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1314-15-4

Basic Information
CAS No.: 1314-15-4
Name: Platinum dioxide
Molecular Structure:
Molecular Structure of 1314-15-4 (Platinum dioxide)
Formula: PtO2
Molecular Weight: 227.08
Synonyms: Adams'catalyst;NSC 402624;Platinic oxide;Platinum dioxide;Platinum(IV) oxide;Platinum(Ⅳ)oxide trihydrate;Platinum oxide (PtO2);
EINECS: 215-223-0
Density: 10.2
Melting Point: 450 °C(lit.)
Boiling Point:
Flash Point:
Solubility: Soluble in caustic potash solution. Insoluble in water, acid, aquaregia.
Appearance: crystalline
Hazard Symbols: OxidizingO,IrritantXi
Risk Codes: 8-41-36/37/38
Safety: 26-36/37/39-28A-22-17
Transport Information: UN 1479
PSA: 34.14000
LogP: -0.24010
Synthetic route
7440-06-4

platinum

A

1314-15-4

platinum(IV) oxide

B

platinum(II) oxide

Conditions
ConditionsYield
at 510 °C;
at 510 °C;
7440-06-4

platinum

A

1314-15-4

platinum(IV) oxide

B

platinum(II) oxide

Conditions
ConditionsYield
at 510 °C; mixt of 70% PtO and 30% PtO2;
High Pressure; from platinum black at 420-450 °C, under 4-60 kg/cm2;
at 510 °C; mixt of 70% PtO and 30% PtO2;
7440-06-4

platinum

1314-15-4

platinum(IV) oxide

Conditions
ConditionsYield
In neat (no solvent) Kinetics; at 10E-1-10E5 Pa at high temp. (1300-1600°C);
on heating under reduced pressure;
under N2 reactn. of glowing filaments under equilibrium conditions at 1611-1943 K;
13454-96-1

platinum(IV) chloride

1314-15-4

platinum(IV) oxide

Conditions
ConditionsYield
With base (NaOH) In water 4 equiv. of C12H25(CH3)2N(1+)(CH2)3COO(1-) betain stabilizer, 50°C, 7 days; UV-vis spectroscopy;
With base (Li2CO3) In water 4 equiv. of C12H25(CH3)2N(1+)CH2COO(1-) betain stabilizer, refluxing for 2.5 h; UV-vis spectroscopy;

PtO3 hydrate

1314-15-4

platinum(IV) oxide

Conditions
ConditionsYield
byproducts: O2; in desiccator;

PtO2*4H2O=H2{Pt(OH)6}

1314-15-4

platinum(IV) oxide

Conditions
ConditionsYield
at 300°C in CO2 flow;

sodium oxide*3platinum(IV) oxide*6H2O

A

1314-15-4

platinum(IV) oxide

B

7440-06-4

platinum

Conditions
ConditionsYield
In neat (no solvent) byproducts: NaOH; calcination;; heterogenous product mixt. obtained;;
In neat (no solvent) byproducts: NaOH; calcination;; heterogenous product mixt. obtained;;

platinum(IV) oxide hydrate

1314-15-4

platinum(IV) oxide

Conditions
ConditionsYield
byproducts: H2O; heating at 175°C;
byproducts: H2O; heating at 200-400°C;

platinum(II) oxide hydrate

A

1314-15-4

platinum(IV) oxide

B

7440-06-4

platinum

Conditions
ConditionsYield
above 400 °C; PtO2 formed solid soln. in PtO;

silver platinum(IV) rhodanide

A

1314-15-4

platinum(IV) oxide

B

333-20-0

potassium thioacyanate

C

155645-84-4, 20667-12-3

silver (I) oxide

Conditions
ConditionsYield
With potassium hydroxide In not given
With KOH In not given

dihydrogen hexachloroplatinate

7631-99-4

sodium nitrate

1314-15-4

platinum(IV) oxide

Conditions
ConditionsYield
In not given

dihydrogen hexachloroplatinate(IV) hexahydrate

1314-15-4

platinum(IV) oxide

Conditions
ConditionsYield
In ethanol deposited by thermal decomposition; dried at 100°C for 10 min; calcined in oven (in air) at 400°C for 1 h;

platinum(II) oxide

A

1314-15-4

platinum(IV) oxide

B

7440-06-4

platinum

Conditions
ConditionsYield
500 °C;
500 °C;

