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132-32-1

Basic Information
CAS No.: 132-32-1
Name: 9H-Carbazol-3-amine,9-ethyl-
Molecular Structure:
Molecular Structure of 132-32-1 (9H-Carbazol-3-amine,9-ethyl-)
Formula: C14H14N2
Molecular Weight: 210.28
Synonyms: Carbazole,3-amino-9-ethyl- (6CI,7CI,8CI);3-Amino-N-ethylcarbazole;9-Ethyl-3-carbazolamine;9-Ethyl-9H-carbazol-3-ylamine;NSC 67709;NSC 96640;
EINECS: 205-057-7
Density: 1.17 g/cm3
Melting Point: 85-88 °C(lit.)
Boiling Point: 420.9 °C at 760 mmHg
Flash Point: 208.4 °C
Solubility: <0.1 g/100 mL at 20 C
Appearance: brown fine crystalline powder and chunks
Hazard Symbols: ToxicT
Risk Codes: 25-36/37/38-40-23/24/25
Safety: 45-36/37/39-26-22
Transport Information: UN 2811 6.1/PG 3
PSA: 30.95000
LogP: 3.97780
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Chemistry

Chemical Name: 3-Amino-9-ethylcarbazole
IUPAC NAME: 9-ethylcarbazol-3-amine
CAS No.: 132-32-1
EINECS: 205-057-7
RTECS: FE3590000
RTECS Class: Tumorigen; Mutagen
Molecular Formula: C14H14N2
Molecular Weight: 210.27 g/mol
Melting Point: 85-88 °C(lit.)
Density: 1.17 g/cm3 
Flash Point: 208.4 °C
Boiling Point: 420.9 °C at 760 mmHg
 3-AMINO-9-ETHYLCARBAZOLE (132-32-1) is stable under normal temperatures and pressures.but incompatible with strong oxidizing agents.Following is the structure of 3-AMINO-9-ETHYLCARBAZOLE (132-32-1):

                  
The chemical synonymous of 3-AMINO-9-ETHYLCARBAZOLE (132-32-1) are TIMTEC-BB SBB000498 ; 2-AMINO-9-ETHYL CARBAZOLE ; 9-ETHYLCARBAZOL-3-AMINE ; 9-ETHYL-9H-CARBAZOL-3-YLAMINE ; AEC ; AEC BUFFER ; AEC SINGLE SOLUTION (RED) ; AEC SUBSTRATE BUFFER

Uses

 3-AMINO-9-ETHYLCARBAZOLE (132-32-1) is used as an intermediate for dye and organic pigment,and used for the production of Violet RL.It is also used as chemical intermediate for c.I. Pigment violet 23 & direct blue 108, histochemical indicator for assaying peroxidase, biological stain.

Production

Product Categories about 3-AMINO-9-ETHYLCARBAZOLE (132-32-1) are Intermediates of Dyes and Pigments ; Carbazoles (for Conduting Polymer Research) ; Carbazoles ; Functional Materials ; Reagents for Conducting Polymer Research ; Biochemistry ; Enzyme ; Substrates ; carbazole

Toxicity Data With Reference

1.    

ipr-mus LD50:150 mg/kg

    NTIS**    National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) AD691-490 .

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Suspected carcinogen with experimental carcinogenic data. Poison by ingestion and intraperitoneal routes. When heated to decomposition it emits toxic fumes of NOx.
Hazard Codes:
T: Toxic
Risk Statements about 3-AMINO-9-ETHYLCARBAZOLE (132-32-1):
    R25 Toxic if swallowed. 
    R36/37/38 Irritating to eyes, respiratory system and skin. 
    R40 Limited evidence of a carcinogenic effect. 
Safety Statements about 3-AMINO-9-ETHYLCARBAZOLE (132-32-1):
    S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
    S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
Health Hazard: ACUTE/CHRONIC HAZARDS: When heated to decomposition 3-Amino-9-ethylcarbazole emits toxic fumes.
Fire Hazard: Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated.
 

Standards and Recommendations

DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans

Specification

1. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
2. Handling: Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
3. Personal Protection: Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
4. Fire Fighting: Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
5. Reactivity Profile: 3-Amino-9-ethylcarbazole neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. May generate hydrogen, a flammable gas, in combination with strong reducing agents such as hydrides.