CAS No.1282-37-7,FERROCENIUM TETRAFLUOROBORATE Suppliers

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Basic Information

CAS No.:

1282-37-7

Name:

FERROCENIUM TETRAFLUOROBORATE

Article Data:

Molecular Structure:

Formula:

C10H10BF4Fe10*

Molecular Weight:

272.841

Synonyms:

FERROCENIUM TETRAFLUOROBORATE;FERROCENIUM TETRAFLUOROBORATE, TECH.

Melting Point:

178 °C (dec.)(lit.)

Boiling Point:

Vapour density:

Solubility:

Toxicity data
(The meaning of any toxi">

Stability

Toxicology

Toxicity data
(The meaning of any toxi

Appearance:

solid

Hazard Symbols:

Risk Codes:

Safety:

Hazard Codes	C
Risk Statements	34
Safety Statements	26-36/37/39-45
RIDADR	UN 3261 8/PG 2
WGK Germany	3

PSA:

0.00000

LogP:

2.35650

Synthetic route

: 67969-82-8
tetrafluoroboric acid diethyl ether

: 102-54-5
ferrocene

: 1282-37-7
ferrocenium(III) tetrafluoroborate

Conditions

Conditions	Yield
In nitromethane; dichloromethane addn. of nitromethane to Fe complex soln. (CH2Cl2) under Ar; addn. of HBF4*Et2O in two portions; stirring, 1h; evapn.; extn. (pentane); stirring with ether; dissoln. in heated CH3CN; filtration through Na2SO4 (free from water) in ether; pptn.; drying (high vac.); elem. anal.;	95%

: 14104-20-2
silver tetrafluoroborate

: 102-54-5
ferrocene

: 1282-37-7
ferrocenium(III) tetrafluoroborate

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: Ag; (Ar or N2), ferrocene in THF treated with 0.8 equiv. of AgBF4 in THF at -78°C; filtered, evapd.(vac.), extd.(CH2Cl2), crystd. at room temp.;	87%

: tetrafluoroboric acid

: 102-54-5
ferrocene

: 1282-37-7
ferrocenium(III) tetrafluoroborate

Conditions

Conditions	Yield
In diethyl ether; nitromethane; dichloromethane 12 h;; removing solvent; extn. with petroleum ether 4 times (40-60°C); stirring with ether; filtn.; drying; elem.anal.;;	78%
With p-benzoquinone In diethyl ether; water

: 102-54-5
ferrocene

: 1282-37-7
ferrocenium(III) tetrafluoroborate

Conditions

Conditions	Yield
With boron trifluoride diethyl etherate; oxygen In not given passing O2 trough soln. of ferrocene and boron trifluoride etherate;;	45%
With O2; boron trifluoride etherate In not given passing O2 trough soln. of ferrocene and boron trifluoride etherate;;	45%
With p-benzoquinone In benzene addn. of BF3 or boron trifluoride etherate soln. of ferrocene and p-benzoquinone in benzene;;
With BF3 or boron trifluoride etherate; p-benzoquinone In benzene addn. of BF3 or boron trifluoride etherate soln. of ferrocene and p-benzoquinone in benzene;;

: 102-54-5
ferrocene

: 7637-07-2
boron trifluoride

: 1282-37-7
ferrocenium(III) tetrafluoroborate

Conditions

Conditions	Yield
With oxygen In diethyl ether byproducts: O2(2-); presence of BF3;;
With O2 In diethyl ether byproducts: O2(2-); presence of BF3;;

: 102-54-5
ferrocene

: 429-42-5
tetrabutylammonium tetrafluoroborate

: 1282-37-7
ferrocenium(III) tetrafluoroborate

Conditions

Conditions	Yield
In acetonitrile Electrochem. Process; Ar atmosphere; oxidn. (Pt mesh, 48.0 C); removal of MeCN (vac., room temp.), no further purification;

: 13755-29-8
sodium tetrafluoroborate

: ferricinium chloroferrate

: 1282-37-7
ferrocenium(III) tetrafluoroborate

Conditions

Conditions	Yield
In water cooling to -5°C, filtration, washing with water, then with THF, drying in vac.;

: 102-54-5
ferrocene

: nitrosonium tetrafluoroborate

: 1282-37-7
ferrocenium(III) tetrafluoroborate

Conditions

Conditions	Yield
In dichloromethane prepn. by oxidn. of Cp2Fe with nitrosonium tetrafluoroborate;
In dichloromethane

: 38117-54-3
cyclopentadienyl iron(II) dicarbonyl dimer

: 1282-37-7
ferrocenium(III) tetrafluoroborate

: 75-18-3
dimethylsulfide

: {Fe(CO)2(Me2S)(η5-C5H5)}BF4

Conditions

Conditions	Yield
In dichloromethane byproducts: (C5H5)2Fe; addn. of ferricinium compd. to Fe complex soln. in the presence of SMe2under Ar; filtration; evapn. to 1/3 the volume; addn. of ether/pentane 3/1); pptn.; thoroughly washing (ether, pentane); drying (high vac.);	99%

...Expand

: 1282-37-7
ferrocenium(III) tetrafluoroborate

: 95865-41-1
dicarbonyl(η5-cyclopentadienyl)(η1-7-methoxy-1-cycloheptenyl)iron

A: 102-54-5
ferrocene

B: 95865-47-7
dicarbonyl(η5-cyclopentadienyl)(η1-7-methoxycycloheptene-1-carbonyl)iron

Conditions

Conditions	Yield
With `CO In dichloromethane Addn. of Cp2FeBF4 to iron-compd. (methylene chloride, 55 psiCO, 1h).; Removal of solvent (vacuo), elution with hexane (alumina column) gives yellow band of ferrocene, elution with CH2Cl2 gives yellow band of dicarbonyl complex, elem. anal.;	A n/a B 99%

...Expand

Raw Materials