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| CAS No.: | 123-77-3 |
|---|---|
| Name: | Azodicarbonamide |
| Molecular Structure: | |
|
|
|
| Formula: | C2H4N4O2 |
| Molecular Weight: | 116.079 |
| Synonyms: | FerrocellAZC 13R;Ficel AC;Ficel EP-A;Genitron EPC;Genitron EPE;HM 80A;Kempore;Kempore 125;Kempore 200;Kempore 60/40;Kempore R 125;Lagocell 20;Lucel ADA;Luvopor 9241;Luvopor ABF70P-FF;MB 31;NSC 41038;NSC 674447;Nortech MF 1062FA;Paramid K 1;PinholeACR 3;Pinhole AK 2;Poramid K 1;Porofor 505;Porofor ADC;S 643;SO 20;SO-G 3;SO-G 3 (foamer);SOL;Supercell AZ 2D;Supercell K-D;Supercell L-D;SupercellV-D;Tracel DB 201/50PE;Unicell D;Unicell D 1500;Azodicarbonamide (NX-4000);Formamide, 1,1'-azobis- (6CI,8CI);1,1'-Azobis[formamide];1,1'-Azobiscarbamide;1,1'-Azodiformamide;1500TID;A 9660;AA 110S;ABFA;AC (foaming agent);AC 1000 (blowing agent);AC 170;AC 1C;AC 1L;AC 2F-K3;AC 3000;AC 3C2;AC 3K2;AC-EFS;AC-K 3;AC-K-F 3;AC-LQ;AC-R;ADC;ADC 21;ADK Stab OF 14;AW 9;AZ 120;AZ 130;AZ 199;AZ 3050I;AZ 605;AZ Ultra 3050;AZ-H;AZO AZ 130;Azobis 50C;Azobis CA;Azobul;Azobul B;Azocel;Azodicarbamide;Diazenedicarboxamide(9CI);ADC blowing agent; |
| EINECS: | 204-650-8 |
| Density: | 1.87 g/cm3 |
| Melting Point: | 220-225 ºC (dec.) |
| Boiling Point: | 284.8 ºC at 760mmHg |
| Flash Point: | 126 ºC |
| Solubility: | soluble in hot water |
| Appearance: | orange crystalline powder |
| Hazard Symbols: |
 Xn
|
| Risk Codes: | 42-44 |
| Safety: | 22-24-37 |
| Transport Information: | UN 3242 4.1/PG 2 |
| PSA: | 110.90000 |
| LogP: | 0.99660 |
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3,6-dihydro-pyridazine-1,2-dicarboxylic acid diamide
| Conditions | Yield |
|---|---|
| With N,N-dimethyl-formamide at 100℃; |
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1,1'-azobisformamide
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| Conditions | Yield |
|---|---|
| With dibenzoyl peroxide |
- 123-77-3
1,1'-azobisformamide
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| Conditions | Yield |
|---|---|
| With hydrogenchloride In sodium hydroxide; water; dimethyl sulfoxide |
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- Total:33 Page 1 of 1 1
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Chemistry
The Molecular Structure of Azodicarbonamide (CAS NO.123-77-3):
Empirical Formula: C2H4N4O2
Molecular Weight: 116.0788
IUPAC Name: (E)-carbamoyliminourea
Appearance: orange crystalline powder
Nominal Mass: 116 Da
Average Mass: 116.0788 Da
Monoisotopic Mass: 116.033425 Da
Index of Refraction: 1.679
Molar Refractivity: 23.39 cm3
Molar Volume: 61.9 cm3
Surface Tension: 101.7 dyne/cm
Density: 1.87 g/cm3
Flash Point: 126 °C
Enthalpy of Vaporization: 52.38 kJ/mol
Boiling Point: 284.8 °C at 760 mmHg
Storage temp: Flammables area
Water Solubility: SOLUBLE IN HOT WATER
Stability: Highly flammable. Incompatible with strong oxidizing agents, strong acids, strong bases, heavy metal salts
Vapour Pressure: 0.00292 mmHg at 25°C
Synonyms: 1,1’-Azobiscarbamide ; 1,1’-Azobis-formamid ; 1,1’-Azodiformamide ; 1,1'-Azodiformamide ; Azobiscarbonamide ; Azobiscarboxamide
Product Categories: Industrial/Fine Chemicals;pharmacetical;A-B;Alphabetical Listings;Flavors and Fragrances;Azo/Diazo Compounds;Nitrogen Compounds;Organic Building Blocks
Uses
Azodicarbonamide (CAS NO.123-77-3) is used in food industry as a food additive, a flour bleaching agent and improving agent. The principal use of Azodicarbonamide(123-77-3) is in the production of foamed plastics. The thermal decomposition of azodicarbonamide results in the evolution of nitrogen, carbon monoxide , carbon dioxide , and ammonia gases which are trapped in the polymer as bubbles to form a foamed article. Common examples of this application are window and door gaskets, padded floor mats, gym/exercise mats, shoe soles etc...
Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| rat | LD50 | intraperitoneal | 440mg/kg (440mg/kg) | LUNGS, THORAX, OR RESPIRATION: RESPIRATORY STIMULATION GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA" SKIN AND APPENDAGES (SKIN): HAIR: OTHER | Acute Toxicity Data. Journal of the American College of Toxicology, Part B. Vol. 15(Suppl, |
| rat | LD50 | oral | > 6400mg/kg (6400mg/kg) | American Industrial Hygiene Association Journal. Vol. 48, Pg. 127, 1987. | |
| rat | LD50 | skin | > 500mg/kg (500mg/kg) | Acute Toxicity Data. Journal of the American College of Toxicology, Part B. Vol. 15(Suppl, |
Safety Profile
Hazard Codes: 
Xn
Risk Statements: 42-44
R42: May cause sensitization by inhalation
R44: Risk of explosion if heated under confinement
Safety Statements: 22-24-37
S22: Do not breathe dust
S24: Avoid contact with skin
S37: Wear suitable gloves
RIDADR: UN 3242 4.1/PG 2
WGK Germany: 1
RTECS: LQ1040000
HazardClass: 4.1
PackingGroup: II
Azodicarbonamide (CAS NO.123-77-3) is a respiratory sensitiser (a possible cause of asthma) and it should be labeled with "May cause sensitisation by inhalation." Azodicarbonamide (CAS NO.123-77-3) may cause an allergic reaction in those sensitive to other azo compounds (such as food dyes). The consumption of azodicarbonamide may also heighten an allergic reaction to other ingredients in a food. Panera Bread uses Azodicarbonamide in their bagels. It should be noted that during the bread baking process azodicarbonamide is completely decomposed into gasses (carbon dioxide, carbon monoxide, nitrogen, and ammonia) and therefore is never eaten.