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12164-94-2

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Basic Information
CAS No.: 12164-94-2
Name: ammonium azide
Molecular Structure:
Molecular Structure of 12164-94-2 (ammonium azide)
Formula: H4N4
Molecular Weight: 60.08
Synonyms: Ammoniumazide (6CI,7CI,8CI)
Density: g/cm3
Melting Point: 160℃ [CIC73]
Boiling Point: °Cat760mmHg
Flash Point: °C
Solubility: g NH4N3/100g H2O: 16.0 (0°C), 25.3 (20°C), 37.1 (40°C) [LAN05]
Safety: Poison by inhalation and ingestion. See also AZIDES. Moderately flammable. Unstable. Explosion hazard upon rapid heating.
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Chemistry

Molecule structure of Ammonium azide (CAS NO.12164-94-2):

Molecular Weight: 60.05856 g/mol
Molecular Formula: H4N4
H-Bond Donor: 2
H-Bond Acceptor: 3
Exact Mass: 60.043596
MonoIsotopic Mass: 60.043596
Topological Polar Surface Area: 26.9
Heavy Atom Count: 4
Complexity: 23 
Canonical SMILES: N.N=[N+]=[N-]
InChI: InChI=1S/HN3.H3N/c1-3-2;/h1H;1H3
InChIKey: MXZUDRZKSUUQRR-UHFFFAOYSA-N

History

 Ammonium azide (CAS NO.12164-94-2) was first obtained by Theodor Curtius in 1890, along with other azides.

Safety Profile

RIDADR: 0473
HazardClass: 1.1A
Poison by inhalation and ingestion. See also AZIDES. Moderately flammable. Unstable. Explosion hazard upon rapid heating.

Standards and Recommendations

DOT Classification:  Forbidden

Specification

 Ammonium azide (CAS NO.12164-94-2) is colourless crystalline salt which is a powerful explosive. But it has a remarkably low sensitivity. Ammonium azide is physiologically active: inhalation of small amounts causes headaches and palpitations.