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| CAS No.: | 123-00-2 |
|---|---|
| Name: | N-(3-Aminopropyl)morpholine |
| Article Data: | 44 |
| Molecular Structure: | |
|
|
|
| Formula: | C7H16N2O |
| Molecular Weight: | 144.217 |
| Synonyms: | Morpholine,4-(3-aminopropyl)- (6CI,7CI,8CI);1-Amino-3-morpholinopropane;1-Morpholino-3-aminopropane;3-(4-Morpholino)propylamine;3-(4-Morpholinyl)-1-propanamine;3-(4-Morpholinyl)-1-propylamine;3-(4-Morpholinyl)propanamine;3-(4-Morpholinyl)propylamine;3-(Morpholin-4-yl)propylamine;3-(Morpholino)-n-propylamine;3-(N-Morpholino)-1-aminopropane;3-Amino-1-(morpholino)propane;3-Morpholinopropanamine;3-Morpholinopropylamine;4-(3-Aminopropyl)morpholine;4-(g-Aminopropyl)morpholine;4-Morpholinepropanamine;NSC 1081;[3-(4-Morpholinyl)propan-1-yl]amine;[3-(Morpholino)propan-1-yl]amine;g-Morpholinopropylamine; |
| EINECS: | 204-590-2 |
| Density: | 0.985 g/cm3 |
| Melting Point: | -15 °C(lit.) |
| Boiling Point: | 227.8 °C at 760 mmHg |
| Flash Point: | 98.9 °C |
| Solubility: | Soluble |
| Appearance: | Clear liquid |
| Hazard Symbols: |
 Xi,  C
|
| Risk Codes: | 21-34-21/22-36/37 |
| Safety: | 26-36/37/39-45 |
| Transport Information: | UN 2735 8/PG 2 |
| PSA: | 38.49000 |
| LogP: | 0.30560 |
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- 106018-95-5
2-Trimethylsilanyl-ethanesulfonic acid (3-morpholin-4-yl-propyl)-amide
- 123-00-2
4-(3-Aminopropyl)morpholine
| Conditions | Yield |
|---|---|
| With cesium fluoride In N,N-dimethyl-formamide at 95℃; for 40h; | 90% |
| Conditions | Yield |
|---|---|
| Stage #1: Argopore Wang resin-bound 3-amino-1-propanol With 1H-imidazole; iodine; triphenylphosphine In N,N-dimethyl-formamide for 16h; Stage #2: morpholine In N,N-dimethyl-formamide at 50℃; for 6h; Stage #3: With trifluoroacetic acid In dichloromethane for 1h; | 86% |
| Conditions | Yield |
|---|---|
| With hydrazine hydrate In ethanol for 24h; Reflux; | 86% |
| With hydrazine hydrate In ethanol at 20℃; Reflux; | 85% |
| With hydrazine hydrate In ethanol Reflux; | |
| With hydrazine hydrate In ethanol for 0.75h; Reflux; | |
| With hydrazine hydrate In ethanol Reflux; |
| Conditions | Yield |
|---|---|
| With sodium tetrahydroborate; hydrogen; nickel dichloride In tert-butyl alcohol at 70℃; under 760.051 Torr; for 8h; | A 22% B 59% |
| Conditions | Yield |
|---|---|
| With xylene Erhitzen des Reaktionsprodukts mit konz. wss. HCl; |
| Conditions | Yield |
|---|---|
| Erhitzen des Reaktionsprodukts mit wss. HCl; |
- 23159-07-1
3-(1-pyrrolidinyl)propylamine
- 123-00-2
4-(3-Aminopropyl)morpholine
| Conditions | Yield |
|---|---|
| With diazene In ethanol for 3h; |
| Conditions | Yield |
|---|---|
| With potassium carbonate; potassium iodide In acetonitrile at 30℃; for 8h; |
- 123-00-2
4-(3-Aminopropyl)morpholine
- 63875-01-4
2-methyl-pyridine-4-carbaldehyde
| Conditions | Yield |
|---|---|
| With magnesium sulfate | 100% |
| With magnesium sulfate In toluene for 18h; | |
| With magnesium sulfate |
| Conditions | Yield |
|---|---|
| Stage #1: C17H17F3O3; di(succinimido) carbonate With triethylamine In acetonitrile at 20℃; for 1h; Stage #2: 4-(3-Aminopropyl)morpholine In acetonitrile at 20℃; for 0.25h; Further stages.; | 100% |
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Chemistry
IUPAC Name: 3-Morpholin-4-ylpropan-1-amine
Synonyms: 3-(Morpholin-4-yl)propan-1-amine ; 4-(Gamma.-Aminopropyl)morpholine ; 4-Morpholinepropanamine ; Morpholine, 4- (3-aminopropyl)-
Molecular Structure of 4-Aminopropylmorpholine (CAS NO.123-00-2) : 
Molecular Formula of 4-Aminopropylmorpholine (CAS NO.123-00-2) : C7H16N2O
Molecular Weight of 4-Aminopropylmorpholine (CAS NO.123-00-2) : 144.21
CAS NO: 123-00-2
EINECS : 204-590-2
Index of Refraction: 1.473
Surface Tension: 35.5 dyne/cm
Density: 0.985 g/cm3
Flash Point: 98.9 °C
Enthalpy of Vaporization: 46.44 kJ/mol
Boiling Point: 227.8 °C at 760 mmHg
Vapour Pressure: 0.0761 mmHg at 25°C
Melting point: -15 ºC
Water solubility: soluble
Appearance:Clear liquid
Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| rabbit | LD50 | skin | 1230uL/kg (1.23mL/kg) | AMA Archives of Industrial Hygiene and Occupational Medicine. Vol. 4, Pg. 119, 1951. | |
| rat | LD50 | oral | 3560mg/kg (3560mg/kg) | Union Carbide Data Sheet. Vol. 3/25/1970, |
Consensus Reports
Reported in EPA TSCA Inventory.
Safety Profile
A corrosive material. Moderately toxic by several routes. A severe skin and eye irritant. Combustible. Can react with oxidizing materials. To fight fire, use alcohol foam, dry chemical. When heated to decomposition it emits toxic fumes of NOx.
Hazard Codes
C,
Xi
Risk Statements 34-21/22-36/37
R20/21:Harmful by inhalation and in contact with skin.
R34:Causes burns.
R36/37:Irritating to eyes and respiratory system.
Safety Statements 26-36/37/39-45
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
RIDADR UN 2735 8/PG 2
WGK Germany 2
RTECS QD7700000
F 10-34
HazardClass 8
PackingGroup II
Specification
1.General Description: A colorless liquid with a faint, fishlike odor. Burns, but requires some effort to ignite. Corrosive to tissue. Produces toxic oxides of nitrogen during combustion.
2.Air & Water Reactions :Soluble in water.
3.Reactivity Profile :N-(3-Aminopropyl)morpholine behaves as an amine. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides.
4.Health Hazard :TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
5.Fire Hazard: Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated.