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1304-29-6

Basic Information
CAS No.: 1304-29-6
Name: Barium peroxide
Molecular Structure:
Molecular Structure of 1304-29-6 (Barium peroxide)
Formula: BaO2
Molecular Weight: 169.34
Synonyms: Bariumoxide (BaO2);Barium peroxide(Ba(O2));
EINECS: 215-128-4
Density: 4.96 g/cm3
Melting Point: 450 °C
Boiling Point: 150.2 °C at 760 mmHg
Flash Point: 21 °C
Solubility: Insoluble in water
Appearance: greyish white powder
Hazard Symbols: OxidizingO,HarmfulXn
Risk Codes: 8-20/22
Safety: 13-27
Transport Information: UN 1449 5.1/PG 2
PSA: 46.12000
LogP: -0.23760
Synthetic route

barium(II) oxide

1304-29-6

barium peroxide

Conditions
ConditionsYield
With water at 500-600°C; with oxygen containing 0.001g H2O/l;100%
With water at 400°C with oxygen containing 0.001g H2O/l;94.6%
With water at 750°C with oxygen containing 0.001g H2O/l;61.9%

barium hexammine

A

1304-29-6

barium peroxide

B

barium(II) oxide

Conditions
ConditionsYield
With oxygen -35°C;A 7.5%
B 92.5%
With oxygen -50°C;A 9.1%
B 90.9%
With oxygen at low temp.;
7440-39-3

barium

A

1304-29-6

barium peroxide

B

barium(II) oxide

Conditions
ConditionsYield
In ammonia conducting oxygen into Ba soln. in NH3 liq.;A 9.07%
B n/a
7440-39-3

barium

1304-29-6

barium peroxide

Conditions
ConditionsYield
Kinetics; byproducts: oxygen; Ba-atoms and O3-molecules are brought to reaction in crossed molecular beams to form BaO2 and O-atoms at high collision energies. Lower collision energies lead to BaO and O2 as products.; Reaction products are detected by quadrupole mass spectrometry.;

barium(II) hydroxide

1304-29-6

barium peroxide

Conditions
ConditionsYield
In not given Electrolysis; electrolysis of Ba(OH)2-solution at 0-12°C at using of a diaphragma; the used solution is treated before and during the electrolysis with O3-containing O2 or ozonated CO2-free air; BaO2 ppts.;;
In not given Electrolysis; electrolysis of Ba(OH)2-solution at 0-12°C at using of a diaphragma; the used solution is treated before and during the electrolysis with O3-containing O2 or ozonated CO2-free air; BaO2 ppts.;;

barium carbonate

A

1304-29-6

barium peroxide

B

barium(II) oxide

Conditions
ConditionsYield
With pyrographite exclusion of air, annealing while passing steam into react. mixt.;
With pyrographite exclusion of air, annealing while passing steam into react. mixture;
With pyrographite exclusion of air, annealing while passing steam into react. mixt.;

barium carbonate

1304-29-6

barium peroxide

Conditions
ConditionsYield
gentle glowing;
heating;

barium carbonate

1304-29-6

barium peroxide

Conditions
ConditionsYield
In neat (no solvent) inert conditions, thermal decompg. of BaCO3 (1373 K, 10**(-2) Pa, 100 h), then dry O2 atmosphere (623 -673 K, 100 h, several regrindings); detd. by X-ray diffraction;
With air In neat (no solvent) heating of a mixture of BaCO3 and soot forms BaO; treatment of the hot BaO with air;;

barium(II) oxide

A

barium hypochlorite

B

1304-29-6

barium peroxide

C

barium(II) chloride

Conditions
ConditionsYield
With chlorine In neat (no solvent) Cl2 reacts with BaO at grinding under formation of an instable addition-compound which decomposites to BaO2, BaCl2 and a trace of Ba(ClO)2;;A <1
B n/a
C n/a
With Cl2 In neat (no solvent) Cl2 reacts with BaO at grinding under formation of an instable addition-compound which decomposites to BaO2, BaCl2 and a trace of Ba(ClO)2;;A <1
B n/a
C n/a

barium(II) oxide

1304-29-6

barium peroxide

Conditions
ConditionsYield
With detonating gas 250-280°C;
With oxygen In neat (no solvent) reaction of BaO with O2 under formation of BaO2;;
With air; water at 500-600°C and normal pressure;

