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1314-20-1

Basic Information
CAS No.: 1314-20-1
Name: Thorium dioxide
Molecular Structure:
Molecular Structure of 1314-20-1 (Thorium dioxide)
Formula: O2Th
Molecular Weight: 264.04
Synonyms: Thoria;Thorium dioxide;Thorium(IV) oxide;Thorotrast;Umbrathor;
EINECS: 215-225-1
Density: 9.86 g/cm3
Melting Point: 3050 °C
Boiling Point: 4400 °C
Solubility: Insoluble in water
Appearance: white, crystalline powder
Hazard Symbols: ToxicT,RadioactiveR
Risk Codes: 45-23/24/25-33
Safety: 53-36/37/39-45
Transport Information: UN 2910 7
PSA: 34.14000
LogP: -0.23760
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Specification

The Thorium oxide, with the CAS registry number 1314-20-1, is also known as Thorium dioxide. It belongs to the product categories of Inorganics; Catalysis and Inorganic Chemistry; Chemical Synthesis; Thorium; Metal Oxide. Its EINECS registry number is 215-225-1. This chemical's molecular formula is O2Th and molecular weight is 264.04. What's more, both its IUPAC name and systematic name are the same which is called Dioxothorium. Thorium oxide is a white, crystalline powder. It is produced mainly as a by-product of lanthanide and uranium production. This chemical is used in high-temperature ceramics, gas mantles, nuclear fuel, flame spraying, crucibles, non-silicia optical glass, catalysis, filaments in incandescent lamps, cathodes in electron tubes and arc-melting electrodes.

Physical properties about Thorium oxide are:
(1)#H bond acceptors: 2; (2)#H bond donors: 0; (3)#Freely Rotating Bonds: 0; (4)Polar Surface Area: 34.14 Å2; (5)Density: 9.86 g/cm3; (6)Melting Point: 3050 °C; (7)Boiling Point: 4400 °C.

Preparation of Thorium oxide:
this chemical can be prepared by thorium nitrate with oxalic acid.
Th(NO3)4 + 2 H2C2O4 → Th(C2O4)2 + 4 HNO3
Th(C2O4)2 → ThO2 + 2CO2 + 2CO

Safety information of Thorium oxide:
When you are dealing with this chemical, you should be very careful. This chemical may cause damage to health at low levels. It can produce or increase the incidence of non-heritable effects in progeny and/or an impairment in reproductive functions or capacity. This chemical is toxic by inhalation, in contact with skin and if swallowed. In addition, it may cause cancer and it has danger of cumulative effects. Therefore, you should wear suitable protective clothing, gloves and eye/face protection. You should avoid exposuring and obtain special instructions before using it. In case of accident or if you feel unwell seek medical advice immediately.

You can still convert the following datas into molecular structure:
(1) SMILES: O=[Th]=O
(2) InChI: InChI=1S/2O.Th
(3) InChIKey: ZCUFMDLYAMJYST-UHFFFAOYSA-N

The toxicity data of Thorium oxideis as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rat LD50 intratracheal > 1140mg/kg (1140mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.