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| CAS No.: | 1273-82-1 |
|---|---|
| Name: | Aminoferrocene |
| Article Data: | 92 |
| Molecular Structure: | |
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| Formula: | C10H11 Fe N |
| Molecular Weight: | 201.051 |
| Synonyms: | Ferrocenylamine(8CI); Iron, (aminocyclopentadienyl)cyclopentadienyl- (6CI,7CI);Aminoferrocene; Ferrocenamine |
| Melting Point: | 153-155 °C |
| Risk Codes: | -36/38 |
| Safety: | 26 |
| PSA: | 26.02000 |
| LogP: | 1.74080 |
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- 1273-82-1
aminoferrocene
| Conditions | Yield |
|---|---|
| With hydrogenchloride; zinc In ethanol; water; benzene | 100% |
| With sodium hydroxide In ethanol; water; benzene | 76% |
| With hydrogenchloride In hydrogenchloride hydrolysis in conc. aq. HCl at room temp.; | 44% |
| With sulfuric acid In sulfuric acid hydrolysis in 98% H2SO4 at room temp.; | 10% |
| Conditions | Yield |
|---|---|
| In ethanol Ar, hydrazine added to a soln. of Fe compd., refluxed for 2 h; cooled to ambient temp., water added, extd. (diethyl ether), extract dried (Na2SO4), evapd. (vac.) to dryness; elem. anal.; | 99% |
| In dichloromethane at 0 - 20℃; for 1h; | 83% |
| In ethanol boiling; | |
| In ethanol Fe complex treated with H2NNH2*H2O in EtOH at room temp.; according to B. Bildstein et al., Organometallics, 1999, 18, 4325 and K. Heinze, M. Schlenker, Eur. J. Inorg. Chem., 2004, 2974; |
| Conditions | Yield |
|---|---|
| With hydrazine hydrate In ethanol for 2h; Reflux; Inert atmosphere; Schlenk technique; Glovebox; | 99% |
| With hydrazine In ethanol; water Ar-atmosphere; refluxing for 2 h; addn. of H2O, extn. (ether), drying (Na2SO4), evapn.; | 96.8% |
| With hydrazine hydrate In ethanol (N2); | 82% |
| Conditions | Yield |
|---|---|
| In isopropyl alcohol under Ar, Schlenk setup, iron compd. (2.87 mmol) suspn. heated at 60°C to complete dissolution, treated with Pd on charcoal (0.09 equiv.), H2 passed for 90 min, solvent evapd.; elem. anal.; | 96% |
- 98639-14-6
benzyl N-ferrocenylcarbamate
- 1273-82-1
aminoferrocene
| Conditions | Yield |
|---|---|
| With hydrogen In methanol 70 bar H2, 75°C; | 96% |
| With palladium on activated charcoal; hydrogen In ethanol 3.5 bar H2, 25-45°C; | 84% |
| With potassium hydroxide In water hydrolysis; |
- 1273-82-1
aminoferrocene
| Conditions | Yield |
|---|---|
| With potassium hydroxide In water under N2, educt dissolved in N2-satd. water, KOH soln. added; extd. with Et2O, dried over Na2SO4, evapd., dried in vac.; | 90% |
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Chemistry
Molecular Structure of Aminoferrocene (CAS NO. 1273-82-1):
Systematic Name: (2-Aminocyclopenta-2,4-dien-1-yl)-cyclopenta-2,4-dien-1-yl-iron
Synonyms: Ferrocenylamine
Molecular Formula: C10H11FeN
Molecular Weight: 201.05
CAS Registry Number: 1273-82-1
Polar Surface Area: 26.02 Å2
Storage Temp.: Refrigerator
Product Categories: Classes of Metal Compounds;Fe (Iron) Compounds;Ferrocenes;Metallocenes;Transition Metal Compounds
Structure Descriptors:
SMILES: C1=CC(C=C1)[Fe]C2C=CC=C2N
InChI: InChI=1/C5H6N.C5H5.Fe/c6-5-3-1-2-4-5;1-2-4-5-3-1;/h1-4H,6H2;1-5H;/rC10H11FeN/c12-10-7-3-6-9(10)11-8-4-1-2-5-8/h1-9H,12H2
InChIKey: JETZZOFQXXBFDQ-AGNZBATFAW
Std. InChI: InChI=1S/C5H6N.C5H5.Fe/c6-5-3-1-2-4-5;1-2-4-5-3-1;/h1-4H,6H2;1-5H
Std. InChIKey: JETZZOFQXXBFDQ-UHFFFAOYSA-N