O → 2 NH4Br + FeO 
It can also be prepared by the action of hydrogen bromide on ammonia as following:
   NH3 + HBr → NH4Br 

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
guinea pig LD50 intraperitoneal 535mg/kg (535mg/kg)   Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 33(10), Pg. 57, 1989.
mouse LD50 intraperitoneal 559mg/kg (559mg/kg)   Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 33(10), Pg. 57, 1989.
mouse LD50 oral 2860mg/kg (2860mg/kg) SENSE ORGANS AND SPECIAL SENSES: OTHER CHANGES: OLFACTION

BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 33(10), Pg. 57, 1989.
rat LD50 oral 2700mg/kg (2700mg/kg) SENSE ORGANS AND SPECIAL SENSES: OTHER CHANGES: OLFACTION

BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 33(10), Pg. 57, 1989.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Hazard Codes of Ammonium bromide (cas no.12124-97-9): HarmfulXn,Xi
Risk Statements: 22-36/37/38 
R22: Harmful if swallowed. 
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements: 22-24/25 
S22: Do not breathe dust. 
S24/25: Avoid contact with skin and eyes.
WGK Germany: 2
RTECS: BO9155000
Moderately toxic by ingestion and intraperitoneal routes. See also BROMIDES. When heated to decomposition it emits very toxic fumes of NOx, Br, and NH3. Incompatible with BrF3; IF7; K.