barium(II) oxide

A

1304-29-6

barium peroxide

B

barium(II) hydroxide

Conditions
ConditionsYield
With air; water 500°C;
With air; H2O 500°C;

barium(II) oxide

10024-97-2

dinitrogen monoxide

A

barium nitrite

B

1304-29-6

barium peroxide

Conditions
ConditionsYield
In neat (no solvent) reation of N2O with BaO at 480-620°C forms BaO2 and Ba(NO2)2;;

barium(II) oxide

20667-12-3

silver(l) oxide

A

1304-29-6

barium peroxide

B

Ba2Ag2O3

Conditions
ConditionsYield
In neat (no solvent) heating a mixture of 3 mol BaO and 1 mol Ag2O in a stream of N2 at 300-400°C for several days;;
In neat (no solvent) heating a mixture of 3 mol BaO and 1 mol Ag2O in a stream of N2 at 300-400°C for several days;;

barium(II) oxide

1304-29-6

barium peroxide

Conditions
ConditionsYield
With hydrogen In not given reaction at 250°C;;
With H2 In not given reaction at 250°C;;
3811-04-9

potassium chlorate

barium(II) oxide

1304-29-6

barium peroxide

Conditions
ConditionsYield
byproducts: KCl; gentle glowing; leaching off KCl from the cooled melt (water); hydrated BaO2;

lead(II) oxide

barium(II) hydroxide

A

1304-29-6

barium peroxide

B

bariumorthoplumbate(IV)

Conditions
ConditionsYield
In melt equal wt. amts.;A 0%
B n/a
In melt equal wt. amts.;A 0%
B n/a

molybdenum(VI) oxide

barium(II) chloride

barium(II) hydroxide

1304-29-6

barium peroxide

Conditions
ConditionsYield
With Al2O3 In neat (no solvent) heating (air, 300 K/h to 1073 K, 5 h at 1073 K), slowly cooling to 923 K (4.2 K/h);
7440-39-3

barium

1304-29-6

barium peroxide

Conditions
ConditionsYield
With air burning;
7440-39-3

barium

1304-29-6

barium peroxide

Conditions
ConditionsYield
burning;
With water 500°C; with dry oxygen;<1
12337-90-5

barium peroxide * hydrogen peroxide

1304-29-6

barium peroxide

Conditions
ConditionsYield
careful drying;
careful drying;

barium peroxide 8-hydrate

1304-29-6

barium peroxide

Conditions
ConditionsYield
100°C; 2 wk standing above P2O5 in vac. at 350°C;
above 200°C;
careful drying;

barium(II) nitrate

1304-29-6

barium peroxide

Conditions
ConditionsYield
heating;
heating;
With O2 In water precipitation from oxygenated water; XRD;

barium(II) nitrate

7722-84-1

dihydrogen peroxide

1304-29-6

barium peroxide

Conditions
ConditionsYield
With NH3 In water pptn. on addn. of NH3 and H2O2 to aq. Ba(NO3)2; drying (O2 flow, 200°C);

barium hydroxide octahydrate

7722-84-1

dihydrogen peroxide

1304-29-6

barium peroxide

Conditions
ConditionsYield
In water boiling of a solution of Ba(OH)2*8H2O in H2O for a longer period of time; addition of 3% H2O2-solution ppts. BaO2*8H2O; sucking off and washing; draining over P2O5 at roomtemperature;; contains 98.87-99.33% BaO2;;
In water filtration of a solution of Ba(OH)2*8H2O in destillated H2O in CO2-free O2-atmosphere; addition of 1% H2O2-solution ppts. BaO2*8H2O; sucking off, washing and drying at 95°C for 5 min in CO2-free O2; draining in vac. at 90°C for 20 min;; content: 97.4% BaO2, 1.4% BaO and 1.2% H2O + CO2;;

Ba(2+)*O2(2-)*99H2O=BaO2*99H2O

1304-29-6

barium peroxide

Conditions
ConditionsYield
byproducts: H2O; at 700°C in pure dry oxygen stream; pure prod. with little hydroxide content;

