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127-18-4

Basic Information
CAS No.: 127-18-4
Name: Ethene,1,1,2,2-tetrachloro-
Molecular Structure:
Molecular Structure of 127-18-4 (Ethene,1,1,2,2-tetrachloro-)
Formula: C2Cl4
Molecular Weight: 165.83
Synonyms: Ethene,tetrachloro- (9CI);Ethylene, tetrachloro- (8CI);1,1,2,2-Tetrachloroethene;Ankilostin;Antisal 1;Asahi Perchlor;Didakene;Dilatin PT;Ethylene tetrachloride;F 1110;F 1110 (halocarbon);Fedal-Un;Freon 1110;NSC 9777;Nema;PCE;PCE (chlorohydrocarbon);PerSec;Perchlorethylene;Perchloroethylene;Perclene;Perklone;PersaP 3;R 1110;Tetlen;Tetracap;Tetraguer;Tetraleno;Tetropil;
EINECS: 204-825-9
Density: 1.653 g/cm3
Melting Point: -22 °C
Boiling Point: 119.1 °C at 760 mmHg
Flash Point: 27.4 °C
Solubility: 0.015 g/100 mL (20 °C) in water
Appearance: colourless liquid with ether-like odour
Hazard Symbols: HarmfulXn,DangerousN,ToxicT,FlammableF
Risk Codes: 40-51/53-23/25-11-39/23/24/25-23/24/25
Safety: 23-36/37-61-45-24-16-7
Transport Information: UN 1897 6.1/PG 3
PSA: 0.00000
LogP: 3.06820
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  • TetrachloroethyleneCAS NO.: 127-18-4

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  • Perchlorethylene

  • Casno:

    127-18-4

    Perchlorethylene

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Specification

The IUPAC name of Perchlorethylene is 1,1,2,2-tetrachloroethene. With the CAS registry number 127-18-4, it is also named as Tetrachloroethylene. The product's categories are Organics; Analytical Chemistry; Standard Solution of Volatile Organic Compounds for Water & Soil Analysis; Standard Solutions (VOC). Besides, it is colourless liquid with ether-like odour, which should be stored in a cool, dry, ventilated warehouse at 0-6 °C. It is stable, but incompatible with strong oxidizing agents, alkali metals, aluminium, strong bases. In addition, its molecular formula is C2Cl4 and molecular weight is 165.83.

The other characteristics of this product can be summarized as: (1)EINECS: 204-825-9; (2)ACD/LogP: 2.95; (3)# of Rule of 5 Violations: 0; (4)ACD/LogD (pH 5.5): 2.95; (5)ACD/LogD (pH 7.4): 2.95; (6)ACD/BCF (pH 5.5): 102.96; (7)ACD/BCF (pH 7.4): 102.96; (8)ACD/KOC (pH 5.5): 960.03; (9)ACD/KOC (pH 7.4): 960.03; (10)#H bond acceptors: 0; (11)#H bond donors: 0; (12)#Freely Rotating Bonds: 0; (13)Index of Refraction: 1.519; (14)Molar Refractivity: 30.45 cm3; (15)Molar Volume: 100.3 cm3; (16)Surface Tension: 35.6 dyne/cm; (17)Density: 1.653 g/cm3; (18)Flash Point: 27.4 °C; (19)Melting Point: -22 °C; (20)FreezingPoint: -22.0 °C; (21)Solubility in water: 0.015 g/100 mL (20 °C); (22)Enthalpy of Vaporization: 34.68 kJ/mol; (23)Boiling Point: 119.1 °C at 760 mmHg; (24)Vapour Pressure: 19.3 mmHg at 25 °C.

Preparation of Perchlorethylene: this chemical can be prepared by the reaction of 1,2-Dichloroethane with Chlorine. This reaction can be catalyzed by a mixture of potassium chloride and aluminium chloride at temperature of 400 °C.
ClCH2CH2Cl + 3 Cl2 → Cl2C=CCl2 + 4 HCl

Uses of Perchlorethylene: thos chemical is an excellent solvent for organic materials. It is often used in dry cleaning. And it is also used as a mixture with other chlorocarbons to degrease metal parts in the automotive and other metalworking industries. Additionally, it can be used as paint stripper and spot remover. It has been used for the treatment for hookworm infestation. Furthermore, it can be used as an intermediate in the manufacture of HFC-134a and related refrigerants.