platinum(IV) oxide hydrate

1314-15-4

platinum(IV) oxide

Conditions
ConditionsYield
byproducts: H2O; heating in air (400°C, 2 h);
7440-06-4

platinum

A

1314-15-4

platinum(IV) oxide

B

platinum(II) oxide

Conditions
ConditionsYield
With O2 High Pressure; at 350°C, treating with aqua regia; washing with alcohol-benzene mixt., drying at 130-140°C;
7440-06-4

platinum

1314-15-4

platinum(IV) oxide

Conditions
ConditionsYield
With oxygen treating with aqua regia at 450°C, under 150 atm, for 50 h;
With O2 treating with aqua regia at 450°C, under 150 atm, for 50 h;

2NH4(1+)*PtCl6(2-)*2NH4(1+)*2Cl(1-)=(NH4)2PtCl6*2NH4Cl

1314-15-4

platinum(IV) oxide

Conditions
ConditionsYield
In solid heating in air at temp. >270°C;
17836-09-8, 17457-51-1, 55449-91-7

trans-dichlorobis(dimethylsulfide)platinum(II)

20667-12-3

silver(l) oxide

1314-15-4

platinum(IV) oxide

Conditions
ConditionsYield
In water byproducts: S(CH3)2, AgCl; shaking with an aq. suspension of Ag2O for 20 min;;
7440-06-4

platinum

A

1314-15-4

platinum(IV) oxide

B

platinum(II) oxide

C

360562-79-4

Pt(η2-OO)

D

50417-49-7

Pt(η2-OO)2

Conditions
ConditionsYield
In neat (no solvent, solid phase) condensed at 4 K; UV;

PtO2

A

1314-15-4

platinum(IV) oxide

PtO2H

Conditions
ConditionsYield
at 1026.84 - 1226.84℃; Temperature;
7440-06-4

platinum

1314-15-4

platinum(IV) oxide

Conditions
ConditionsYield
at 976.84 - 1626.84℃; Temperature;
1314-15-4

platinum(IV) oxide

215656-54-5

N-[4-[2-(1-pyrrolidinyl)ethoxy]benzyl]-2-nitroaniline

215656-55-6

N1-[4-[2-(1-Pyrrolidinyl)ethoxy]benzyl]-1,2-benzenediamine

Conditions
ConditionsYield
In ethanol100%
1314-15-4

platinum(IV) oxide

215656-64-7

N-[3-methoxy-4-[(1-pyrrolidinyl)methyl]benzyl]-2-nitroaniline

215656-65-8

N1-[3-methoxy-4-[(1-pyrrolidinyl)methyl]benzyl]-1,2-benzenediamine

Conditions
ConditionsYield
In ethanol100%
1314-15-4

platinum(IV) oxide

10450-60-9

periodic acid

I6O18Pt(2-)*2H2O*2H(1+)

Conditions
ConditionsYield
With lithium carbonate for 96h; Autoclave; Heating;80%
1314-15-4

platinum(IV) oxide

7440-06-4

platinum

Conditions
ConditionsYield
With hydrogen In acetic acid under 760.051 Torr; for 1.5h;
With hydrogenchloride; hydrogen In hydrogenchloride bubbling of H2 through suspn. of PtO2 in aq. HCl for 20 min;
With hydrogen In water react. of PtO2 with H2 (50 psi) in water at room temp. for 30 min;
1314-15-4

