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CAS No.: | 13139-86-1 |
---|---|
Name: | 4-Methoxyphenylmagnesium bromide |
Article Data: | 38 |
Molecular Structure: | |
Formula: | C7H7BrMgO |
Molecular Weight: | 211.341 |
Synonyms: | Magnesium,bromo(p-methoxyphenyl)- (7CI,8CI);p-Methoxyphenylmagnesium bromide (6CI);(4-Methoxyphenyl)magnesium bromide;(p-Anisyl)bromomagnesium;4-Anisylmagnesiumbromide;Bromo(4-methoxyphenyl)magnesium;Bromo(p-methoxyphenyl)magnesium;p-Anisylmagnesium bromide; |
Density: | 0.955 g/mL at 25 °C |
Boiling Point: | 65-67 °C |
Flash Point: | -4 °F |
Solubility: | Severe reaction |
Appearance: | Clear to brown solution when properly stored |
Hazard Symbols: | F,C |
Risk Codes: | 11-14/15-19-34 |
Safety: | 16-26-36/37/39-43B-43-45-6A |
Transport Information: | UN 2924 3/PG 2 |
PSA: | 9.23000 |
LogP: | 2.34100 |
1-bromo-4-methoxy-benzene
4-methoxyphenyl magnesium bromide
Conditions | Yield |
---|---|
With magnesium; bromine In diethyl ether | |
With magnesium; copper(l) iodide In diethyl ether at -78℃; for 0.5h; Grignard reaction; Title compound not separated from byproducts; | |
With magnesium In tetrahydrofuran at 80℃; for 0.333333h; microwave irradiation; |
1-bromo-4-methoxy-benzene
7-chloro-1,2,3,4,4a,9b-hexahydro-2-methyl-5H-1,3-ethanoindeno-[1,2-c]pyridin-5-one
A
7-Chloro-5-(p-methoxyphenyl)-2-methyl-1,3-ethano-1,2,3,4,4a,9b-hexahydro-5H-indeno[1,2-c]pyridin-5-ol
B
4-methoxyphenyl magnesium bromide
Conditions | Yield |
---|---|
With magnesium In tetrahydrofuran; dichloromethane |
1-bromo-4-methoxy-benzene
1,10-Phenanthroline
ethylene dibromide
4-methoxyphenyl magnesium bromide
Conditions | Yield |
---|---|
With iodine; magnesium In tetrahydrofuran; 5,5-dimethyl-1,3-cyclohexadiene; iso-butanol |
1-bromo-4-methoxy-benzene
3-(p-methoxyphenyl)cyclobutanone
A
1,3-bis(p-methoxyphenyl)cyclobutanol
B
4-methoxyphenyl magnesium bromide
Conditions | Yield |
---|---|
In tetrahydrofuran |
Conditions | Yield |
---|---|
With 1,2-dibromomethane In tetrahydrofuran at 40℃; for 1.5h; | |
In tetrahydrofuran at 20℃; for 2h; | |
In tetrahydrofuran | |
In tetrahydrofuran Inert atmosphere; | |
With lithium chloride In tetrahydrofuran at 0 - 25℃; for 0.5h; Inert atmosphere; Schlenk technique; |
Conditions | Yield |
---|---|
With diethyl ether; iodine | |
With diethyl ether; iodine; benzene |
2-adamantanespiroxirane
4-methoxyphenyl magnesium bromide
2-(p-methoxy)benzyl-2-adamantanol
Conditions | Yield |
---|---|
In diethyl ether for 2h; Ambient temperature; | 100% |
4-methoxyphenyl magnesium bromide
Conditions | Yield |
---|---|
In tetrahydrofuran at -45℃; | 100% |
(2S,3S)-3-cyano-2,3-epoxy-1-propanol TBS ether
4-methoxyphenyl magnesium bromide
[(2R,3S)-3-(tert-Butyl-dimethyl-silanyloxymethyl)-oxiranyl]-(4-methoxy-phenyl)-methanone
Conditions | Yield |
---|---|
In toluene at -30℃; | 100% |
2,2,2-trifluoro-1-triphenylsilylethanone
4-methoxyphenyl magnesium bromide
Conditions | Yield |
---|---|
In tetrahydrofuran 1) -30 deg C, 15 min, 2) rt, 1 h; | 100% |
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Molecular Structure of 4-Methoxyphenylmagnesium bromide (CAS No.13139-86-1):
Molecular Formula: C7H7BrMgO
Molecular Weight: 211.3389
CAS No: 13139-86-1
H bond acceptors: 1
H bond donors: 0
Freely Rotating Bonds: 2
Polar Surface Area: 9.23 Å2
Systematic Name: Bromo(4-methoxyphenyl)magnesium
InChI: InChI=1/C7H7O.BrH.Mg/c1-8-7-5-3-2-4-6-7;;/h3-6H,1H3;1H;/q;;+1/p-1/rC7H7BrMgO/c1-10-7-4-2-6(9-8)3-5-7/h2-5H,1H3
InChIKey: JKXAZEXIOPFJSC-DZVGZYEUAY
Std. InChI: InChI=1S/C7H7O.BrH.Mg/c1-8-7-5-3-2-4-6-7;;/h3-6H,1H3;1H;/q;;+1/p-1
Std. InChIKey: JKXAZEXIOPFJSC-UHFFFAOYSA-M
Product Categories: Aryl;Grignard Reagents;Organometallic Reagents
Hazard Codes: F,C
Risk Statements: 11-14-19-22-34-14/15
R11:Highly flammable.
R14 :Reacts violently with water.
R22:Harmful if swallowed.
R34:Causes burns.
R15:Contact with water liberates extremely flammable gases.
Safety Statements: 16-26-33-36/37/39-45-6A-43B
S16:Keep away from sources of ignition.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S33:Take precautionary measures against static discharges.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S6:Keep under ... (there follows the name of an inert gas).
S43:In case of fire use ... (there follows the type of fire-fighting equipment to be used.)
RIDADR: UN 2924 3/PG 2
HazardClass: 4.3
PackingGroup: II
4-Methoxyphenylmagnesium bromide (CAS No.13139-86-1), its synonyms are p-Anisylmagnesium bromide ; Bromo(4-methoxyphenyl)magnesium ; Magnesium, bromo(4-methoxyphenyl)- .