Ba(2+)*O2(2-)*2H2O2=BaO2*2H2O2

1304-29-6

barium peroxide

Conditions
ConditionsYield
careful drying;
careful drying;

A

1304-29-6

barium peroxide

B

mercury

C

barium(II) hydroxide

D

barium(II) oxide

Conditions
ConditionsYield
With barium amalgam not very dry oxygen;A <1
B n/a
C n/a
D n/a
1304-29-6

barium peroxide

Conditions
ConditionsYield
With barium amalgam 10h, 60 atm, 15°C;
With barium amalgam >10h, 60 atm, 15°C; or 1h, 60 atm, 100°C;0%

barium(II) hydroxide

1304-29-6

barium peroxide

Conditions
ConditionsYield
In melt blowing air or oxygen into the melt at 400-600°C; sieving in melt;
10h, 60 atm, 15°C;0%
In water Electrolysis; blowing oxygen into a cooled soln.;
In water Electrolysis; blowing oxygen into a cooled soln.;
1304-29-6

barium peroxide

barium(II) oxide

Conditions
ConditionsYield
1h at 1150°C in electric oven;100%
With metals heating;
iron(III) oxide byproducts: oxygen; beginning of oxygen formation at 200-250°C;

copper(I) oxide

yttrium(III) oxide

1304-29-6

barium peroxide

copper(II) oxide

Ba2Cu3O(x)Y, tetragonal

Conditions
ConditionsYield
In neat (no solvent) High Pressure; the mixt. of the oxides was placed in a pyrophyllite container with a graphite heater lined with a Pt foil in a toroidal high-pressure chamber; 1.0 GPa, 940°C, 10 min.;;100%
7440-36-0

antimony

1304-29-6

barium peroxide

7440-39-3

barium

7440-43-9

cadmium

A

Ba3Cd2Sb4

B

Ba11Cd6Sb12

C

Ba5Cd2O0.7Sb5

Conditions
ConditionsYield
In neat (no solvent) (Ar or vac.); heated to 900°C at a rate of 200°C/h, kept at 900°C for 20 h, cooled to 500°C at a rate of 5°C/h; allowed to cool to room temp.;A 1%
B 1%
C 99%

chromium(III) oxide

1304-29-6

barium peroxide

barium chromate

Conditions
ConditionsYield
In solid heating mixt. of educts in air, O2 or N2 atm. at 450 °C, 10 min.;;95%
In neat (no solvent, solid phase) heating mixt. of educts in air, O2 or N2 atm. at 450 °C, 10 min.;;95%

yttrium(III) oxide

1304-29-6

barium peroxide

7440-05-3

palladium

barium carbonate

copper(II) oxide

A

diyttrium barium copper(II) pentoxide

B

barium cuprate

C

YBa2Cu2.5Pd0.5O6.8

Conditions
ConditionsYield
In neat (no solvent, solid phase) a mixt. of 1BaCO3 + 1BaO2 + 0.5Y2O3 + 1 Pd is heated in a silica crucible at 815°C (22 h); at temps. above 850°C, YBa2Cu(3-x)Pd(x)O(y) is decomposed; at temps. below 800°C, BaCuO2 is the major phase; Cu(3+) content detd. by chem. anal.;A n/a
B n/a
C 90%

yttrium(III) oxide

1304-29-6

barium peroxide

7440-05-3

palladium

barium carbonate

copper(II) oxide

YBa2Cu2.5Pd0.5O6.8

Conditions
ConditionsYield
In neat (no solvent) heated in alumina crucibles at 815°C;90%
1304-29-6

barium peroxide

titanium(IV) oxohydroxide

A

barium titanate

B

barium carbonate

Conditions
ConditionsYield
With air explosive compression of a powder mixture of the reaction components;A 80%
B 10%

chromium(III) oxide

1304-29-6

barium peroxide

7429-90-5

aluminium

7440-47-3

chromium

Conditions
ConditionsYield
96% of the theoretically necessary Al; 80% BaO2 refer to used Al amt.; Al content: <0.1%;74.3%
96% of the theoretically necessary Al; 80% BaO2 refer to used Al amt.; Al content: <0.1%;74.3%
96% of the theoretically necessary Al; 30% BaO2 refer to used Al amt.; Al content: <.1%;65%
96% of the theoretically necessary Al; 30% BaO2 refer to used Al amt.; Al content: <.1%;65%
1304-29-6

