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13395-16-9

Basic Information
CAS No.: 13395-16-9
Name: Cupric acetylacetonate
Article Data: 15
Molecular Structure:
Molecular Structure of 13395-16-9 (Cupric acetylacetonate)
Formula: C10H14CuO4
Molecular Weight: 261.765
Synonyms: Copper, bis(2,4-pentanedionato-kO,kO')-, (SP-4-1)- (9CI);Bis(2,4-pentanedionato)copper;Bis(acetylacetonato)copper;Bis(acetylacetone)copper;Copperbis(2,4-pentanedionate);Copper bis(acetylacetonate);Copperbis(acetylacetone);Copper diacetylacetonate;Copper(2+) bis(acetylacetonate);Copper(II) acetylacetonate;Copper(II) bis(2,4-pentanedionate);Cupricacetylacetonate;Cupric bis(2,4-pentanedionate);Copper, bis(2,4-pentanedionato-O,O')-,(SP-4-1)-;Copper,bis(2,4-pentanedionato)- (6CI,8CI);Nacem Copper;
EINECS: 236-477-9
Density: 0.721 g/cm3
Melting Point: 284-288 °C (dec.)(lit.)
Boiling Point: 160 °C (9.7513 mmHg)
Flash Point: 160°C/10mm
Solubility: 0.2 g/L (20 °C) in water
Appearance: crystalline solid
Hazard Symbols: HarmfulXn, IrritantXi
Risk Codes: 36/37/38-20/21/22
Safety: 26-36-36/37/39
PSA: 52.60000
LogP: 1.91770
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Chemistry

Molecular Formula: C10H14CuO4
Molar mass: 261.76 g/mol
EINECS: 236-477-9
Flash Point: 71.9 °C
Boiling Point: 187.6 °C at 760 mmHg
Vapour Pressure: 0.174 mmHg at 25°C
Melting point: 284-288 °C (dec.)(lit.)
Appearance: Crystalline solid
Product categories: Pharmaceutical Intermediates;Homogeneous Catalysts;Organometallics;Chemistry;Transition Metal Compounds
Structure of Cupric acetylacetonate (13395-16-9):
                
XLogP3-AA: 4.1
H-Bond Donor: 0
H-Bond Acceptor: 4
IUPAC Name: Copper 4-oxopent-2-en-2-olate
Canonical SMILES: CC(=CC(=O)C)[O-].CC(=CC(=O)C)[O-].[Cu+2]
InChI: InChI=1S/2C5H8O2.Cu/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2 
InChIKey: QYJPSWYYEKYVEJ-UHFFFAOYSA-L

Uses

 Cupric acetylacetonate (13395-16-9) can be used as catalysts for organic synthesis and as analytical reagent.

Toxicity Data With Reference

1.    

ipr-mus LD50:19 mg/kg

    CHTHBK    Chemotherapy. 16 (1971),371.
2.    

ivn-mus LD50:10 mg/kg

    CSLNX*    U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) NX#00604 .

Carcinogenicity of Cupric acetylacetonate (13395-16-9) hasn't been listed as a carcinogen by NTP, IARC,ACGIH, or CA Prop 65. And its toxicological properties have not been fully investigated.You can see actual entry in RTECS for complete information.

Consensus Reports

Reported in EPA TSCA Inventory. Copper and its compounds are on the Community Right-To-Know List.

Safety Profile

Poison by intravenous and intraperitoneal routes. See also COPPER COMPOUNDS. When heated to decomposition it emits acrid smoke and fumes of Cu.
 

Hazard Codes: Xi,Xn
Risk Statements:
20:  Harmful by inhalation
21:  Harmful in contact with skin
22:  Harmful if swallowed 
36:  Irritating to the eyes
37:  Irritating to the respiratory system
38:  Irritating to the skin
Safety Statements:
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36:  Wear suitable protective clothing 
37:  Wear suitable gloves
39:  Wear eye/face protection

Specification

 Cupric acetylacetonate (13395-16-9) also can be called Copper(2+) bis[(2Z)-4-oxo-2-penten-2-olate] ; Copper(II) acetylacetonate .It is hazardous,so the first aid measures and others should be known.Such as: When on the skin: first,should  flush skin with plenty of water immediatelyfor at least 15 minutes while removing contaminated clothing. Secondly,Get shoesmedical aid . Or in the eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids.Then get medical aid soon.While ,it's Inhaled: Remove from exposure and move to fresh air immediately.Give artificial respiration while not breathing. When breathing is difficult, give oxygen.And as soon as to get medical aid. Then you have the ingesting of the product : Wash mouth out with water,and get medical aid immediately.Notes to physician: Treat supportively and symptomatically.
In addition, Cupric acetylacetonate (13395-16-9) is not compatible with strong oxidizing agents, and you must not take it with incompatible materials and dust generation. And also prevent it to broken down into hazardous decomposition products: carbon dioxide, carbon monoxide, 2,4-pentanedione , oxides of copper.