platinum(IV) oxide

441064-91-1

3-cyclohexyl-imidazo[1,5-a]pyrazine

441064-90-0

3-cyclohexyl-5,6,7,8-tetrahydro-imidazo[1,5-a]pyrazine

Conditions
ConditionsYield
In ethanol
1314-15-4

platinum(IV) oxide

4-Bromo-2-[2-[3-bromophenyl]ethenyl]benzoic acid

216658-15-0

4-Bromo-2-[2-[3-bromophenyl]ethyl]benzoic acid

Conditions
ConditionsYield
In toluene
1314-15-4

platinum(IV) oxide

3-phosphonopyridine-2-carboxylic acid hydrochloride

3-phosphonopiperidine-2-carboxylic acid

Conditions
ConditionsYield
In acetic acid
In acetic acid
1314-15-4

platinum(IV) oxide

118343-42-3

3-isopropenyl-3H-isobenzofuran-1-one

64002-57-9

3-(methylethyl)-1(3H)-isobenzofuranone

Conditions
ConditionsYield
In ethanol
1314-15-4

platinum(IV) oxide

135675-29-5

1-(2-furyl)-1,2,3,4-tetrahydroisoquinoline

A

2'SR-1-(2-tetrahydrofuranyl)-1,2,3,4-tetrahydroisoquinoline

2'SR-1-(2-tetrahydrofuranyl)-1,2,3,4-tetrahydroisoquinoline

B

SR-1-(tetrahydrofuran-2-yl)-1,2,3,4-tetrahydroisoquinoline

Conditions
ConditionsYield
In ethanol
1314-15-4

platinum(IV) oxide

5,6-epoxy-6-(3-[3-hydroxy-undec-1E,5Z-dien-1-yl]phenyl) hexane-1-ol

Oxiranebutanoic acid, 3-[3-(3-hydroxy-1,5-undecadienyl)phenyl]-

Conditions
ConditionsYield
With nitrogen; sodium hydrogencarbonate In diethyl ether; water; acetone
1314-15-4

platinum(IV) oxide

6-(6-[3-hydroxy-undec-1E,5Z-dien-1-yl]pyridine-2-yl)-5Z-hexen-1-ol

5-Hexenoic acid, 6-[6-(3-hydroxy-1,5-undecadienyl)-2-pyridinyl)-

Conditions
ConditionsYield
With nitrogen; sodium hydrogencarbonate In water; acetone
1314-15-4

platinum(IV) oxide

403-66-7

p-nitrophenyl trifluoromethyl sulfide

372-16-7

thioorthocarbonotrifluoridic acid 4-amino-phenyl ester

Conditions
ConditionsYield
In ethanol
1314-15-4

platinum(IV) oxide

4287-19-8, 86809-26-9

1-amino-3-phenoxy-isopropanol

107332-71-8

methyl p-(2-oxopropoxy)phenoxyacetate

139734-40-0

methyl 2-p-(2-[(2-hydroxy-3-phenoxypropyl)amino]propoxy)-phenoxyacetate

Conditions
ConditionsYield
In methanol; dichloromethane; acetic acid methyl ester; water; toluene
1314-15-4

platinum(IV) oxide

82673-02-7

4-Allyloxy-3-chloro-phenylacetyl-glycine methyl ester

A

petroleum

petroleum

B

82673-16-3

4-n-Propoxy-3-chloro-phenylacetyl-glycine methyl ester

Conditions
ConditionsYield
In ethanol; hydrogen
1314-15-4

platinum(IV) oxide

66417-46-7

trans-3-(3-hydroxyphenyl)acrylic acid methyl ester

103324-20-5

methyl 2-(3-hydroxyphenyl)propanoate

107-30-2

chloromethyl methyl ether

50704-55-7

Methyl 3-(m-Methoxymethoxyphenyl)propionate

Conditions
ConditionsYield
In tetrahydrofuran; methanol
1314-15-4

platinum(IV) oxide

30030-80-9

3-(1-acetyl-1,4-dihydro-4-pyridyl)-5-methoxy-1H-indole

A

111608-71-0

3-(1-acetyl-4-piperidyl)-5-methoxyindole

B

52157-82-1

4-(5-methoxy-1H-indol-3-yl)piperidine

Conditions
ConditionsYield
In ethanol
1314-15-4

platinum(IV) oxide

yttrium(III) oxide

barium carbonate

copper(II) oxide

Y2BaCu1.6O(x)#dotPt

Y2BaCu1.6O(x)#dotPt

Conditions
ConditionsYield
In solid mixing oxides and BaCO3 (0.5 wt% PtO2), calcination (930°C, 24 h), pelletizing, sintering (950°C, 24 h), heating at 1100°C,air-quenching; electron and optical microscopy, EPMA;
1314-15-4

platinum(IV) oxide

yttrium barium copper oxide

Y2Ba2Cu2.6O(x)#dotPt

Y2Ba2Cu2.6O(x)#dotPt

Conditions
ConditionsYield
In solid heating YBa2Cu3O(x) (1100°C, 24 h), crushing, Pt doping, pelletizing, heating (1100°C, 24 h), crushing, Pt doping, pelletizing, heating (1100°C, 24 h); electron and optical microscopy, EPMA;
1314-15-4

platinum(IV) oxide

1633-05-2

strontium(II) carbonate

lead(II) oxide

Sr4PbPt4O11

Conditions
ConditionsYield
In melt SrCO3, PtO, PbO mixed, heated at 930°C for 3 h, slowly cooled to 850°C at 1°C/h, allowed to cool to room temp.; extd. with hot acetic acid, filtered, rinsed with water;
1314-15-4

platinum(IV) oxide

558-13-4

carbon tetrabromide

68-12-2, 33513-42-7

N,N-dimethyl-formamide

PtBr4*2(dmf)