barium peroxide

rutile

A

barium titanate

B

barium carbonate

Conditions
ConditionsYield
With air explosive compression of a powder mixture of the reaction components;A 70%
B 20%
Conditions
ConditionsYield
With oxygen In solid solid combustion synthesis, mixed, pressed, ignited under O2 atmosphere, powdered and recompacted products resintered;A 35%
B 65%
With oxygen In solid solid combustion synthesis, mixed, pressed, ignited under O2 atmosphere; BaCuO2: main product;A n/a
B 30%
With oxygen In solid pellets fired twice in the conventional way;A 5%
B n/a

yttrium(III) oxide

1304-29-6

barium peroxide

copper(II) oxide

A

copper(I) oxide

B

diyttrium barium copper(II) pentoxide

Ba2Cu3O(x)Y, tetragonal

Conditions
ConditionsYield
In neat (no solvent) High Pressure; the mixt. of the oxides was placed in a pyrophyllite container with a graphite heater lined with a Pt foil in a toroidal high-pressure chamber; 1.0 GPa, 940°C, 10 min.;;A n/a
B n/a
C 60%
With Cu In neat (no solvent) High Pressure; the mixt. of the oxides was placed in a pyrophyllite container with a graphite heater lined with a Cu foil in a toroidal high-pressure chamber; 2.0 GPa, 940°C, 10 min.;;A n/a
B n/a
C 10%
With Cu In neat (no solvent) High Pressure; the mixt. of the oxides was placed in a pyrophyllite container with a graphite heater lined with a Cu foil in a toroidal high-pressure chamber; 1.0 GPa, 940°C, 10 min.;;A n/a
B n/a
C 5%
1304-29-6

barium peroxide

titanium(IV) oxide

A

barium titanate

B

barium carbonate

Conditions
ConditionsYield
With air explosive compression of a powder mixture of the reaction components;A 40%
B 50%

potassium cyanide

1304-29-6

barium peroxide

584-08-7

potassium carbonate

potassium nitrate

Conditions
ConditionsYield
after 3 h;40%
after 3 h;40%
1304-29-6

barium peroxide

barium carbonate

Conditions
ConditionsYield
With air explosive compression;30%
With alkali carbonate In water byproducts: alkali peroxide;
With alkali carbonate In water byproducts: alkali peroxide;
1304-29-6

barium peroxide

aluminium oxide

A

barium monoaluminate

B

barium hexa-aluminate

alumina

Conditions
ConditionsYield
mechanical activation, annealing at 1200°C; detd. by X-ray diffraction and scanning electron microscopy;A 1%
B n/a
C n/a
mechanical activation, annealing at 1100 or 1300°C; detd. by X-ray diffraction and scanning electron microscopy;
1633-05-2

strontium(II) carbonate

1304-29-6

barium peroxide

lead(II) oxide

1304-76-3

bismuth(III) oxide

Ba0.75Sr0.25Pb0.8Bi0.2O3

Conditions
ConditionsYield
With air In neat (no solvent) heating of components at 850-900°C for 48 h;
1633-05-2

strontium(II) carbonate

1304-29-6

barium peroxide

124-38-9

carbon dioxide

barium carbonate

copper(II) oxide

0.3Sr(2+)*1.7Ba(2+)*Cu(2+)*2O(2-)*CO3(2-)=Sr0.3Ba1.7CuO2CO3

Conditions
ConditionsYield
With air used an alumina crucible with a lid, samples are fired in air in a temp. range of 900 to 935°C; powder x-ray diffraction;
1633-05-2

strontium(II) carbonate

1304-29-6

barium peroxide

124-38-9

carbon dioxide

barium carbonate

copper(II) oxide

0.65Sr(2+)*1.35Ba(2+)*Cu(2+)*2O(2-)*CO3(2-)=Sr0.65Ba1.35CuO2CO3

Conditions
ConditionsYield
With air used an alumina crucible with a lid, attempts are made under a moderate flow of N2 with one end of the furnace tube open to the air, firing the samples in a temp. range of 900 to 935°C several times to ensure homogenity and phase purity; powder x-ray diffraction;
1633-05-2

