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CAS No.: | 13435-20-6 | ||||||||||||||||
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Name: | TETRAETHYLAMMONIUM CYANIDE | ||||||||||||||||
Article Data: | 3 | ||||||||||||||||
Molecular Structure: | |||||||||||||||||
Formula: | C8 H20 N | ||||||||||||||||
Molecular Weight: | 156.271 | ||||||||||||||||
Synonyms: | Ammonium,tetraethyl-, cyanide (8CI); Ethanaminium, N,N,N-triethyl-, cyanide (9CI);Tetraethylammonium cyanide (7CI) | ||||||||||||||||
Density: | g/cm3 | ||||||||||||||||
Melting Point: |
250 °C (dec.)(lit.) |
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Boiling Point: | °Cat760mmHg | ||||||||||||||||
Flash Point: | °C | ||||||||||||||||
Hazard Symbols: | |||||||||||||||||
Risk Codes: | 26/27/28-32-50/53 | ||||||||||||||||
Safety: |
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PSA: | 23.79000 | ||||||||||||||||
LogP: | 1.97918 |
Conditions | Yield |
---|---|
In water for 1h; Reflux; | 79% |
Conditions | Yield |
---|---|
In methanol | 50.6% |
2-isopropyliodobenzene
tetraethylammoniumcyanide
copper(I) cyanide
2-Isopropyl-1-benzonitrile
Conditions | Yield |
---|---|
1,1'-bis-(diphenylphosphino)ferrocene; tris-(dibenzylideneacetone)dipalladium(0) In tetrahydrofuran for 1.5h; Heating / reflux; | 100% |
C15H23ClN4O4
tetraethylammoniumcyanide
methyl 2-cyano-6-[2-{[(1,1-dimethylethyl)oxy]carbonyl}-1-(2-methylpropyl)hydrazino]-4-pyrimidinecarboxylate
Conditions | Yield |
---|---|
With trimethylamine In tetrahydrofuran at -78 - 20℃; for 24h; | 100% |
thorium di-π-cyclooctatetraene
tetraethylammoniumcyanide
Conditions | Yield |
---|---|
With pyridine for 15h; Reflux; Inert atmosphere; | 100% |
Conditions | Yield |
---|---|
In acetonitrile at 0℃; | 100% |
tetraethylammoniumcyanide
Conditions | Yield |
---|---|
In dichloromethane byproducts: tetraethylammonium tetrafluoroborate; Et4NCN (5% xs) was added to a soln. of Fe-complex in CH2Cl2 under Ar at 0°C, mixt. was stirred for 0.5 h; ether was added, soln. was filtered through a short plug of alumina to remove Et4NBF4, evapd. in vacuo; elem. anal.; | 99% |
tetraethylammoniumcyanide
Conditions | Yield |
---|---|
In acetonitrile room temp.; elem. anal.; | 99% |
tetraethylammoniumcyanide
Conditions | Yield |
---|---|
In nitromethane; dichloromethane inert atmosphere; 2 equiv. Et4NCN, stirring in CH2Cl2/MeNO2=1:1 for 1 h (dissoln.); filtration, crystn. on layering with Et2O (overnight), collection (filtration; elem. anal.; | 99% |
tris(bis(trimethylsilylamido))cerium(III)
tetraethylammoniumcyanide
Conditions | Yield |
---|---|
In toluene at -78 - 20℃; for 6h; Inert atmosphere; | 99% |