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13709-47-2

Basic Information
CAS No.: 13709-47-2
Name: Scandium trifluoride
Article Data: 79
Molecular Structure:
Molecular Structure of 13709-47-2 (Scandium trifluoride)
Formula: ScF3
Molecular Weight: 101.951
Synonyms: Scandiumfluoride;Scandium trifluoride;Scandium trifluoride (ScF3);
EINECS: 237-255-4
Density: 2.5
Melting Point: 1515°C
Appearance: powder
Hazard Symbols: ToxicT
Risk Codes: 23/24/25-32
Safety: 26-36/37/39-45
Transport Information: UN 3288 6.1/PG 3
PSA: 0.00000
LogP: 1.26060
Synthetic route

scandium(III) oxide

7664-39-3

hydrogen fluoride

A

13709-47-2

scandium(III) fluoride

B

scandium fluoride oxide

C

ScOF*2H2O

Conditions
ConditionsYield
In water 0°C;

scandium(III) oxide

cadmium(II) fluoride

13709-47-2

scandium(III) fluoride

Conditions
ConditionsYield
byproducts: CdO;
1279123-63-5

potassium hydrogenfluoride

scandium(III)

13709-47-2

scandium(III) fluoride

Conditions
ConditionsYield
In hydrogenchloride pptn. from 7E-3 molar Sc(3+)-soln. in aq. HCl, 90-95°C, pH=2;; no quantitative react. in presence of Zr(4+), Ti(4+), Al(3+) or Fe(3+);,;>99

scandium(III) oxide

ammonium fluoride

7664-39-3

hydrogen fluoride

13709-47-2

scandium(III) fluoride

Conditions
ConditionsYield
In hydrogenchloride dissolving Sc2O3 in aq. HCl, addn. of concd. HF-soln., evapn., further addn. of aq. HF and evapn. until complete removal of HCl; addn. of aq. HF, addn. of excess NH4HF, evapn. to dryness;; heating in a dry N2-stream to 700-800°C to remove NH4*HF and moisture (Pt-vessel), pure product;;
In hydrogenchloride dissolving Sc2O3 in aq. HCl, addn. of concd. HF-soln., evapn., further addn. of aq. HF and evapn. until complete removal of HCl; addn. of aq. HF, addn. of excess NH4HF, evapn. to dryness;; heating in a dry N2-stream to 700-800°C to remove NH4*HF and moisture (Pt-vessel), pure product;;

ammonium fluoride

scandium(III) chloride

13709-47-2

scandium(III) fluoride

Conditions
ConditionsYield
In water on addn. of ScCl3-soln. to excess NH4F;;0%

potassium fluoride

scandium(III)

13709-47-2

scandium(III) fluoride

Conditions
ConditionsYield
In water pptn. with aq. KF;;

scandium(III)

sodium fluoride

13709-47-2

scandium(III) fluoride

Conditions
ConditionsYield
In water pptn. with aq. NaF;;

scandium(III) oxide

13709-36-9

xenon difluoride

A

13709-47-2

scandium(III) fluoride

B

xenon

Conditions
ConditionsYield
In neat (no solvent) byproducts: oxygen; explosive convertion at 330-380°C, starting of fluorination at 210°C;

fluoride

scandium(III)

A

13709-47-2

scandium(III) fluoride

B

139890-84-9, 25376-96-9

tetrafluoroscandate(1-)

C

ScF(2+)

D

{ScF2}(2+)

Conditions
ConditionsYield
In perchloric acid formation in aq. soln.;;
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Chemistry

 Scandium fluoride ,its cas register number is 13709-47-2,is also named as Scadium trifluoride ; Scandium fluoride ; Scandium(III) fluoride ; Scandium fluoride (ScF3) ; Scandiumfluoride(scf3) ; Scandium fluoride, anhydrous, 99.99% ; Scandium (III) fluoride (99.9%-SC) (REO) ; CID83678 ; LS-144616 ,and so on. Scandium fluoride (CAS No.13709-47-2) is usually bright white powder.

IUPAC Name: Trifluoroscandium
CAS: 13709-47-2
Molecular Formula: F3Sc
Molecular Weight: 101.95
Molecular structure:
EINECS: 237-255-4
Melting point:  1515°C
Form:  powder
Sensitive:  Hygroscopic
H bond acceptors: 0 
H bond donors: 0 
Freely Rotating Bonds: 0 
H-Bond Donor: 0
H-Bond Acceptor: 3
Rotatable Bond Count: 0
Topological Polar Surface Area: 0
Heavy Atom Count: 4
Formal Charge: 0
Complexity: 8
Isotope Atom Count: 0
Covalently-Bonded Unit Count: 1

Uses

 Scandium fluoride (CAS No.13709-47-2) is commonly used as chemical reagent.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mammal (species unspecified) LD intraperitoneal > 10gm/kg (10000mg/kg)   Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 35(8), Pg. 43, 1991.
mammal (species unspecified) LD oral > 10gm/kg (10000mg/kg)   Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 35(8), Pg. 43, 1991.

RTECS:  VQ8930000

Safety Profile

Hazard Codes:  T,Xi  
Risk Statements:  23/24/25-32 (R23/24/25:Toxic by inhalation, in contact with skin and if swallowed. R32:Contact with acid liberates very toxic gas.)
Safety Statements:  26-36/37/39-45 (S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.))
RIDADR:  UN 3288 6.1/PG 3
WGK Germany:  3
Hazard Note:  Irritant
HazardClass:  6.1
PackingGroup:  III

Specification

Removal in wastewater treatment of Scandium fluoride (CAS No.13709-47-2) can be stated as follows:
Total removal:1.85  percent
Total biodegradation:0.09  percent
Total sludge adsorption:1.76  percent
Total to Air:0.00  percent
(using 10000 hr Bio P,A,S)