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CAS No.: | 13453-32-2 | ||||||
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Name: | THALLIUM(III) CHLORIDE HYDRATE | ||||||
Article Data: | 69 | ||||||
Molecular Structure: | |||||||
Formula: | Cl3Tl | ||||||
Molecular Weight: | 310.742 | ||||||
Synonyms: | Thallicchloride; Thallium (III) chloride; Thallium chloride; Thallium trichloride;Trichlorothallium | ||||||
Density: | g/cm3 | ||||||
Melting Point: | 155°C | ||||||
Boiling Point: | °Cat760mmHg | ||||||
Flash Point: | °C | ||||||
Solubility: | very soluble H2O, alcohols, ether [KIR83] | ||||||
Safety: |
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PSA: | 9.23000 | ||||||
LogP: | -9.05230 |
thallium (III) chloride
Conditions | Yield |
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With hydrogenchloride In not given rather concd. HCl, boiling;; | 100% |
With HCl In not given rather concd. HCl, boiling;; | 100% |
Conditions | Yield |
---|---|
In acetonitrile TlCl suspd. in CH3CN; Cl2 added under vigorous stirring; stirred for 30 min; soln. filtered; solvent evapd. in vacuum; SOCl2 added; evapd. after 10 min; | 98.5% |
Conditions | Yield |
---|---|
In neat (no solvent) at -20°C;; | |
In neat (no solvent) at -20°C;; |
Conditions | Yield |
---|---|
In neat (no solvent) at -20°C;; | |
In neat (no solvent) at -20°C;; |
thallium (III) chloride
Conditions | Yield |
---|---|
With chlorine In not given heating;; | |
With chlorine In water aq. suspension of TlCl;; | |
With KMnO4 or PbO2 or BaO2 In hydrogenchloride |
chlorochromate(VI) ion
B
thallium (III) chloride
Conditions | Yield |
---|---|
With hydrogenchloride In acetic acid Kinetics; prepn. of mixtures (TL(I), Cr(VI)) in 60% aq.CH3COOH (1.23 mol/l); keeping them at 25°C for about 3 h; accelaration of react. on increasing concn. of H(+) and Cl(-); addn. of Tl(III), Cr(III), Mn(II), Ce(III), Th(IV), U(VI) does not affect react.; detn. of Cr(VI) spectrophotometrically; detn. of Tl(III) jodometrically; | |
With ammonium vanadate In acetic acid Kinetics; prepn. of mixtures of TlCl and CrO3Cl(1-) in 60% aq. acetic acid contg. 1.25 mol/l HCl; keeping them at 25°C for more than 3 h; accelaration of react. by addn. of V(V) until concn. of V(V) exceeds concn. of Tl(I); detn. of Cr(VI) spectrophotometrically, detn. of Tl(III) jodometrically; |
Conditions | Yield |
---|---|
In neat (no solvent) vigorous reaction (coooling by solid CO2);; | |
In neat (no solvent) vigorous reaction (coooling by solid CO2);; |
thallium (III) chloride
Conditions | Yield |
---|---|
With hydrogenchloride In hydrogenchloride byproducts: Cl2; decompn.;; | |
With HCl In hydrogenchloride byproducts: Cl2; decompn.;; |
Conditions | Yield |
---|---|
In neat (no solvent) at -20°C;; | |
In neat (no solvent) at -20°C;; |
Conditions | Yield |
---|---|
In neat (no solvent) at -20°C;; | |
In neat (no solvent) at -20°C;; |