strontium(II) carbonate

1304-29-6

barium peroxide

124-38-9

carbon dioxide

barium carbonate

copper(II) oxide

0.9Sr(2+)*1.1Ba(2+)*Cu(2+)*2O(2-)*CO3(2-)=Sr0.9Ba1.1CuO2CO3

Conditions
ConditionsYield
With air used an alumina crucible with a lid, attempts are made under a moderate flow of N2 with one end of the furnace tube open to the air, firing the samples in a temp. range of 900 to 935°C several times to ensure homogenity and phase purity; powder x-ray diffraction;
1633-05-2

strontium(II) carbonate

1304-29-6

barium peroxide

124-38-9

carbon dioxide

barium carbonate

copper(II) oxide

0.4Sr(2+)*1.6Ba(2+)*Cu(2+)*2O(2-)*CO3(2-)=Sr0.4Ba1.6CuO2CO3

Conditions
ConditionsYield
With air used an alumina crucible with a lid, firing the samples in air in a temp. range of 900 to 935°C several times to ensure homogenity and phase purity; powder x-ray diffraction;
1633-05-2

strontium(II) carbonate

1304-29-6

barium peroxide

124-38-9

carbon dioxide

barium carbonate

copper(II) oxide

0.5Sr(2+)*1.5Ba(2+)*Cu(2+)*2O(2-)*CO3(2-)=Sr0.5Ba1.5CuO2CO3

Conditions
ConditionsYield
With air used an alumina crucible with a lid, sample is fired in air in a temp. range of 900 to 935°C; powder x-ray diffraction;
1633-05-2

strontium(II) carbonate

1304-29-6

barium peroxide

124-38-9

carbon dioxide

barium carbonate

copper(II) oxide

2Ba(2+)*Cu(2+)*2O(2-)*CO3(2-)=Ba2CuO2CO3

Conditions
ConditionsYield
With air used an alumina crucible with a lid, attempts are made under a moderate flow of N2 with one end of the furnace tube open to the air, firing the samples in a temp. range of 900 to 935°C several times to ensure homogenity and phase purity; powder x-ray diffraction;

yttrium(III) oxide

1633-05-2

strontium(II) carbonate

1304-29-6

barium peroxide

lead(II) oxide

calcium oxide

PbBaSrY0.70Ca0.30Cu3O7

Conditions
ConditionsYield
In neat (no solvent, solid phase) further educt CuO; appropriate amts. BaO2, SrCO3, Y2O3, CaO and CuO mixed, sintered twice (930°C, 12, air), cooled, PbO mixed in, heated twice (830°C, 12h, 1%O2-N2); quenched (N2), sintered (740-830°C, 40h, 1%O2-N2), quenched (N2); impurity phase = BaPbO3 (X-ray diffraction), EDX, iodide titration for amt. O;

yttrium(III) oxide

1633-05-2

strontium(II) carbonate

1304-29-6

barium peroxide

lead(II) oxide

calcium oxide

PbBaSrY0.90Ca0.10Cu3O7

Conditions
ConditionsYield
In neat (no solvent, solid phase) further educt CuO; appropriate amts. BaO2, SrCO3, Y2O3, CaO and CuO mixed, sintered twice (930°C, 12, air), cooled, PbO mixed in, heated twice (830°C, 12h, 1%O2-N2); quenched (N2), sintered (740-830°C, 40h, 1%O2-N2), quenched (N2); single phase (X-ray diffraction), EDX, iodide titration for amt. O;

yttrium(III) oxide

1633-05-2

strontium(II) carbonate

1304-29-6

barium peroxide

lead(II) oxide

calcium oxide

PbBaSrY0.75Ca0.25Cu3O7

Conditions
ConditionsYield
In neat (no solvent, solid phase) further educt CuO; appropriate amts. BaO2, SrCO3, Y2O3, CaO and CuO mixed, sintered twice (930°C, 12, air), cooled, PbO mixed in, heated twice (830°C, 12h, 1%O2-N2); quenched (N2), sintered (740-830°C, 40h, 1%O2-N2), quenched (N2); single phase (X-ray diffraction), EDX, iodide titration for amt. O;

