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13368-42-8

Basic Information
CAS No.: 13368-42-8
Name: Morpholine,4-(trimethylsilyl)-
Molecular Structure:
Molecular Structure of 13368-42-8 (Morpholine,4-(trimethylsilyl)-)
Formula: C7H17NOSi
Molecular Weight: 159.30
Synonyms: Morpholinotrimethylsilane;N-(Trimethylsilyl)morpholine;Trimethylmorpholinosilane;
EINECS:
Density: 0.91 g/cm3
Melting Point: <0 °C
Boiling Point: 160.1 °C at 760 mmHg
Flash Point: 50.6 °C
Solubility:
Appearance: Clear colorless to pale yellow liquid
Hazard Symbols: CorrosiveC
Risk Codes: 10-34
Safety: 26-36/37/39-45-16
Transport Information: UN 1993 3/PG 3
PSA: 12.47000
LogP: 1.09140
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Specification

The 4-(Trimethylsilyl)morpholine is an organic compound with the formula C7H17NOSi. The IUPAC name of this chemical is trimethyl(morpholin-4-yl)silane. With the CAS registry number 13368-42-8, it is also named as N-Trimethylsilylmorpholine. The product's categories are Protection & Derivatization Reagents (for Synthesis); Si (Classes of Silicon Compounds); Silicon Compounds (for Synthesis); Si-N Compounds; Synthetic Organic Chemistry; Trimethylsilylazide, etc.; Building Blocks; Heterocyclic Building Blocks; Morpholines.

Physical properties about 4-(Trimethylsilyl)morpholine are: (1)ACD/LogP: 0.17; (2)ACD/LogD (pH 5.5): -2.67; (3)ACD/LogD (pH 7.4): -1.12; (4)ACD/BCF (pH 5.5): 1; (5)ACD/BCF (pH 7.4): 1; (6)ACD/KOC (pH 5.5): 1; (7)ACD/KOC (pH 7.4): 1.49; (8)#H bond acceptors: 2 ; (9)#Freely Rotating Bonds: 1; (10)Polar Surface Area: 12.47 Å2; (11)Index of Refraction: 1.449; (12)Molar Refractivity: 46.78 cm3; (13)Molar Volume: 174.3 cm3; (14)Polarizability: 18.54×10-24cm3; (15)Surface Tension: 24.3 dyne/cm; (16)Density: 0.91 g/cm3; (17)Flash Point: 50.6 °C; (18)Enthalpy of Vaporization: 38.03 kJ/mol; (19)Boiling Point: 160.1 °C at 760 mmHg; (20)Vapour Pressure: 3.16 mmHg at 25°C.

Preparation: this chemical can be prepared by E-1-morpholino-1-phenyl-2-trimethylsilylethene. This reaction will need reagent morpholine. The reaction time is 19 hours at ambient temperature. The yield is about 41%.



Uses of 4-(Trimethylsilyl)morpholine: it can be used to produce 4-nitro-morpholine at temperature of 0 °C. It will need reagent N2O5 and solvent CH2Cl2 with reaction time of 2 hours. The yield is about 80%.

When you are using this chemical, please be cautious about it as the following:
It is flammable. Please keep away from sources of ignition - No smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Besides, this chemical can cause burns. When you are using it, wear suitable gloves and eye/face protection. In case of accident or if you feel unwell seek medical advice immediately (show the label where possible).

You can still convert the following datas into molecular structure:
(1)SMILES: O1CCN([Si](C)(C)C)CC1
(2)InChI: InChI=1/C7H17NOSi/c1-10(2,3)8-4-6-9-7-5-8/h4-7H2,1-3H3
(3)InChIKey: JJOWIQMPCCUIGA-UHFFFAOYAO
(4)Std. InChI: InChI=1S/C7H17NOSi/c1-10(2,3)8-4-6-9-7-5-8/h4-7H2,1-3H3
(5)Std. InChIKey: JJOWIQMPCCUIGA-UHFFFAOYSA-N