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1310-66-3

Basic Information
CAS No.: 1310-66-3
Name: Lithium hydroxide monohydrate
Article Data: 25
Molecular Structure:
Molecular Structure of 1310-66-3 (Lithium hydroxide monohydrate)
Formula: LiOH.H2O
Molecular Weight: 41.9636
Synonyms: Lithium hydroxide, monohydrate or lithium hydroxide, solid;Lithium Hydroxide ];Lithium hydroxide, solution;
EINECS: 215-183-4
Density: 1.51 g/cm3
Melting Point: 462 °C
Boiling Point: 100 °C at 760 mmHg
Solubility: 109 g/L (20 °C) in water
Appearance: colourless, hygroscopic crystals
Hazard Symbols: CorrosiveC
Risk Codes: 20/22-35
Safety: 26-36/37/39-45-22
Transport Information: UN 2680 8/PG 2
PSA: 32.29000
LogP: -0.24110
Synthetic route
1310-65-2

lithium hydroxide

1310-66-3

lithium hydroxide monohydrate

Conditions
ConditionsYield
In ethanol; water boiling soln. of LiOH in 62.8 vol.-% alcohol, pptn. of hydrate on vaporization or cooling ;;
With sulfuric acid In water vaporization of cold. concd. LiOH soln. over H2SO4;;
In water aq. LiOH soln.; various conditions;;
554-13-2

lithium carbonate

1310-66-3

lithium hydroxide monohydrate

Conditions
ConditionsYield
With sulfuric acid In sulfuric acid Electrolysis; electrochemical conversion of LiCO3 into LiOH in aq. H2SO4 at temp. 30-40°C in membrane electrolyzer is suggested; soln. of LiOH cooled, evapd. and LiOH*H2O crystd.; product washed with LiOH soln. and dried; elem. anal.;

lithium chloride

1310-66-3

lithium hydroxide monohydrate

Conditions
ConditionsYield
In water Electrolysis; formation by electrolysis of aq. LiCl with a Hg-circulation cathode;; the formed LiOH*H2O is free of Cl(1-), SO4(2-), PO4(3-) and Fe(3+);;
In water
1310-65-2

lithium hydroxide

1310-66-3

lithium hydroxide monohydrate

Conditions
ConditionsYield
In water formation as precipitate on evaporation a aq. soln. of LiOH;;
In water formation as precipitate on evaporation a aq. soln. of LiOH;;
554-13-2

lithium carbonate

1310-66-3

lithium hydroxide monohydrate

Conditions
ConditionsYield
With caustic lime In water reaction of Li2CO3 with caustic lime in aq. soln.;;
With caustic lime In water
109-72-8, 29786-93-4

n-butyllithium

potassium based lithium manganese oxyiodide

potassium based lithium manganese oxyiodide

A

1310-66-3

lithium hydroxide monohydrate

Li(x)Mn(x)O(x), cubic

C

potassium based lithium manganese oxyiodide

Conditions
ConditionsYield
In hexane 1.6 M n-BuLi in hexane, 48 h; ppt. was washed thoroughly with hexane and EtOH, dried in vac., elem. anal., detected by X-ray powder diffractometry;A n/a
B 0%
C n/a
109-72-8, 29786-93-4

n-butyllithium

sodium-based lithium manganese oxyiodide

sodium-based lithium manganese oxyiodide

A

1310-66-3

lithium hydroxide monohydrate

Li(x)Mn(x)O(x), cubic

C

sodium-based lithium manganese oxyiodide

Conditions
ConditionsYield
In hexane 1.6 M n-BuLi in hexane, 48 h; ppt. was washed thoroughly with hexane and EtOH, dried in vac., elem. anal., detected by powder X-ray diffractometry;A n/a
B 0%
C n/a

Li7.9MnN3.2O1.6

A

lithium manganese oxide

B

1310-66-3

lithium hydroxide monohydrate

C

manganese(II) oxide

D

554-13-2

lithium carbonate

Conditions
ConditionsYield
In neat (no solvent) stored in open air for 8 wk; detd. by X-ray diffraction;

Li11.9MnN3.7O3

A

1310-66-3

lithium hydroxide monohydrate

B

manganese(II) oxide

Conditions
ConditionsYield
In neat (no solvent) stored in open air for 8 wk; detd. by X-ray diffraction;

Li34.2MnN3.9O13.7

A

1310-66-3

lithium hydroxide monohydrate

B

manganese(II) oxide

C

554-13-2

lithium carbonate

Conditions
ConditionsYield
In neat (no solvent) stored in open air for 8 wk; detd. by X-ray diffraction;
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    Product Name Lithium Hydroxide CAS No. 1310-66-3 Molecular Formula LiOH·H2O Molecular Weight 41.96 g·mol−1 LiOH

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    Product Name: Lithium hydroxide monohydrate CAS: 1310-66-3 MF: Li.HO.H2O MW: 41.96 EINECS: 603-454-3 Mol File: 1310-66-3.mol Lithium hydroxide monohydrate Structure Lithium hydroxide monohydrate Chemical Properties Melting point

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    Lithium hydroxide monohydrate CAS: 1310-66-3 Specification Lithium hydroxide mono (Industrial grade) CAS No: 1310-66-3 Appearance: White crystal LiOH: 56.5% min. CO32-: 0.5% max K: 0.005% max Na: 0.005% max Mg: 0.005% max Mn: 0.005% max Si : 0.005%

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Specification

The Lithium hydroxide monohydrate, with the CAS registry number 1310-66-3,is also known as Lithium hydroxide. It belongs to the product categories of Chemical Synthesis;metal hydroxide. This chemical's molecular formula is LiOH.H2O and molecular weight is 41.96.Its EINECS number is 206-114-9. What's more,Its systematic name is Lithium hydroxide monohydrate. It is a white crystals or pellets which is stable,incompatible with moisture,strong acids,carbon dioxide. And it absorbs carbon dioxide from the air.It is used as analytical reagent, photographic developer, Besides it is also used in the manufacture of lithium .

Physical properties about Lithium hydroxide monohydrate are:
(1)ACD/LogP:  -1.38; (2)# of Rule of 5 Violations:  0; (3)ACD/LogD (pH 5.5):  -1.38; (4)ACD/LogD (pH 7.4):  -1.38; (5)ACD/BCF (pH 5.5):  1.00; (6)ACD/BCF (pH 7.4):  1.00; (7)#H bond acceptors:  1; (8)#H bond donors:  2; (9)#Freely Rotating Bonds:  0; (10)Enthalpy of Vaporization:  40.65 kJ/mol; (11)Boiling Point:  100 °C at 760 mmHg; (12)Vapour Pressure:  24.5 mmHg at 25°C.

You can still convert the following datas into molecular structure:
(1)SMILES:[Li+].[OH-].O;
(2)Std. InChI:InChI=1S/Li.2H2O/h;2*1H2/q+1;;/p-1;
(3)Std. InChIKey:GLXDVVHUTZTUQK-UHFFFAOYSA-M.

Safety Information of Lithium hydroxide monohydrate:
The Lithium hydroxide monohydrate is harmful by inhalation and if swallowed. In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) .It can causes severe burns. When you use it ,you should wear suitable protective clothing, gloves and eye/face protection and do not breathe dust.. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Take off immediately all contaminated clothing.

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