yttrium(III) oxide

1633-05-2

strontium(II) carbonate

1304-29-6

barium peroxide

lead(II) oxide

calcium oxide

PbBaSrY0.95Ca0.05Cu3O7

Conditions
ConditionsYield
In neat (no solvent, solid phase) further educt CuO; appropriate amts. BaO2, SrCO3, Y2O3, CaO and CuO mixed, sintered twice (930°C, 12, air), cooled, PbO mixed in, heated twice (830°C, 12h, 1%O2-N2); quenched (N2), sintered (740-830°c, 40h, 1%O2-N2), quenched (N2)L; single phase (X-ray diffraction), EDX, iodide titration for amt. O;

yttrium(III) oxide

1633-05-2

strontium(II) carbonate

1304-29-6

barium peroxide

lead(II) oxide

calcium oxide

PbBa0.8Sr1.2Y0.6Ca0.4Cu3O7

Conditions
ConditionsYield
In neat (no solvent, solid phase) further educt CuO; appropriate amts. BaO2, SrCO3, Y2O3, CaO and CuO mixed, sintered twice (930°C, 12, air), cooled, PbO mixed in, heated twice (830°C, 12h, 1%O2-N2); quenched (N2), sintered (785 or 830°lC, 40h, 1%O2-N2), quenched (N2); EDX, iodide titration for amt. O;
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  • Casno:

    1304-29-6

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Consensus Reports

Reported in EPA TSCA Inventory. Barium and its compounds are on the Community Right-To-Know List.

Standards and Recommendations

OSHA PEL: TWA 0.5 mg(Ba)/m3
ACGIH TLV: TWA 0.5 mg(Ba)/m3; Not Classifiable as a Human Carcinogen
DFG MAK: 0.5 mg(Ba)/m3
DOT Classification:  5.1; Label: Oxidizer, Poison

Specification

The systematic name of this chemical is barium dioxidanediide. With the CAS registry number 1304-29-6, it is also named as Peroxyde de baryum. The product's categories are industrial / fine chemicals; inorganics; oxidation; peroxides; synthetic reagents. It is greyish white powder which is insoluble in water. In addition, it is noncombustible, but accelerates the burning of combustible material. Barium peroxide is one of the most common inorganic peroxides, and it is a peroxide, containing O22- subunits wherein the oxygen atoms bond to each other as well as to the barium. Furthermore, it is not compatible with reducing agents, acids, bases, acetic anhydride, finely powdered metals, hydroxylamine, organic materials, and you must not take it combustible materials, heat and incompatible materials. This chemical should be sealed in the container and stored in the cool and dry place.

The other characteristics of this product can be summarized as: (1)ACD/LogP: -0.43; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -0.42; (4)ACD/LogD (pH 7.4): -0.42; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)#H bond acceptors: 2; (8)#H bond donors: 2; (9)#Freely Rotating Bonds: 1; (10)Enthalpy of Vaporization: 45.09 kJ/mol; (11)Boiling Point: 150.2 °C at 760 mmHg; (12)Vapour Pressure: 1.48 mmHg at 25°C.

Preparation of Barium peroxide: It can be obtained by the reversible absorption of O2 by barium oxide. The oxygen is released above 500°C. 2 BaO + O2 = 2 BaO2

Uses of Barium peroxide: It is used for bleaching. And it is also used in fireworks as an oxidizer, which also gives a vivid green colour, as do all barium compounds.

When you are using this chemical, please be cautious about it as the following:
It may cause fire when contact with combustible material. And it is harmful by inhalation and if swallowed, so peopel should keep away from food, drink and animal foodstuffs. Additionally, it should kept away from combustible material.

People can use the following data to convert to the molecule structure.
1. SMILES:[Ba+2].[O-][O-]
2. InChI:InChI=1/Ba.O2/c;1-2/q+2;-2 
3. InChIKey:ZJRXSAYFZMGQFP-UHFFFAOYAZ

The following are the toxicity data which has been tested.

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 subcutaneous 50mg/kg (50mg/kg)   Zhurnal Vsesoyuznogo Khimicheskogo Obshchestva im. D.I. Mendeleeva. Journal of the D.I. Mendeleeva All-Union Chemical Society. Vol. 19, Pg. 186, 1974.