Conditions
ConditionsYield
In N,N-dimethyl-formamide slow reaction, 100°C;
1314-15-4

platinum(IV) oxide

68-12-2, 33513-42-7

N,N-dimethyl-formamide

13063-43-9

dichloromalononitrile

PtCl4*2(dmf)

Conditions
ConditionsYield
In N,N-dimethyl-formamide 100°C;
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    Product Name: Platinum dioxide Synonyms: ADAMS CATALYST;ADAM'S CATALYST;ADAMS' CATALYST;ADAM'S TYPE CATALYST;Platimicoxide;Platinium oxide;Platinium oxide, PtO2;Platinum oxide (PtO2) CAS: 1314-15-4 MF: O2Pt MW: 227.08

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    Platinum dioxide 1314-15-4

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  • Casno:

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    Platinum dioxide/1314-15-4CAS NO.: 1314-15-4

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    1314-15-4

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  • Casno:

    1314-15-4

    MSDS/COA Download

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  • Casno:

    1314-15-4

    Platinum dioxide CAS NO.1314-15-4

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  • Casno:

    1314-15-4

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    1314-15-4

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    1314-15-4

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    1314-15-4

    ISO 9001 National Research Platform CAS No. 1314-15-4

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    1314-15-4

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  • PLATINUM DIOXIDE

  • Casno:

    1314-15-4

    PLATINUM DIOXIDE

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  • Casno:

    1314-15-4

    Platinum(IV) oxide/Cas No.:1314-15-4

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  • Casno:

    1314-15-4

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    1314-15-4

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  • Casno:

    1314-15-4

    Platinum dioxide

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    1314-15-4

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    1314-15-4

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    1314-15-4

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  • Casno:

    1314-15-4

    Platinum dioxide

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    Product Name: Platinum dioxide CAS: 1314-15-4 MF: O2Pt MW: 227.08 EINECS: 215-223-0 Mol File: 1314-15-4.mol Platinum dioxide Structure Platinum dioxide Chemical Properties Melting point 450 °C (lit.) density 10.2 RTECS

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    1314-15-4

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  • Casno:

    1314-15-4

    Platinum dioxide

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  • Casno:

    1314-15-4

    Platinum dioxide

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Specification

The Platinum dioxide (PtO2), with the CAS registry number 1314-15-4 and EINECS registry number 215-223-0, has the systematic name of dioxoplatinum. It is a kind of inorganics, and often used as hydrogenation catalyst. And the molecular formula of this chemical is PtO2.

The physical properties of Platinum dioxide (PtO2) are as followings: (1)#H bond acceptors: 2; (2)#H bond donors: 0; (3)#Freely Rotating Bonds: 0; (4)Polar Surface Area: 34.14 Å2.  

Preparation: Boil the concentrated pure H2PtCl6 solution and Na2CO3 concentrated solution to obtain PtO2.xH2O precipitate. Then kilndry it with the temperature of 200°C. Boil the precipitate with dilute Na2CO3 solution and distilled water to remove the chloride. And add dilute H2SO4 solution and distilled water to remove the alkali. After then, filter it and place it in water bath to make it dry.

You should be cautious while dealing with this chemical. It irritates to eyes, respiratory system and skin, and it also has risk of serious damage to eyes. What' s more, if contact with combustible material, it may cause fire. Therefore, you had better take the following instructions: Do not breathe dust; Keep away from combustible material; Wear suitable protective clothing, gloves and eye/face protection, and in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice; After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer).

You can still convert the following datas into molecular structure:
(1)SMILES: O=[Pt]=O
(2)InChI: InChI=1/2O.Pt/rO2Pt/c1-3-2
(3)InChIKey: YKIOKAURTKXMSB-FVLSDXBIAR