When you are using this chemical, please be cautious about it as the following: it may cause damage to health which is reflected in some aspects. It is toxic by inhalation and if swallowed or in contact with skin, and may even have very serious irreversible effect. Then it has limited evidence of a carcinogenic effect to our health. It is not only harmful to our health but also to our environment. This is dangerous for the environment  for it  may present an immediate or delayed danger to one or more components of the environment; Then it is toxic to aquatic organisms and may cause long-term adverse effects in the aquatic environment. What's more, it is highly flammable because it may catch fire in contact with air, only needing brief contact with an ignition source, and it has a very low flash point or evolve highly flammable gases in contact with water.

People can use the following data to convert to the molecule structure.
(1)Canonical SMILES: C(=C(Cl)Cl)(Cl)Cl
(2)InChI: InChI=1S/C2Cl4/c3-1(4)2(5)6
(3)InChIKey: CYTYCFOTNPOANT-UHFFFAOYSA-N

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
cat LDLo oral 4gm/kg (4000mg/kg) BEHAVIORAL: SLEEP

BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
American Journal of Hygiene. Vol. 9, Pg. 430, 1929.
child TDLo oral 545mg/kg (545mg/kg) BEHAVIORAL: COMA Journal of Toxicology, Clinical Toxicology. Vol. 23, Pg. 103, 1985.
dog LD50 intraperitoneal 2100mg/kg (2100mg/kg) LIVER: LIVER FUNCTION TESTS IMPAIRED Toxicology and Applied Pharmacology. Vol. 10, Pg. 119, 1967.
dog LDLo intravenous 85mg/kg (85mg/kg)   Quarterly Journal of Pharmacy & Pharmacology. Vol. 7, Pg. 205, 1934.
dog LDLo oral 4gm/kg (4000mg/kg) BEHAVIORAL: SLEEP

BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
American Journal of Hygiene. Vol. 9, Pg. 430, 1929.
human TCLo inhalation 96ppm/7H (96ppm) PERIPHERAL NERVE AND SENSATION: LOCAL ANESTHETIC

SENSE ORGANS AND SPECIAL SENSES: CONJUNCTIVE IRRITATION: EYE

BEHAVIORAL: "HALLUCINATIONS, DISTORTED PERCEPTIONS"
National Technical Information Service. Vol. PB257-185,
man TCLo inhalation 600ppm/10M (600ppm) SENSE ORGANS AND SPECIAL SENSES: CONJUNCTIVE IRRITATION: EYE

BEHAVIORAL: GENERAL ANESTHETIC
AMA Archives of Industrial Hygiene and Occupational Medicine. Vol. 5, Pg. 566, 1952.
mouse LC50 inhalation 5200ppm/4H (5200ppm)   Acta Pharmacologica et Toxicologica. Vol. 9, Pg. 303, 1953.
mouse LD intraperitoneal > 500mg/kg (500mg/kg)   "Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. Vol. 4, Pg. 378, 1952.
mouse LD50 oral 8100mg/kg (8100mg/kg) BEHAVIORAL: GENERAL ANESTHETIC National Technical Information Service. Vol. PB257-185,
mouse LD50 subcutaneous 65gm/kg (65000mg/kg) BEHAVIORAL: SLEEP

BEHAVIORAL: ATAXIA
Journal of Pharmacology and Experimental Therapeutics. Vol. 123, Pg. 224, 1958.
rabbit LD skin > 3228mg/kg (3228mg/kg)   National Technical Information Service. Vol. AD-A180-198,
rabbit LDLo oral 5gm/kg (5000mg/kg) BEHAVIORAL: SLEEP

BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
American Journal of Hygiene. Vol. 9, Pg. 430, 1929.
rabbit LDLo subcutaneous 2200mg/kg (2200mg/kg)   Quarterly Journal of Pharmacy & Pharmacology. Vol. 7, Pg. 205, 1934.
rat LC50 inhalation 34200mg/m3/8H (34200mg/m3)   American Industrial Hygiene Association Journal. Vol. 20, Pg. 364, 1959.
rat LD50 intraperitoneal 4678mg/kg (4678mg/kg)   Environmental Research. Vol. 40, Pg. 411, 1986.
rat LD50 oral 2629mg/kg (2629mg/kg)   American Industrial Hygiene Association Journal. Vol. 20, Pg. 364, 1959.
rat LDLo intratracheal 450mg/kg (450mg/kg)   National Technical Information Service. Vol. OTS0520615,