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123640-93-7

Basic Information
CAS No.: 123640-93-7
Name: 4 4'-BIS(TRIETHOXYSILYL)-1 1'-BIPHENYL
Article Data: 2
Molecular Structure:
Molecular Structure of 123640-93-7 (4 4'-BIS(TRIETHOXYSILYL)-1 1'-BIPHENYL)
Formula: C24H38 O6 Si2
Molecular Weight: 478.733
Synonyms: Silane,[1,1'-biphenyl]-4,4'-diylbis[triethoxy- (9CI);4,4'-Bis(triethoxysilyl)-1,1'-biphenyl; 4,4'-Bis(triethoxysilyl)biphenyl
Density: 1.047 g/mL at 25oC(lit.)
Boiling Point: 203-206oC0.3 mm Hg(lit.)
Flash Point: >230 °F
Safety:
WGK Germany 3
PSA: 55.38000
LogP: 3.86440
Synthetic route
78-10-4

tetraethoxy orthosilicate

92-86-4

4-(4-bromophenyl)bromobenzene

123640-93-7

4,4'-bis(triethoxysilyl)-1,1'-biphenyl

Conditions
ConditionsYield
With magnesium In tetrahydrofuran at 75℃; for 120h;34%
With magnesium In tetrahydrofuran at 74.85℃; for 120h;16%
123640-93-7

4,4'-bis(triethoxysilyl)-1,1'-biphenyl

183387-28-2

1,3,5,7,9,11,14-heptacyclopentyltricyclo[7.3.3.15,11]heptasiloxane-endo-3,7,14-triol

C82H134O24Si16

Conditions
ConditionsYield
With tetramethyl ammoniumhydroxide In methanol; ethanol at 0 - 5℃; for 24h; Cooling with ice;75.9%
106-37-6

1.4-dibromobenzene

123640-93-7

4,4'-bis(triethoxysilyl)-1,1'-biphenyl

4,4'-bis(tris(4-bromophenyl)silyl)-1,1'-biphenyl

Conditions
ConditionsYield
Stage #1: 1.4-dibromobenzene With n-butyllithium In diethyl ether at -78℃; for 1.25h; Inert atmosphere;
Stage #2: 4,4'-bis(triethoxysilyl)-1,1'-biphenyl In diethyl ether for 12h; Inert atmosphere; Cooling;
60%
112-03-8

trimethyloctadecylammonium chloride

123640-93-7

4,4'-bis(triethoxysilyl)-1,1'-biphenyl

C21H32O3Si2

Conditions
ConditionsYield
With sodium hydroxide In water at 19.84 - 94.84℃; for 42h;
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    Business Type:Lab/Research institutions

    Tel:86-731-85570686

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    Business Type:Trading Company

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