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| CAS No.: | 13520-92-8 |
|---|---|
| Name: | Zirconyl chloride octahydrate |
| Molecular Structure: | |
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|
|
| Formula: | ZrOCl2.8(H2O) |
| Molecular Weight: | 322.252 |
| Synonyms: | Dichlorooxozirconiumoctahydrate;Zirconium chloride oxide (ZrCl2O) octahydrate;Zirconium chlorideoxide, octahydrate;Zirconium dichloride monoxide octahydrate;Zirconiumdichloride oxide octahydrate;Zirconium monoxide dichloride octahydrate;Zirconium oxy dichloride octahydrate;Zirconium oxychloride octahydrate (ZrOCl2.8H2O); |
| EINECS: | 231-717-9 |
| Density: | 1.91 g/cm3 |
| Melting Point: | 400 °C (dec.) |
| Boiling Point: | 210°C |
| Solubility: | soluble in water |
| Appearance: | solid |
| Hazard Symbols: |
 C
|
| Risk Codes: | 34-22 |
| Safety: | 26-36/37/39-45-27 |
| PSA: | 90.91000 |
| LogP: | 0.74580 |
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| Conditions | Yield |
|---|---|
| In hydrogenchloride byproducts: CO2; Zr(CO3)2 dissolved in concd. HCl, refluxed for 1 h; cooled, filtered, washed with cold concd. HCl, recrystd. from aq. HCl, air dried; |
- 13520-92-8
ziconium(IV) oxychloride octahydrate
- 756-79-6
dimethyl methane phosphonate
| Conditions | Yield |
|---|---|
| With aq. HCl In water reflux (24 h or 112 h); aq. HBr or H2O alone may also be used; filtration, washing (H2O; acetone), drying (40°C, 18 h, then 200°C, 24 h); elem. anal.; | 99% |
| Conditions | Yield |
|---|---|
| In water | 95% |
| Conditions | Yield |
|---|---|
| In water | 95% |
| Conditions | Yield |
|---|---|
| In water | 95% |
| Conditions | Yield |
|---|---|
| In water | 95% |
| Conditions | Yield |
|---|---|
| In water | 95% |
- 13520-92-8
ziconium(IV) oxychloride octahydrate
- 10213-10-2
sodium tungstate (VI) dihydrate
| Conditions | Yield |
|---|---|
| With hydrogenchloride In water at 160℃; Autoclave; | 95% |
- 13520-92-8
ziconium(IV) oxychloride octahydrate
- 142-45-0
Acetylenedicarboxylic acid
| Conditions | Yield |
|---|---|
| Stage #1: ziconium(IV) oxychloride octahydrate; Acetylenedicarboxylic acid With acetic acid In N,N-dimethyl-formamide Sonication; Stage #2: In N,N-dimethyl-formamide at 85℃; for 6h; Sealed tube; | 94% |
- 13520-92-8
ziconium(IV) oxychloride octahydrate
- 142-45-0
Acetylenedicarboxylic acid
| Conditions | Yield |
|---|---|
| Stage #1: ziconium(IV) oxychloride octahydrate; Acetylenedicarboxylic acid With acetic acid In water; N,N-dimethyl-formamide for 0.0333333h; Sonication; Stage #2: at 85℃; for 6h; Sealed tube; | 94% |
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Standards and Recommendations
ACGIH TLV: TWA 5 mg(Zr)/m3; STEL 10 mg(Zr)/m3; Not Classifiable as a Human Carcinogen
DFG MAK: 1 mg(Zr)/m3
Specification
The Zirconyl chloride oxide octahydrate is an organic compound with the formula ZrOCl2.8(H2O). The IUPAC name of this chemical is oxozirconium octahydrate dihydrochloride. With the CAS registry number 13520-92-8, it is also named as Zirconium oxychloride octahydrate. The product's classification codes are Mutation data; Tumor data. Besides, it should be stored in a dry and well-ventilated place. It is used to manufacture zirconia. It is also used as rubber additives, paint drying, refractories, ceramics, glaze, and fiber treatment agent. It is widely used in rubber additives, paint driers, refractory and ceramic glaze.
Physical properties about Zirconyl chloride oxide octahydrate are: (1)#H bond acceptors: 1; (2)Polar Surface Area: 17.07 Å2.
Preparation: this chemical can be prepared by zircon and caustic soda. This reaction will need reagent sulfuric acid, ammonia, hydrochloric acid.
ZrSiO3+4NaOH→Na2ZrO3+NazSiO3+2H2O
Na2ZrO3+3H2SO4→Zr(SO4)2+Na2SO4+3H2O
Zr(SO4)2+4NH3.H2O→Zr(OH)4↓+2(NH4)2SO4
Zr(OH)4+2HCl+5H2O→ZrOCl2.8(H2O)
When you are using this chemical, please be cautious about it as the following:
It is harmful if swallowed. Please take off immediately all contaminated clothing. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Besides, this chemical can cause burns. When you are using it, wear suitable gloves and eye/face protection. In case of accident or if you feel unwell seek medical advice immediately (show the label where possible).
You can still convert the following datas into molecular structure:
(1)SMILES: O=[Zr].Cl.Cl.O.O.O.O.O.O.O.O
(2)InChI: InChI=1/2ClH.8H2O.O.Zr/h2*1H;8*1H2;;/r2ClH.OZr.8H2O/c;;1-2;;;;;;;;/h2*1H;;8*1H2
(3)InChIKey: FUBACIUATZGHAC-FUJGLDTFAK
(4)Std. InChI: InChI=1S/2ClH.8H2O.O.Zr/h2*1H;8*1H2;;
(5)Std. InChIKey: FUBACIUATZGHAC-UHFFFAOYSA-N